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    Multilayer imageable elements
    1.
    发明授权
    Multilayer imageable elements 失效
    多层可成像元件

    公开(公告)号：US07049045B2

    公开(公告)日：2006-05-23

    申请号：US10641888

    申请日：2003-08-14

    申请人： Paul Kitson ,  Kevin B. Ray ,  S. Peter Pappas

    发明人： Paul Kitson ,  Kevin B. Ray ,  S. Peter Pappas

    IPC分类号： G03F7/11

    CPC分类号： B41C1/1016 ,  B41C2210/02 ,  B41C2210/06 ,  B41C2210/14 ,  B41C2210/22 ,  B41C2210/24 ,  B41C2210/262 ,  Y10S430/145 ,  Y10S430/146

    摘要： Multilayer, positive working, thermally imageable, bakeable imageable elements are disclosed. The elements have a substrate, an underlayer, and a top layer. The underlayer comprises a resin or resins having activated methylol and/or activated alkylated methylol groups, such as a resole resin, and a polymeric material that comprises, in polymerized form about 5 mol % to about 30 mol % of methacrylic acid; about 20 mol % to about 75 mol % of N-phenylmaleimide, N-cyclohexylmaleimide, N-benzylmaleimide, or a mixture thereof; optionally, about 5 mol % to about 50 mol % of methacrylamide; and about 3 mol % to about 50 mol % of a compound represented by the formula: CH2C(R2)C(O)NHCH2OR1, in which R1 is C1 to C12 alkyl, phenyl, C1 to C12 substituted phenyl, C1 to C12 aralkyl, or Si(CH3)3; and R2 is H or methyl. The elements produce bakeable lithographic printing plates that are resistant to press chemistries.

    摘要翻译： 公开了多层，正面加工，可热成像的可烘烤成像元件。 这些元件具有基底，底层和顶层。 底层包括具有活化羟甲基和/或活化的烷基化羟甲基的树脂或树脂，例如甲阶酚醛树脂和聚合物形式，其聚合形式为约5mol％至约30mol％的甲基丙烯酸; 约20mol％至约75mol％的N-苯基马来酰亚胺，N-环己基马来酰亚胺，N-苄基马来酰亚胺或其混合物; 任选地，约5mol％至约50mol％的甲基丙烯酰胺; 和约3mol％至约50mol％的由下式表示的化合物：<？in-line-formula description =“In-line Formulas”end =“lead”？> CH 2 C （R 2）C（O）NHCH 2或OR 1，<βin-line-formula description =“In-line Formulas”end =“尾”→其中R 1为C 1〜C 12烷基，苯基，C 1〜 至C 12取代的苯基，C 1至C 12芳烷基或Si（CH 3 3） 3 R 2是H或甲基。 这些元件产生耐压印化学品的可烘烤平版印刷版。

    Multilayer imageable elements
    2.
    发明授权
    Multilayer imageable elements 失效
    多层可成像元件

    公开(公告)号：US06893783B2

    公开(公告)日：2005-05-17

    申请号：US10681701

    申请日：2003-10-08

    申请人： Paul Kitson ,  Kevin B. Ray ,  Mathias Jarek ,  S. Peter Pappas

    发明人： Paul Kitson ,  Kevin B. Ray ,  Mathias Jarek ,  S. Peter Pappas

    IPC分类号： G03F7/004 ,  B41C1/10 ,  B41M5/36 ,  G03F7/00 ,  G03F7/26 ,  G03F7/039 ,  G03F7/11 ,  G03F7/14 ,  G03F7/30 ,  G03F7/40

    CPC分类号： B41C1/1016 ,  B41C2210/02 ,  B41C2210/06 ,  B41C2210/14 ,  B41C2210/22 ,  B41C2210/24 ,  B41C2210/262 ,  Y10S430/111 ,  Y10S430/165

    摘要： Multilayer, positive working, thermally imageable elements are disclosed. The elements produce bakeable lithographic printing plates that are resistant to press chemistries. The elements have a substrate, an underlayer, and a top layer. The underlayer comprises a resin or resins having activated methylol and/or activated alkylated methylol groups, such as a resole resin, and a polymeric material that comprises, in polymerized form, (a) methacrylic acid; (b) N-phenylmaleimide, N-cyclohexylmaleimide, N-benzylmaleimide, or a mixture thereof; and (c) one or more monomers of the structure: in which: R1 is H or methyl; X is —(CH2)n—, where n is an integer from 2 to 12; —(CH2—CH2—O)p—CH2—CH2—, where p is an integer from 1 to 3; or —Si(R′)(R″)— where R′ and R″ are each independently methyl or ethyl; and m is 1, 2, or 3.

    摘要翻译： 公开了多层，正性加工，可热成像的元件。 这些元件产生耐压印化学品的可烘烤平版印刷版。 这些元件具有基底，底层和顶层。 底层包括具有活化羟甲基和/或活化的烷基化羟甲基的树脂或树脂，例如甲阶酚醛树脂和聚合物形式的聚合物材料，（a）甲基丙烯酸; （b）N-苯基马来酰亚胺，N-环己基马来酰亚胺，N-苄基马来酰亚胺或其混合物; 和（c）一种或多种结构单体：其中：R 1是H或甲基; X是 - （CH 2）n - ，其中n是2至12的整数; - （CH 2 CH 2 -CH 2） - CH 2 -CH 2 - SUB> - ，其中p是1至3的整数; 或-Si（R'）（R“） - 其中R'和R”各自独立地是甲基或乙基; m为1,2或3。

    Preparation of a printing plate using ink-jet
    3.
    发明授权
    Preparation of a printing plate using ink-jet 失效
    使用喷墨制备印版

    公开(公告)号：US07056643B2

    公开(公告)日：2006-06-06

    申请号：US10682707

    申请日：2003-10-09

    申请人： Kevin B. Ray ,  S. Peter Pappas ,  Kevin Wieland

    发明人： Kevin B. Ray ,  S. Peter Pappas ,  Kevin Wieland

    IPC分类号： G03F7/30

    CPC分类号： B41C1/1066 ,  B41M5/368

    摘要： A method for forming an image useful as a lithographic printing plate is disclosed. The imageable precursor comprises a water solubilized phenolic resin made up of an insoluble phenolic resin and a surfactant. The precursor can be imaged with an imaging solution, either off press or on press, using ink jet imaging techniques. The resulting imaged precursor can be developed using an aqueous liquid, such as water or a fountain solution, either off press or on press.

    摘要翻译： 公开了一种形成可用作平版印刷版的图像的方法。 可成像前体包括由不溶性酚醛树脂和表面活性剂组成的水溶性酚醛树脂。 使用喷墨成像技术，可以使用成像溶液，无论是按压还是按压成像前体。 所得到的成像前体可以使用水性液体如水或喷泉溶液来显影，无论是按压还是按压。

    Imageable element and waterless printing plate
    5.
    发明授权
    Imageable element and waterless printing plate 失效
    可成像元件和无水印版

    公开(公告)号：US06555283B1

    公开(公告)日：2003-04-29

    申请号：US09589334

    申请日：2000-06-07

    申请人： Xing-Fu Zhong ,  Jianbing Huang ,  S. Peter Pappas

    发明人： Xing-Fu Zhong ,  Jianbing Huang ,  S. Peter Pappas

    IPC分类号： G03F7021

    CPC分类号： B41C1/1016 ,  B41C2201/02 ,  B41C2201/14 ,  B41C2210/02 ,  B41C2210/04 ,  B41C2210/12 ,  B41C2210/14 ,  B41C2210/16 ,  B41C2210/22 ,  B41C2210/24 ,  B41M5/368 ,  G03F7/016 ,  G03F7/021 ,  G03F7/031 ,  G03F7/0752

    摘要： This invention relates to an imageable element that can be imaged and developed to produce a printing plate. The imageable element comprises a substrate and a radiation-sensitive imageable composition applied to the substrate. The imageable composition comprises (a) a first layer having (i) a photosensitive composition which undergoes a decrease in solubility in developer upon absorption of actinic radiation and (ii) an inhibitor, and (b) a second layer comprising an ink-repellent polymeric material. In one embodiment, the inhibitor is activated by heat or radiation of longer wavelength than actinic radiation. Upon activation, the inhibitor retards the solubility decrease of the photosensitive composition upon absorption of actinic radiation. In another embodiment, the inhibitor initially retards the solubility decrease of the photosensitive composition upon absorption of actinic radiation. However, the inhibitor is deactivated by heat or radiation of longer wavelength than actinic radiation, and upon deactivation the inhibitor no longer retards the solubility decrease of the photosensitive composition.

    摘要翻译： 本发明涉及可成像和显影以产生印版的可成像元件。 可成像元件包括施加到基底的基底和辐射敏感可成像组合物。 可成像组合物包含（a）第一层，其具有（i）在吸收光化辐射时在显影剂中溶解度降低的光敏组合物和（ii）抑制剂，和（b）包含拒油聚合物 材料。 在一个实施方案中，抑制剂通过比光化辐射更长波长的热或辐射活化。 激活时，抑制剂在吸收光化辐射时阻碍光敏组合物的溶解度降低。 在另一个实施方案中，抑制剂最初延迟光敏组合物在吸收光化辐射时的溶解度降低。 然而，抑制剂通过比光化辐射更长波长的热或辐射而失活，并且在失活时，抑制剂不再延迟感光组合物的溶解度降低。

    .alpha., .beta.-diacid/N,N-substituted diamine adduct catalyst for epoxy resin and acid polyester
    6.
    发明授权
    .alpha., .beta.-diacid/N,N-substituted diamine adduct catalyst for epoxy resin and acid polyester 失效
    用于环氧树脂和酸性聚酯的α，β-二酸/ N，N-取代二胺加合催化剂

    公开(公告)号：US5023303A

    公开(公告)日：1991-06-11

    申请号：US150167

    申请日：1988-01-29

    申请人： S. Peter Pappas

    发明人： S. Peter Pappas

    IPC分类号： C08G59/68 ,  C09D163/00

    CPC分类号： C08G59/686 ,  C09D163/00 ,  Y10S525/934

    摘要： The invention relates to a latent catalyst for epoxy resin containing compounds according to formula 1 ##STR1## in which R.sup.1 =C.sub.1 -C.sub.10 alkyl or arylR.sup.2 and R.sup.3 are the same or different C.sub.1 -C.sub.6 alkyl, C.sub.6 -C.sub.8 aryl or R.sup.2 and R.sup.3 form together a 4-8 membered ringin which R.sup.1, R.sup.2 and/or R.sup.3 can contain an ether-oxygen or sulphur atom, in which the amide and acid groups are in an a-b position bound to an aliphatic or aromatic group.

    Substrate improvements for thermally imageable composition and methods of preparation
    7.
    发明授权
    Substrate improvements for thermally imageable composition and methods of preparation 失效
    可热成像组合物的基材改进和制备方法

    公开(公告)号：US06692890B2

    公开(公告)日：2004-02-17

    申请号：US09826315

    申请日：2001-04-04

    申请人： Jen-Chi Huang ,  Xing-Fu Zhong ,  S. Peter Pappas ,  Shashikant Saraiya

    发明人： Jen-Chi Huang ,  Xing-Fu Zhong ,  S. Peter Pappas ,  Shashikant Saraiya

    IPC分类号： G03F700

    CPC分类号： B41C1/1025 ,  B41C2201/04 ,  B41C2210/04 ,  B41C2210/06 ,  B41C2210/10 ,  B41C2210/24 ,  B41C2210/262 ,  B41N3/03 ,  B41N3/038

    摘要： The present invention includes a radiation-imageable element for lithographic printing having a hydrophilic anodized aluminum base with a surface having pores and a image-forming layer having polymer particles coated on the aluminum base. The ratio of the average pore diameter to the average particle diameter is from 0.4:1 to 10:1. The present invention further includes a method of producing the imaged element. The method includes the steps of imagewise exposing the radiation-imageable element to radiation to produce exposed and unexposed regions and contacting the imagewise exposed radiation-imageable element and a developer to remove the exposed or the unexposed regions.

    摘要翻译： 本发明包括用于平版印刷的可辐射成像元件，其具有具有孔的表面的亲水阳极化铝基底和具有涂覆在铝基底上的聚合物颗粒的图像形成层。 平均孔径与平均粒径之比为0.4:1〜10:1。 本发明还包括一种制造成像元件的方法。 该方法包括以下步骤：将可辐射成像元件成像曝光到辐射以产生曝光和未曝光区域，并使图像曝光的可辐射成像元件和显影剂接触以去除曝光或未曝光区域。

    Masked presensitized printing plate intermediates and method of imaging same
    8.
    发明授权
    Masked presensitized printing plate intermediates and method of imaging same 失效
    掩蔽的敏化印版中间体及其成像方法

    公开(公告)号：US06413700B1

    公开(公告)日：2002-07-02

    申请号：US09709128

    申请日：2000-11-09

    申请人： Robert W. Hallman ,  Hui Zhu ,  Ken-Ichi Shimazu ,  S. Peter Pappas

    发明人： Robert W. Hallman ,  Hui Zhu ,  Ken-Ichi Shimazu ,  S. Peter Pappas

    IPC分类号： G03F711

    CPC分类号： G03F7/2018 ,  B41C1/1066

    摘要： A method for forming an image on a printing plate intermediate having a radiation transparent removable coating layer is disclosed. An image mask, opaque to ultraviolet radiation, is applied to the coating layer with an ink jet system. After the plate intermediate is exposed with ultraviolet radiation, the image mask and coating layer are removed, and plate intermediate developed.

    摘要翻译： 公开了一种在具有辐射透明可移除涂层的印版中间形成图像的方法。 用喷墨系统对涂层施加对紫外线辐射不透明的图像掩模。 将板中间体用紫外线照射后，除去图像掩模和涂层，并将平板中间体显影。