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    Imaging members with ionic multifunctional epoxy compounds
    2.
    发明授权
    Imaging members with ionic multifunctional epoxy compounds 失效
    成像用离子多官能环氧化合物

    公开(公告)号：US06841335B2

    公开(公告)日：2005-01-11

    申请号：US10207583

    申请日：2002-07-29

    申请人： Paul R. West ,  Jeffrey W. Leon ,  Robert E. McCovick ,  Nicki R. Miller

    发明人： Paul R. West ,  Jeffrey W. Leon ,  Robert E. McCovick ,  Nicki R. Miller

    IPC分类号： C08G59/14 ,  C09D163/00 ,  G03C1/76

    CPC分类号： B41C1/1041 ,  C08G59/1433 ,  C09D163/00 ,  Y10S430/165 ,  C08L2666/02

    摘要： An imaging member, such as a negative-working printing plate or on-press cylinder, can be prepared using a hydrophilic imaging layer comprising a hydrophilic heat-sensitive polymer containing a crosslinking agent comprising ionic groups and epoxy groups. This polymer may comprise quaternary ammonium carboxylate groups which may include at least one substituted-alkylene(C1-C3)-phenyl group. The imaging member also includes an infrared radiation sensitive material to provide added sensitivity to heat that can be supplied by laser irradiation in the IR region. The heat-sensitive polymer may be “switchable” in response to heat, and provides a lithographic image without wet processing.

    摘要翻译： 可以使用包含含有包含离子基团和环氧基团的交联剂的亲水性热敏性聚合物的亲水性成像层来制备成像构件，例如负性印刷板或压印滚筒。 该聚合物可以包含可以包括至少一个取代的亚烷基（C 1 -C 3） - 苯基的季铵羧酸酯基团。 成像构件还包括红外辐射敏感材料，以提供可以通过IR区域中的激光照射提供的热量的增加的灵敏度。 热敏聚合物可以响应于热量而“可切换”，并提供平版印刷图像而不进行湿法处理。

    Switchable polymer printing plates with carbon bearing ionic and steric stabilizing groups
    3.
    发明授权
    Switchable polymer printing plates with carbon bearing ionic and steric stabilizing groups 失效
    具有碳离子和立体稳定基团的可切换聚合物印版

    公开(公告)号：US07250245B2

    公开(公告)日：2007-07-31

    申请号：US10852552

    申请日：2004-05-24

    申请人： Paul R. West ,  Jeffrey W. Leon ,  Nicki R. Miller

    发明人： Paul R. West ,  Jeffrey W. Leon ,  Nicki R. Miller

    IPC分类号： G03F7/004 ,  G03F7/30

    CPC分类号： B41C1/1041

    摘要： The present invention provides an imageable member having an imageable layer including a heat-sensitive ionomer characterized by a net positive or negative charge, and a photothermal conversion material. The photothermal conversion material includes carbonaceous particles having thereon both an organic moiety including an ionic substituent having like charge as the ionomer, and a group represented by the formula —X-[NIon]p-Rterminal; wherein X represents an aromatic group or an alkyl group, NIon represents a non-ionic, non-ionizable group, Rterminal represents hydrogen, an aromatic group, an alkoxy group, or an alkyl group, and p is an integer from 1 to about 500. The heat-sensitive ionomer and modified carbonaceous particles can be formulated in water or water-miscible solvents without agglomeration. Imageable members utilizing the modified carbonaceous particles as a photothermal conversion material exhibit acceptable optical density and exposure speed, and imaged members made therefrom exhibit excellent background performance.

    摘要翻译： 本发明提供了一种可成像的构件，其具有包括以正正电荷或负电荷为特征的热敏离聚物的可成像层和光热转换材料。 光热转换材料包括其上具有包括具有类似电荷的离子取代基的有机部分作为离聚物的碳质粒子，以及由式<βin-line-formula description =“In-line Formulas”end =“lead “？” - X- [NIon] ; <？in-line-formula description =“In-line Formulas”end =“tail”？> 其中X表示芳族基团或烷基，NIon表示非离子型，不可离子化的基团，R 3表示氢，芳基，烷氧基或烷基，p表示 是1至约500的整数。热敏离聚物和改性碳质颗粒可以配制成水或水混溶性溶剂而不凝聚。 利用改性碳质颗粒作为光热转换材料的可成像构件表现出可接受的光密度和曝光速度，并由其制成的成像构件表现出优异的背景性能。

    Radiation-sensitive compositions and imageable materials
    5.
    发明授权
    Radiation-sensitive compositions and imageable materials 有权
    辐射敏感组合物和可成像材料

    公开(公告)号：US07175949B1

    公开(公告)日：2007-02-13

    申请号：US11356518

    申请日：2006-02-17

    申请人： Ting Tao ,  Paul R. West ,  Scott A. Beckley ,  Nicki R. Miller

    发明人： Ting Tao ,  Paul R. West ,  Scott A. Beckley ,  Nicki R. Miller

    IPC分类号： G03F7/032 ,  G03F7/033 ,  G03F7/031 ,  G03F7/30

    CPC分类号： G03F7/029 ,  G03F7/031 ,  G03F7/033 ,  Y10S430/106 ,  Y10S430/111

    摘要： A negative-working radiation-sensitive composition includes a polymeric binder comprising a polymer backbone and having attached thereto a carbazole derivative represented by the following Structure (I): wherein Y is a direct bond or a linking group, and R1 to R8 are independently hydrogen, or an alkyl, alkenyl, aryl, halo, cyano, alkoxy, acyl, acyloxy, or carboxylate groups, or any adjacent R1 through R8 groups can together form a carbocyclic or heterocyclic group or a fused aromatic ring. The composition can be sensitive to radiation having a maximum wavelength of from about 150 to about 1500 nm, and can be used to prepare negative-working imageable elements that be imaged and developed as lithographic printing plates.

    摘要翻译： 负性辐射敏感性组合物包括聚合物粘合剂，其包含聚合物骨架并且与其连接有由以下结构（I）表示的咔唑衍生物：其中Y是直接键或连接基，R 1， R 8和R 8独立地是氢或烷基，烯基，芳基，卤素，氰基，烷氧基，酰基，酰氧基或羧酸根基团，或任何相邻的R 1 通过R 8 O 8基团可以一起形成碳环或杂环基或稠合芳环。 组合物可以对具有约150至约1500nm的最大波长的辐射敏感，并且可用于制备作为平版印刷版成像和显影的负性可成像元件。

    Method for reducing start up blinding in no-process lithographic printing plates
    7.
    发明授权
    Method for reducing start up blinding in no-process lithographic printing plates 有权
    减少无处理平版印刷版中起动盲法的方法

    公开(公告)号：US06844140B1

    公开(公告)日：2005-01-18

    申请号：US10747643

    申请日：2003-12-29

    申请人： Scott Alan Wertz ,  Paul R. West ,  Nicki R. Miller

    发明人： Scott Alan Wertz ,  Paul R. West ,  Nicki R. Miller

    IPC分类号： B41C1/10 ,  B41M1/06 ,  B41N3/08 ,  G03F7/038 ,  B41F1/18 ,  B41M5/00 ,  B41M5/26 ,  G03F7/26

    CPC分类号： B41C1/1041 ,  B41C1/10 ,  B41M1/06 ,  B41N3/08 ,  B41P2227/70 ,  Y10S430/165

    摘要： A method for reducing start up blinding in no-process lithographic printing plates is disclosed. An imageable element, comprising an imageable layer over a substrate, is thermally imaged. The imageable layer comprises a thermally sensitive polymer that comprises quaternary ammonium salts of carboxylic acids. Following imaging, the surface of the imaged imageable is contacted with an aqueous solution comprising 0.05 wt % to about 5 wt % of an added organic acid having a pKa of about 1 to about 6. This reduces the amount of waste produced by the printing process by reducing the number of unusable sheets produced during the “make ready” process.

    摘要翻译： 公开了一种用于减少无工艺平版印刷版中的起动盲法的方法。 包含在衬底上的可成像层的可成像元件被热成像。 可成像层包含含有羧酸季铵盐的热敏聚合物。 成像后，成像的可成像的表面与包含0.05重量％至约5重量％的pKa为约1至约6的加入的有机酸的水溶液接触。这减少了印刷过程产生的废物量 通过减少在“准备”过程中生产的不可用片材的数量。

    System for direct-to-press imaging
    8.
    发明授权
    System for direct-to-press imaging 失效
    直接成像系统

    公开(公告)号：US06832554B2

    公开(公告)日：2004-12-21

    申请号：US10609732

    申请日：2003-06-30

    申请人： Nicki R. Miller ,  Barbara Nüssel ,  Jianbing Huang

    发明人： Nicki R. Miller ,  Barbara Nüssel ,  Jianbing Huang

    IPC分类号： B41F3102

    CPC分类号： B41C1/1041 ,  Y10S430/145 ,  Y10S430/146 ,  Y10S430/165

    摘要： A direct-to-press imaging method comprises: (a) applying an imageable coating to a printing cylinder, wherein the imageable coating comprises a composition such as a thermally switchable polymer which changes affinity for a printing fluid upon exposure to imaging radiation such as infrared radiation delivered imagewise via a laser, and the imageable coating is substantially insoluble in the printing fluid; (b) imagewise exposing the imageable coating to actinic radiation to obtain an imaged coating; (c) printing a plurality of copies of an image from the imaged coating; and (d) reapplying the imageable coating as desired by repeating steps (a) through (c) at least once without substantially removing the prior imaged coating before reapplying the imageable coating.

    摘要翻译： 直接成像成像方法包括：（a）将可成像涂层施加到印刷滚筒，其中可成像涂层包括诸如可热切换聚合物的组合物，其在暴露于诸如红外线的成像辐射时改变对印刷液体的亲和​​性 通过激光成像的辐射辐射，并且可成像的涂层基本上不溶于印刷液体;（b）将可成像的涂层成像曝光到光化辐射以获得成像的涂层;（c）从成像的 涂层; 和（d）通过重复步骤（a）至（c）至少一次，根据需要重新施加可成像涂层，而在重新施加可成像涂层之前基本上不去除现有的成像涂层。

    Method and system for direct-to-press imaging
    9.
    发明授权
    Method and system for direct-to-press imaging 失效
    直接成像的方法和系统

    公开(公告)号：US06610458B2

    公开(公告)日：2003-08-26

    申请号：US09911159

    申请日：2001-07-23

    申请人： Nicki R. Miller ,  Barbara Nüssel ,  Jianbing Huang

    发明人： Nicki R. Miller ,  Barbara Nüssel ,  Jianbing Huang

    IPC分类号： G03F7038

    CPC分类号： B41C1/1041 ,  Y10S430/145 ,  Y10S430/146 ,  Y10S430/165

    摘要： A direct-to-press imaging method comprises: (a) applying an imageable coating to a printing cylinder, wherein the imageable coating comprises a composition such as a thermally switchable polymer which changes affinity for a printing fluid upon exposure to imaging radiation such as infrared radiation delivered imagewise via a laser, and the imageable coating is substantially insoluble in the printing fluid; (b) imagewise exposing the imageable coating to actinic radiation to obtain an imaged coating; (c) printing a plurality of copies of an image from the imaged coating; and (d) reapplying the imageable coating as desired by repeating steps (a) through (c) at least once without substantially removing the prior imaged coating before reapplying the imageable coating.

    摘要翻译： 直接成像成像方法包括：（a）将可成像涂层施加到印刷滚筒，其中可成像涂层包括诸如可热切换聚合物的组合物，其在暴露于诸如红外线的成像辐射时改变对印刷液体的亲和​​性 通过激光成像的辐射辐射，并且可成像的涂层基本上不溶于印刷液体;（b）将可成像的涂层成像曝光到光化辐射以获得成像的涂层;（c）从成像的 涂层; 和（d）通过重复步骤（a）至（c）至少一次，根据需要重新施加可成像涂层，而在重新施加可成像涂层之前基本上不去除现有的成像涂层。