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公开(公告)号：US06346593B1
公开(公告)日：2002-02-12
申请号：US09458249
申请日：1999-12-09
IPC分类号： C08G7708
摘要： A polymerization process comprising mixing siloxane polymers with organosilicon compounds having at least one silicon-bonded group RN, which is a substituent comprising at least one amine group, and with a phosphazene base catalyst and allowing the siloxanes and organosilicon compounds to polymerize to form amino-functional polyorganosiloxane polymers is claimed. Preferably the phosphazene base is selected from the following formulae: ((R12N)3P═N—)x(R12N)3−xP═NR2; {((R12N)3P═N—)x(R12N)3−xP—N(H)R2}+{A−} {((R12N)3P═N—)y(R12N)4−yP}+{A}− or {(R12N)3P═N—(P(NR12)2═N)n—P+(NR12)3}{A−} in which R1 is hydrogen or an optionally substituted hydrocarbon group, or in which two R1 groups bonded to the same N atom may be linked to complete a heterocyclic ring, R2 is hydrogen or an optionally substituted hydrocarbon group, x is 1, 2 or 3; y is 1, 2, 3 or 4, n is an integer with a value of from 1 to 10 and A is an anion.
摘要翻译： 聚合方法包括将硅氧烷聚合物与具有至少一个含硅键合基团RN（其是包含至少一个胺基的取代基）和磷腈碱催化剂的有机硅化合物混合，并使硅氧烷和有机硅化合物聚合形成氨基 - 要求保护功能性聚有机硅氧烷聚合物。 优选地，磷腈碱选自下式：其中R 1是氢或任选取代的烃基，或者其中与相同N原子键合的两个R 1基团可以连接以形成杂环，R 2是氢或任选地 取代的烃基，x为1,2或3; y为1,2,3或4，n为1〜10的整数，A为阴离子。
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公开(公告)号：US06284859B1
公开(公告)日：2001-09-04
申请号：US09458251
申请日：1999-12-09
申请人： Peter Hupfield , Avril Surgenor , Richard Taylor
发明人： Peter Hupfield , Avril Surgenor , Richard Taylor
IPC分类号： C08G7708
CPC分类号： C08G77/08
摘要： A polymerization process comprising mixing siloxanes having silicon-bonded groups R′ with ionic phosphazene base catalysts and allowing condensation via reaction of Si—R′ groups with the formation of a Si—O—Si linkage, R′ denoting a hydroxyl group or a hydrocarbonoxy group having up to 8 carbon atoms is claimed. The catalysts may be of the general formulae: {((R12N)3P═N—)x(R12N)3−xP—N(H)R2}+{A−} or {((R12N)3P═N—)y(R12N)4−yP}+{A}− in which R1 is hydrogen or an optionally substituted hydrocarbon group or in which two R1 groups bonded to the same N atom may be linked to complete a heterocyclic ring, R2 is hydrogen or an optionally substituted hydrocarbon group, x is 1, 2 or 3, y is 1, 2, 3 or 4 and A is an anion. Also claimed is a process which comprises mixing siloxanes having silicon-bonded groups R′ and cyclic or linear siloxanes having no silicon-bonded groups R′ with ionic phosphazene base catalysts and allowing the siloxane having silicon-bonded groups R′ to condense and the cyclic and linear siloxanes having no silicon-bonded R′ groups to polymerize by equilibration.
摘要翻译： 一种聚合方法，包括将具有硅键合基团R'的硅氧烷与离子磷腈碱催化剂混合，并通过Si-R'基团与Si-O-Si键的形成反应进行缩合，R'表示羟基或烃氧基 要求具有至多8个碳原子的基团。 催化剂可以具有以下通式：其中R 1是氢或任选取代的烃基，或者其中与相同N原子键合的两个R 1可以连接成完全杂环，R 2是氢或任选被取代的烃基 ，x为1,2或3，y为1,2,3或4，A为阴离子。 还要求保护的方法包括将具有硅键合基团R'的硅氧烷与不与硅键合基团R'的环状或线性硅氧烷与离子型磷腈碱催化剂混合，并使具有硅键合基团R'的硅氧烷缩合并循环 和不具有硅键合的R'基团的直链硅氧烷通过平衡聚合。
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公开(公告)号：US06448196B1
公开(公告)日：2002-09-10
申请号：US09458244
申请日：1999-12-09
IPC分类号： B01J2714
摘要： Siloxanes are polymerized by equilibration, condensation and/or ring-opening polymerization using a phosphazene base catalyst. A linear phosphazene base catalyst of the general formula wherein R denotes a C1-10 hydrocarbon or wherein two R groups on one N atom form with the N atom a heterocyclic group, X denotes an anion and n is from 1 to 10 is prepared by reacting a linear phosphonitrile halide compound with a secondary amine or a salt of a secondary amine or a metal amide thereof to form an aminated phosphazene material, followed by an ion exchange reaction replacing the anion with a nucleophile.
摘要翻译： 硅氧烷通过使用磷腈碱催化剂的平衡，缩合和/或开环聚合而聚合。 通式化合物R的线型磷腈碱催化剂表示C1-10烃，或者其中一个N原子上的两个R基团与N原子是杂环基，X表示阴离子，n为1至10，通过使 线性磷腈卤化物与仲胺或仲胺或其金属酰胺的盐形成胺化磷腈材料，然后用亲核试剂代替阴离子进行离子交换反应。
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公开(公告)号：US06353075B1
公开(公告)日：2002-03-05
申请号：US09458245
申请日：1999-12-09
申请人： Peter Hupfield , Avril Surgenor , Richard Taylor
发明人： Peter Hupfield , Avril Surgenor , Richard Taylor
IPC分类号： C08G7708
摘要： A polymerization process comprising mixing a siloxane having silicon-bonded groups R′ and a cyclic or linear siloxane having no silicon-bonded groups R′ with a phosphazene base catalyst in the presence of water and allowing the siloxane having silicon-bonded groups R′ to condense and the cyclic or linear siloxane having no silicon-bonded R′ groups to polymerize by equilibration.
摘要翻译： 聚合方法包括在水存在下将具有硅键合基团R'的硅氧烷与不具有硅键合基团R'的环状或线性硅氧烷与磷腈碱催化剂混合并使具有硅键合基团R'的硅氧烷 缩合，并且没有硅键合的R'基团的环状或线性硅氧烷通过平衡聚合。
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公开(公告)号：US20090068911A1
公开(公告)日：2009-03-12
申请号：US11918308
申请日：2006-05-08
申请人： Peter Hupfield , Avril Surgenor
发明人： Peter Hupfield , Avril Surgenor
CPC分类号： D06M15/6436 , C08G77/26 , C08G77/28 , C11D3/373 , D06L1/00 , D06M15/657 , D21H19/32 , Y10T442/60
摘要： An organopolysiloxane containing both an amino functional organic group and a mercapto functional organic group is disclosed. A method of making such amino-mercapto functional organopolysiloxanes is by reacting (A) a silanol-functional polysiloxane, (B) an amino functional alkoxy silane, and (C) a mercapto functional alkoxy silane, via a condensation reaction. The amino-mercapto functional organopolysiloxanes products are useful in textile and fabric treatments.
摘要翻译： 公开了含有氨基官能的有机基团和巯基官能的有机基团的有机聚硅氧烷。 制备这种氨基 - 巯基官能的有机聚硅氧烷的方法是通过缩合反应使（A）硅烷醇官能的聚硅氧烷，（B）氨基官能的烷氧基硅烷和（C）巯基官能的烷氧基硅烷反应。 氨基 - 巯基官能的有机聚硅氧烷产品可用于纺织和织物处理。
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公开(公告)号：US20070073028A1
公开(公告)日：2007-03-29
申请号：US11602559
申请日：2006-11-21
申请人： Peter Hupfield , Avril Surgenor , Stephen Westall
发明人： Peter Hupfield , Avril Surgenor , Stephen Westall
摘要： An amino-functional polysiloxane is prepared by reacting an aminosilane (A) which contains an aminoalkyl group and at least one alkoxy group bonded to Si with a carboxylic acid and a silanol-functional polysiloxane (B). The aminosilane (A) is partially converted into its carboxylate salt which acts as a catalyst for the siloxane condensation polymerization reaction between (A) and (B).
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公开(公告)号：US08399591B2
公开(公告)日：2013-03-19
申请号：US13184688
申请日：2011-07-18
申请人： Peter Hupfield , Avril Surgenor
发明人： Peter Hupfield , Avril Surgenor
IPC分类号： C08G77/26
CPC分类号： D06M15/6436 , C08G77/26 , C08G77/28 , C11D3/373 , D06L1/00 , D06M15/657 , D21H19/32 , Y10T442/60
摘要： An organopolysiloxane containing both an amino functional organic group and a mercapto functional organic group is disclosed. A method of making such amino-mercapto functional organopolysiloxanes is by reacting (A) a silanol-functional polysiloxane, (B) an amino functional alkoxy silane, and (C) a mercapto functional alkoxy silane, via a condensation reaction. The amino-mercapto functional organopolysiloxanes products are useful in textile and fabric treatments.
摘要翻译： 公开了含有氨基官能的有机基团和巯基官能的有机基团的有机聚硅氧烷。 制备这种氨基 - 巯基官能的有机聚硅氧烷的方法是通过缩合反应使（A）硅烷醇官能的聚硅氧烷，（B）氨基官能的烷氧基硅烷和（C）巯基官能的烷氧基硅烷反应。 氨基 - 巯基官能的有机聚硅氧烷产品可用于纺织和织物处理。
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公开(公告)号：US08003746B2
公开(公告)日：2011-08-23
申请号：US11918308
申请日：2006-05-08
申请人： Peter Hupfield , Avril Surgenor
发明人： Peter Hupfield , Avril Surgenor
IPC分类号： C08G77/26
CPC分类号： D06M15/6436 , C08G77/26 , C08G77/28 , C11D3/373 , D06L1/00 , D06M15/657 , D21H19/32 , Y10T442/60
摘要： An organopolysiloxane containing both an amino functional organic group and a mercapto functional organic group is disclosed. A method of making such amino-mercapto functional organopolysiloxanes is by reacting (A) a silanol-functional polysiloxane, (B) an amino functional alkoxy silane, and (C) a mercapto functional alkoxy silane, via a condensation reaction. The amino-mercapto functional organopolysiloxanes products are useful in textile and fabric treatments.
摘要翻译： 公开了含有氨基官能的有机基团和巯基官能的有机基团的有机聚硅氧烷。 制备这种氨基 - 巯基官能的有机聚硅氧烷的方法是通过缩合反应使（A）硅烷醇官能的聚硅氧烷，（B）氨基官能的烷氧基硅烷和（C）巯基官能的烷氧基硅烷反应。 氨基 - 巯基官能的有机聚硅氧烷产品可用于纺织和织物处理。
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公开(公告)号：US07645518B2
公开(公告)日：2010-01-12
申请号：US10574679
申请日：2004-11-12
申请人： Peter Hupfield
发明人： Peter Hupfield
CPC分类号： D06M15/643 , C08G77/388 , C08G77/442 , C14C9/00 , D06M2200/11 , Y10T428/31663
摘要： Polymeric products are disclosed that are suitable for application to fibrous substrates such as textiles, leather and paper, to impart oil (oleophobicity) and water repellent (hydrophobicity) properties to the treated material. The polymeric products comprise an amino-functional polysiloxane bonded through its amino groups to an addition copolymer of a fluoro-substituted alkyl ester of an olefinically unsaturated carboxylic acid and an olefinically unsaturated monomer having a functional group capable of reacting with the amino groups of polysiloxane and optionally one or more olefinically unsaturated comonomers.
摘要翻译： 公开了适用于纺织品，皮革和纸等纤维基材以赋予处理材料油（疏油性）和疏水性（疏水性）性质的聚合物。 聚合产物包含通过其氨基与通过烯属不饱和羧酸的氟取代的烷基酯和具有能够与聚硅氧烷的氨基反应的官能团的烯属不饱和单体的加成共聚物键合的氨基官能聚硅氧烷， 任选的一种或多种烯属不饱和共聚单体。
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公开(公告)号：US07642326B2
公开(公告)日：2010-01-05
申请号：US10591842
申请日：2005-02-14
申请人： Peter Hupfield
发明人： Peter Hupfield
IPC分类号： C08F18/20
CPC分类号： D06M15/6436 , C08G77/442 , C08G77/452 , C09D183/08 , C09D183/10 , C14C9/00 , D06M15/277 , D06M15/3568 , D06M15/65 , D06M15/652 , D06M15/653 , D06M15/657 , D06M2200/10 , D06M2200/11 , D06M2200/12 , C08L2666/04 , C08L2666/28
摘要： Polymeric reaction products derived from a substituted aminosiloxane and a fluorosubstituted alkyl ester of an ethylenically carboxylic acid are disclosed. The polymeric reaction products are suitable for application to substrates such as textiles, particularly fabrics, to impart oil repellent properties to textiles.
摘要翻译： 公开了衍生自取代的氨基硅氧烷和烯键式羧酸的氟取代的烷基酯的聚合反应产物。 聚合反应产物适用于纺织品，特别是织物等基材，以赋予纺织品防油性能。
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