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    Polymerization catalyst and polymerization process
    2.
    发明授权
    Polymerization catalyst and polymerization process 有权
    聚合催化剂和聚合方法

    公开(公告)号：US06448196B1

    公开(公告)日：2002-09-10

    申请号：US09458244

    申请日：1999-12-09

    Applicant: David Eglin ,  Jean de la Cro Habimana ,  Peter Hupfield ,  Avril Surgenor ,  Richard Taylor

    Inventor： David Eglin ,  Jean de la Cro Habimana ,  Peter Hupfield ,  Avril Surgenor ,  Richard Taylor

    IPC: B01J2714

    CPC classification number: C08G77/08 ,  C07F9/067

    Abstract: Siloxanes are polymerized by equilibration, condensation and/or ring-opening polymerization using a phosphazene base catalyst. A linear phosphazene base catalyst of the general formula wherein R denotes a C1-10 hydrocarbon or wherein two R groups on one N atom form with the N atom a heterocyclic group, X denotes an anion and n is from 1 to 10 is prepared by reacting a linear phosphonitrile halide compound with a secondary amine or a salt of a secondary amine or a metal amide thereof to form an aminated phosphazene material, followed by an ion exchange reaction replacing the anion with a nucleophile.

    Abstract translation: 硅氧烷通过使用磷腈碱催化剂的平衡，缩合和/或开环聚合而聚合。 通式化合物R的线型磷腈碱催化剂表示C1-10烃，或者其中一个N原子上的两个R基团与N原子是杂环基，X表示阴离子，n为1至10，通过使 线性磷腈卤化物与仲胺或仲胺或其金属酰胺的盐形成胺化磷腈材料，然后用亲核试剂代替阴离子进行离子交换反应。

    Catalyst systems for polycondensation reactions
    3.
    发明授权
    Catalyst systems for polycondensation reactions 失效
    用于缩聚反应的催化剂体系

    公开(公告)号：US06828272B2

    公开(公告)日：2004-12-07

    申请号：US10149173

    申请日：2002-10-25

    Applicant: Jens-Peter Wiegner ,  Rolf Eckert ,  Volkmar Voerckel ,  Gunter Feix ,  Marion Sela ,  Sarat Munjal

    Inventor： Jens-Peter Wiegner ,  Rolf Eckert ,  Volkmar Voerckel ,  Gunter Feix ,  Marion Sela ,  Sarat Munjal

    IPC: B01J2714

    CPC classification number: B01J23/007 ,  B01J21/005 ,  B01J21/10 ,  B01J23/06 ,  C08G63/82

    Abstract: The invention pertains to new catalyst systems for polycondensation reactions, for example for producing polyethylene terephthalate. In accordance with the invention, complex compounds with hydrotalcite-analogous structures of general formula [M(II)1−xM(III)x(OH)2]x+(An−x/n).mH2O are used, wherein M(II) represents divalent metals, preferably Mg or Zn or NI or Cu or Fe(II) or Co, and M(III) represents trivalent metals, for example Al or Fe(III), and A represents anions, preferably carbonates or borates. These catalysts can be calcinated and can be used in combination with phosphorus compounds that contain at least one hydrolyzable phosphorus-oxygen bond.

    Abstract translation: 本发明涉及用于缩聚反应的新催化剂体系，例如用于生产聚对苯二甲酸乙二醇酯。 根据本发明，使用具有通式[M（II）1-xM（III）x（OH）2] x +（A n-）x / n）·mH 2 O的水滑石 - 类似结构的复合化合物 其中M（II）表示二价金属，优选Mg或Zn或NI或Cu或Fe（II）或Co，M（III）表示三价金属，例如Al或Fe（III），A表示阴离子 碳酸盐或硼酸盐。 这些催化剂可以被煅烧并且可以与含有至少一个可水解的磷 - 氧键的磷化合物组合使用。

    Methods of removing halogen from non-zeolitic molecular sieve catalysts
    5.
    发明授权
    Methods of removing halogen from non-zeolitic molecular sieve catalysts 有权
    从非沸石分子筛催化剂中除去卤素的方法

    公开(公告)号：US06440894B1

    公开(公告)日：2002-08-27

    申请号：US09891674

    申请日：2001-06-25

    Applicant: Luc R. Martens ,  Stephen N. Vaughn ,  Albert E. Schweizer ,  John K. Pierce

    Inventor： Luc R. Martens ,  Stephen N. Vaughn ,  Albert E. Schweizer ,  John K. Pierce

    IPC: B01J2714

    CPC classification number: B01J37/0009 ,  B01J29/85 ,  B01J37/10 ,  B01J2229/36 ,  C07C1/20 ,  C07C2529/85 ,  Y02P30/42

    Abstract: Methods of calcining non-zeolitic molecular sieve catalyst to remove most, if not nearly all, of halogen contained in the catalyst. One method includes heating the catalyst in a low moisture environment, followed by contacting the heated catalyst with air and/or steam. Another method includes steam-treating the catalyst at a temperature from 400° C. to 1000° C. The calcination methods provides a catalyst that contains from about 10 ppmw to about 600 ppmw chlorine, preferably 10 ppmw to about 200 ppmw chlorine, more preferably 10 ppmw to about 80 ppmw chlorine.

    Abstract translation: 煅烧非沸石分子筛催化剂以除去催化剂中所含的大部分（如果不是几乎全部）卤素的方法。 一种方法包括在低湿度环境中加热催化剂，然后将加热的催化剂与空气和/或蒸汽接触。 另一种方法包括在400℃至1000℃的温度下对催化剂进行蒸汽处理。煅烧方法提供了一种催化剂，其含有约10ppmw至约600ppmw的氯，优选含有10ppmw至约200ppmw的氯，更优选 10ppmw至约80ppmw氯。

    Process of preparing a fluid rare earth alkoxylation catalyst
    7.
    发明授权
    Process of preparing a fluid rare earth alkoxylation catalyst 有权
    制备流体稀土烷氧基化催化剂的方法

    公开(公告)号：US06514898B2

    公开(公告)日：2003-02-04

    申请号：US09737989

    申请日：2000-12-15

    Applicant: Charles Lee Edwards

    Inventor： Charles Lee Edwards

    IPC: B01J2714

    CPC classification number: C07C41/03 ,  B01J27/1804 ,  C07C43/11

    Abstract: A process to prepare an improved fluid rare earth phosphate catalyst composition useful in preparing alkylene oxide adducts of organic compounds having active hydrogen atoms is provided. The catalyst is prepared by dissolving a rare earth salt in a C9-C30 active hydrogen containing organic compound and then adding phosphoric acid to the organic compound rare earth mixture.

    Abstract translation: 提供了制备用于制备具有活性氢原子的有机化合物的环氧烷加合物的改进的流体稀土磷酸盐催化剂组合物的方法。 通过将稀土盐溶解在含C9-C30活性氢的有机化合物中，然后向有机化合物稀土混合物中加入磷酸制备催化剂。

    Mixtures comprising tetrakis(pyrrolidino/piperdino)phosphonium salts
    8.
    发明授权
    Mixtures comprising tetrakis(pyrrolidino/piperdino)phosphonium salts 有权
    包含四（吡咯烷子基/哌啶子）鏻盐的混合物

    公开(公告)号：US06407029B1

    公开(公告)日：2002-06-18

    申请号：US09617470

    申请日：2000-07-17

    Applicant: Berthold Schiemenz ,  Thomas Wessel ,  Ralf Pfirmann ,  Andreas Beck ,  Walter Hahn

    Inventor： Berthold Schiemenz ,  Thomas Wessel ,  Ralf Pfirmann ,  Andreas Beck ,  Walter Hahn

    IPC: B01J2714

    CPC classification number: C07C45/63 ,  C07B39/00 ,  C07F9/572 ,  C07F9/59 ,  C07C47/55

    Abstract: The present invention relates to mixtures comprising from 70 to 99.5% by weight of a compound of the formula (R)4P+X− (1) and from 30 to 0.5% by weight of a compound of the formula (R)3P═O (2), where R is in each case a radical and X− is an inorganic or organic anion or the equivalent of a multiply charged inorganic or organic anion, also to a process for preparing the mixtures by reacting a phosphorus pentahalide with pyrrolidine or piperidine in the molar ratio 1:6 to 1:50 in the presence of an inert solvent initially at −20 to 80° C., subsequently continuing the reaction at 90 to 180° C., treating the resulting reaction product at 0 to 80° C. with aqueous alkali at a pH of 7 to 15, and separating aqueous and organic phase from one another, and to the use of the mixtures as catalyst and cocatalyst for phase-transfer reactions, nucleophilic substitution reactions or halogen-fluorine exchange reactions.

    Abstract translation: 本发明涉及包含70-99.5重量％的式（R）4P + X-（1）的化合物和30至0.5重量％的式（R）化合物3P = O的混合物 （2），其中R在每种情况下是基团，X是无机或有机阴离子或相当于多电荷无机或有机阴离子，也是通过使五卤化磷与吡咯烷或哌啶反应制备混合物的方法 摩尔比1:6至1:50，最初在-20至80℃的惰性溶剂存在下，随后在90至180℃下继续反应，在0至80℃下处理所得反应产物 与碱水溶液在pH为7至15，并分离水相和有机相，并将混合物用作催化剂和助催化剂用于相转移反应，亲核取代反应或卤素 - 氟交换反应。

    Catalyst of a metal heteropoly acid salt that is insoluble in a polar solvent on a non-metallic porous support and method of making
    10.
    发明授权
    Catalyst of a metal heteropoly acid salt that is insoluble in a polar solvent on a non-metallic porous support and method of making 失效
    在非金属多孔载体上不溶于极性溶剂的金属杂多酸盐的催化剂及其制备方法

    公开(公告)号：US06815392B2

    公开(公告)日：2004-11-09

    申请号：US10280750

    申请日：2002-10-24

    Applicant: Yong Wang ,  Charles H. F. Peden ,  Saemin Choi

    Inventor： Yong Wang ,  Charles H. F. Peden ,  Saemin Choi

    IPC: B01J2714

    CPC classification number: B01J37/0209 ,  B01J27/188 ,  B01J37/0205

    Abstract: The present invention includes a catalyst having (a) a non-metallic support having a plurality of pores; (b) a metal heteropoly acid salt that is insoluble in a polar solvent on the non-metallic support; wherein at least a portion of the metal heteropoly acid salt is dispersed within said plurality of pores. The present invention also includes a method of depositing a metal heteropoly acid salt that is insoluble in a polar solvent onto a non-metallic support having a plurality of pores. The method has the steps of: (a) obtaining a first solution containing a first precursor of a metal salt cation; (b) obtaining a second solution containing a second precursor of a heteropoly acid anion in a solvent having a limited dissolution potential for said first precursor; (c) impregnating the non-metallic support with the first precursor forming a first precursor deposit within the plurality of pores, forming a first precursor impregnated support; (d) heating said first precursor impregnated support forming a bonded first precursor impregnated support; (e) impregnating the second precursor that reacts with the precursor deposit and forms the metal heteropoly acid salt.

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