Methine-azo compounds containing cyclic ammonium groups
    1.
    发明授权
    Methine-azo compounds containing cyclic ammonium groups 失效
    含有环状铵基团的甲基 - 偶氮化合物

    公开(公告)号:US4754021A

    公开(公告)日:1988-06-28

    申请号:US767912

    申请日:1985-08-21

    Applicant: Peter Mockli

    Inventor: Peter Mockli

    CPC classification number: D21H21/28 C09B56/16

    Abstract: Methine-azo compounds of the formulae ##STR1## in which A is the complement to a heterocyclic 5- or 6-membered ring which has a quaternized N atom as a ring member, which can contain further hetero atoms and which can be substituted and/or be fused with carbocyclic or heterocyclic rings,R is hydrogen, cyano or C.sub.2 -C.sub.3 -alkylene which is bonded to an N atom of ring A to form a 5- or 6-membered ring,B is substituted or unsubstituted phenylene or naphthylene,m and n independently of each other are the numbers 1 or 2, in the formula (I) at least one of the two symbols m and n being the number 2 and where in the case m=2 the two B's are identical or different,KK is the radical of a coupling componentX.sup..crclbar. is an anion and Y is a bridge member. These compounds can be used for dyeing and printing in particular polyacrylonitrile, acid-modified polyester and especially paper.

    Abstract translation: 其中A是具有季铵化的N原子作为环成员的杂环的5或6元环的互补物,其可以包含另外的化合物(IMA)(I)的化合物 杂原子,并且其可以被取代和/或与碳环或杂环稠合,R是氢,氰基或与环A的N原子键合以形成5-或6-元环的C 2 -C 3 - 亚烷基, B是取代或未取代的亚苯基或亚萘基,m和n彼此独立地是数字1或2,在式(I)中,两个符号m和n中的至少一个是数2,并且在情况m = 2两个B相同或不同,KK是偶联组分X( - )的基团是阴离子,Y是桥连构件。 这些化合物可用于特别是聚丙烯腈,酸改性聚酯和特别是纸的染色和印刷。

    Process for controlling tool infeed at machining start of a gear cutting
machine
    2.
    发明授权
    Process for controlling tool infeed at machining start of a gear cutting machine 失效
    齿轮切削机加工起始时控制刀具进给的过程

    公开(公告)号:US4744179A

    公开(公告)日:1988-05-17

    申请号:US875840

    申请日:1986-06-18

    Applicant: Peter Mockli

    Inventor: Peter Mockli

    Abstract: A process for controlling the tool infeed prior to machining a semi-machined gear comprises aligning the tool with the gear and feeding the tool radially inwardly in rapid traverse without making contact with the gear. The continuous rotating tool is then fed in incrementally in intervals of at least one gear revolution until the tool touches the gear for the first time. At this time the machining process is started.

    Abstract translation: 在加工半加工齿轮之前控制刀具进给的过程包括将刀具与齿轮对准,并以快速移动径向向内馈送刀具,而不与齿轮接触。 然后连续旋转工具以至少一个齿轮转的间隔递增递送,直到工具首次接触齿轮。 此时开始加工过程。

    Method of dyeing keratin-containing fibres

    公开(公告)号:US20060026776A1

    公开(公告)日:2006-02-09

    申请号:US11235912

    申请日:2005-09-27

    Applicant: Peter Mockli

    Inventor: Peter Mockli

    CPC classification number: A61Q5/065 A61K8/4946 C09B44/16

    Abstract: A method of dyeing keratin-containing fibres, which comprises using a dye of formula wherein R1 and R2 are each independently of the other hydrogen, C1-C4alkyl, halogen or nitro, R3 and R4 are each independently of the other unsubstituted C1-C4alkyl or C1-C4alkyl substituted by OH, C1-C4alkoxy, halogen, CN or by phenyl, X1 and X2 are each independently of the other hydrogen, C1-C4alkyl, C1-C4alkoxy or halogen, R5 is hydrogen or C1-C4alkyl, R6 is C5-C12alkyl or C5-C8cycloalkyl each unsubstituted or substituted by OH, C1-C4alkoxy, halogen, CN or phenyl, or R6 is C1-C4alkyl substituted by phenyl or by C5-C8cycloalkyl, or wherein R5 and R6 together with the nitrogen atom linking them form a piperazine ring, which is substituted, at the nitrogen atom that is not bonded to the phenyl group, by C1-C8-alkyl or phenyl, or which is quaternised at that nitrogen atom by two such groups, the C1-C8-alkyl radicals and phenyl mentioned as substituents of the nitrogen atom of the piperazine ring being unsubstituted or substituted by OH, C1-C4alkoxy, halogen, CN or phenyl, and wherein X− is an anion.

    Process for exchanging the anions of cationic compounds
    4.
    发明申请
    Process for exchanging the anions of cationic compounds 审中-公开
    交换阳离子化合物阴离子的方法

    公开(公告)号:US20050120493A1

    公开(公告)日:2005-06-09

    申请号:US10507383

    申请日:2003-03-04

    Applicant: Peter Mockli

    Inventor: Peter Mockli

    CPC classification number: D06P1/66 A61K8/494 A61Q5/10 C09B69/06

    Abstract: Process for converting sparingly soluble salts of cationic organic compounds and inorganic acids into more readily soluble salts of organic acids, which process comprises: a) preparing a sparingly water-soluble salt of the cationic organic compound with the anion of an inorganic acid, b) adding thereto, in a monohydric aliphatic alcohol, an alkali metal salt or an organic acid, c) filtering off the resulting sparingly soluble alkali metal salt of the inorganic acid, and d) optionally converting the resulting solution into a solid form.

    Abstract translation: 将阳离子有机化合物和无机酸的微溶盐转化为更容易溶解的有机酸盐的方法,该方法包括:a)用无机酸的阴离子制备阳离子有机化合物的微水溶性盐,b) 在一元脂肪醇,碱金属盐或有机酸中加入,c)过滤掉所得到的无机酸的微溶碱金属盐,以及d)任选地将所得溶液转化为固体形式。

    Methine-azo compounds containing cyclic cationic ammonium groups and
open-chain coupling components
    5.
    发明授权
    Methine-azo compounds containing cyclic cationic ammonium groups and open-chain coupling components 失效
    含有环状阳离子铵基团和开链偶合组分的甲基 - 偶氮化合物

    公开(公告)号:US4847364A

    公开(公告)日:1989-07-11

    申请号:US62418

    申请日:1987-06-16

    Applicant: Peter Mockli

    Inventor: Peter Mockli

    CPC classification number: D21H21/28 C09B56/16

    Abstract: Methine-azo compounds of the formula ##STR1## in which A is the complement to a heterocyclic 5- or 6-membered ring which has a quaternized N atom as a ring member, which can contain further hetero atoms and which can be substituted or/and be fused with carbocyclic or heterocyclic rings,R is hydrogen, cyano or C.sub.2 --C.sub.3 -alkylene which is bonded to an N atom of ring A to form a 5- or 6-membered ring,B is substituted or unsubstituted phenylene or naphthylene,X.sup..crclbar. is an anion andKK is the radical of an open-chain coupling component which contains active methylene groups, except that, if A is the complement to a pyridinium ring, KK cannot be the radical of acetoacetanilide which is unsubstituted or alkyl-substituted in the aniline ring.They are suitable for use as dyes for dyeing and printing cationically dyeable substrates, in particular paper.

    Abstract translation: 其中A是具有季铵化的N原子作为环成员的杂环5或6元环的互补物的式(IMAGE)的次甲基偶氮化合物,其可以含有其它杂原子并且可以被取代或/ 并与碳环或杂环稠合,R为氢,氰基或与环A的N原子键合的C 2 -C 3 - 亚烷基,形成5-或6-元环,B为取代或未取代的亚苯基或亚萘基, X( - )是阴离子,KK是含有活性亚甲基的开链偶联组分的基团,不同之处在于,如果A是吡啶鎓环的互补物,则KK不能是未取代的或烷基的乙酰乙酰苯胺基 在苯胺环中被取代。 它们适用于染色和印刷阳离子可染色基材,特别是纸张。

    Basic water-soluble bis-(.beta.-azo-.alpha.-naphtholamino)-triazine
compounds
    6.
    发明授权
    Basic water-soluble bis-(.beta.-azo-.alpha.-naphtholamino)-triazine compounds 失效
    碱性水溶性双 - (β-氮杂 - α-萘酚氨基) - 三嗪化合物

    公开(公告)号:US4654384A

    公开(公告)日:1987-03-31

    申请号:US570254

    申请日:1984-01-12

    CPC classification number: D21H21/28 C09B33/04 C09B43/16 C09B44/02

    Abstract: Novel water-soluble triazine compounds of the formula ##STR1## in which D and D.sub.1 independently of one another are radicals of diazo components, R and R.sub.1 independently of one another are hydrogen or C.sub.1 -C.sub.4 -aklyl, X is a monosubstituted or disubstituted amino group, a C.sub.1 -C.sub.4 -alkoxy group or an aryloxy group, the symbols Y are basic or cationic groups, which can be identical or different, l is 2, 3, 4, 5 or 6 and n is 0 or 1, and the number of basic and/or cationic groups Y in the molecule must be equal to or greater than the number of SO.sub.3 H groups are useful as dyes for dyeing and printing textile materials, leather and in particular, paper. The dyeings have good general fastness properties and the effluents remain colorless.

    Abstract translation: 其中D和D1彼此独立的式(I)< IMAGE>的新型水溶性三嗪化合物是重氮组分的基团,R和R 1彼此独立地是氢或C 1 -C 4 - 甲基,X 是单取代或二取代的氨基,C 1 -C 4 - 烷氧基或芳氧基,符号Y是碱性或阳离子基团,其可以相同或不同,l为2,3,4,5或6,n为 0或1,并且分子中碱基和/或阳离子基团Y的数目必须等于或大于SO 3 H基团的数量,其可用作染色和印刷纺织材料,皮革,特别是纸的染料。 染色具有良好的一般牢度特性,并且流出物保持无色。

    Cyanogenation of benzopyrones and naphthopyrones
    7.
    发明授权
    Cyanogenation of benzopyrones and naphthopyrones 失效
    苯并吡喃和萘醌的氰化

    公开(公告)号:US4634779A

    公开(公告)日:1987-01-06

    申请号:US430413

    申请日:1982-09-30

    Applicant: Peter Mockli

    Inventor: Peter Mockli

    CPC classification number: C09B57/00 C09B57/02

    Abstract: There are described novel dyes of the formulae ##STR1## in which R.sub.1 and R.sub.2 independently of one another are each hydrogen, unsubstituted or substituted alkyl, cycloalkyl, aralkyl or aryl, and R.sub.1 and R.sub.2 together with the nitrogen atom, and optionally with the inclusion of further hetero atoms, can also form a 5- to 7-membered heterocycle, or one of the radicals R.sub.1 or R.sub.2 can be linked with the carbon atom, in the o-position with respect to the amino group, of the ring A to form a fused-on, saturated, unsubstituted or substituted 5- or 6-membered ring,X is .dbd.NR.sub.3, .dbd.NCOR.sub.4, ##STR2## .dbd.NH or .dbd.O, wherein R.sub.3 is alkyl or unsubstituted or substituted phenyl,R.sub.4 is unsubstituted or substituted alkyl, aralkyl, aryl, vinyl, alkoxy, phenoxy or amino, andR.sub.5 is cyano, carbalkoxy, or unsubstituted or substituted carbonamide, andR.sub.6 is an electron-attracting radical,processes for producing them, and their use for dyeing and printing synthetic and semi-synthetic fibres, such as polyamide and cellulose triacetate materials, especially however polyester materials.

    Abstract translation: 描述了式(I)和(IMA)(II)的新颖染料,其中R 1和R 2彼此独立地为氢,未取代或取代的烷基,环烷基,芳烷基或芳基,并且R 1和R 2一起 与氮原子一起并且任选地含有另外的杂原子也可以形成5-至7-元杂环,或者R 1或R 2中的一个可以与碳原子连接,在o位置相对于 环A的氨基以形成稠合的,饱和的,未取代的或取代的5-或6-元环,X = NR 3,= NCOR 4,NH 3 =或其中R 3是烷基 或未取代或取代的苯基,R 4为未取代或取代的烷基,芳烷基,芳基,乙烯基,烷氧基,苯氧基或氨基,R 5为氰基,烷氧基或未取代或取代的碳酰胺,R6为吸电子基团, 它们以及它们用于染色和印刷合成纤维和半合成纤维如聚合物的用途 de和三乙酸纤维素材料,特别是聚酯材料。

    Dye mixtures of anthraquinone dyes
    8.
    发明授权
    Dye mixtures of anthraquinone dyes 失效
    蒽醌染料的染料混合物

    公开(公告)号:US4510088A

    公开(公告)日:1985-04-09

    申请号:US409211

    申请日:1982-08-18

    Applicant: Peter Mockli

    Inventor: Peter Mockli

    CPC classification number: C09B67/0038 C09B1/545 D06P1/20

    Abstract: Dye mixtures containing at least two dyes of the formula (1) ##STR1## wherein R is hydrogen, methyl or ethyl, and n is an integer from 2 to 4, exhibit on synthetic textile material a build-up which is considerably better than that of the individual dyes.

    Abstract translation: 含有至少两种式(1)的染料的染料混合物(1)其中R是氢,甲基或乙基,n是2至4的整数,在合成纺织材料上表现出相当大的组成 比单个染料好。

    Transfer printing supports and dyes for their manufacture: fluoroalkoxy
anthraquinone dye
    9.
    发明授权
    Transfer printing supports and dyes for their manufacture: fluoroalkoxy anthraquinone dye 失效
    转印印刷支架和染料用于制造:氟烷氧基蒽醌染料

    公开(公告)号:US4385900A

    公开(公告)日:1983-05-31

    申请号:US311332

    申请日:1981-10-14

    Applicant: Peter Mockli

    Inventor: Peter Mockli

    Abstract: The invention relates to transfer printing supports printed with a design which vaporizes in the temperature range from 180.degree. to 210.degree. C., and also to a process for printing synthetic planar textiles using such supports. The transfer printing supports contain, as red component, a 1-amino-4-hydroxyanthraquinone or -4-aminoanthraquinone compound which does not contain sulfo and carboxyl groups and which carries in the 2-position of the anthraquinone nucleus an alkoxy group which contains at least one fluorine atom and preferably at least three fluorine atoms.

    Abstract translation: 本发明涉及以180度至210℃的温度范围内蒸发的设计印刷的转印印刷载体,以及使用这种载体印刷合成平面纺织品的方法。 转印印刷支持体含有不含磺基和羧基的1-氨基-4-羟基蒽醌或-4-氨基蒽醌化合物,并且其在蒽醌核的2-位具有烷氧基,其含有 至少一个氟原子,优选至少三个氟原子。

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