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22 条记录 (耗时 0.031 秒)

    Process for preparing acylphosphanes and derivatives thereof
    1.
    发明授权
    Process for preparing acylphosphanes and derivatives thereof 有权
    制备酰基磷烷及其衍生物的方法

    公开(公告)号：US07687657B2

    公开(公告)日：2010-03-30

    申请号：US11667780

    申请日：2005-11-14

    申请人： Peter Murer ,  Jean-Pierre Wolf ,  Stephan Burkhardt ,  Hansjörg Grützmacher ,  Daniel Stein ,  Kurt Dietliker

    发明人： Peter Murer ,  Jean-Pierre Wolf ,  Stephan Burkhardt ,  Hansjörg Grützmacher ,  Daniel Stein ,  Kurt Dietliker

    IPC分类号： C07C69/76 ,  C07C69/95

    CPC分类号： G03F7/029 ,  C07F9/5036 ,  C07F9/5337 ,  C07F9/5537 ,  C07F9/65515 ,  C07F9/6552

    摘要： The invention relates to a process for the preparation of (bis)acylphosphanes of formula I, wherein n and m are each independently of the other 1 or 2; R1 if n=1, is e.g. unsubstituted or substituted C1-C18alkyl or C2-C18alkenyl, or phenyl, R1 if n=2, is e.g. a divalent radical of the monovalent radical defined above; R2 is e.g. C1-C18alkyl, C3-C12cycloalkyl, C2-C18alkenyl, mesityl, phenyl, naphthyl; R3 is one of the radicals defined under R1; the process comprises the steps a) contacting e.g. elemental phosphorous [P]∞, P(Hal)3 with a reducing metal optionally in the presence of a catalyst or an activator in a solvent to obtain metal phosphides Me3P or Me′3P2, wherein Me is an alkali metal and Me′ is an earth alkali metal or to obtain metal polyphosphides b) optionally adding a proton source, optionally in the presence of a catalyst or an activator to obtain metal dihydrogen phosphides MePH2; c) subsequent acylation reaction with m acid halides of formula III or m carboxylic acid esters of formula IV or, in case that in formula I m=1, with one carboxylic ester of formula IV followed by one acid halide of formula III or vice versa, wherein R is the residue of an alcohol and R2 is as defined above; d) alkylation reaction subsequent reaction with an electrophilic agent R1Hal or other electrophilic agents to obtain the compounds of formula I. An oxidation step may follow to obtain mono- and bisacylphosphane oxides or mono- and bisacylphosphane sulfides, which are used as photoinitiators.

    摘要翻译： 本发明涉及制备式（I）的（双）酰基磷烷的方法，其中n和m各自独立地为1或2; 如果n = 1，则为R1。 未取代或取代的C1-C18烷基或C2-C18链烯基，或苯基，如果n = 2，则为R1。 上述定义的一价基团的二价基团; R2是例如 C 1 -C 18烷基，C 3 -C 12环烷基，C 2 -C 18烯基，三甲苯基，苯基，萘基; R3是R1下定义的基团之一; 该方法包括以下步骤：a） 元素磷[P]∞，P（Hal）3与还原金属，任选在催化剂或活化剂存在下在溶剂中，得到金属磷化物Me3P或Me'3P2，其中Me为碱金属，Me'为 碱土金属或获得金属多磷酸盐b）任选地在催化剂或活化剂存在下加入质子源以获得金属二磷化磷MePH2; c）随后与式III的酰基卤或式IV的羧酸酯的酰化反应，或在式I中m = 1的情况下，与一种式IV的羧酸酯接触，然后加入式III的酰卤，反之亦然 其中R是醇的残基，R 2如上所定义; d）烷基化反应随后与亲电子试剂R1Hal或其他亲电子试剂反应以获得式I化合物。随后可以进行氧化步骤以获得用作光引发剂的单酰基和双酰基膦烷氧化物或单酰基和双酰基磷烷硫化物。

    Process for Preparing Acylphosphanes and Derivatives Thereof
    3.
    发明申请
    Process for Preparing Acylphosphanes and Derivatives Thereof 有权

    公开(公告)号：US20080004464A1

    公开(公告)日：2008-01-03

    申请号：US11667780

    申请日：2005-11-14

    申请人： Peter Murer ,  Jean-Pierre Wolf ,  Stephan Burkhardt ,  Hansjorg Grutzmacher ,  Daniel Stein ,  Kurt Dietliker

    发明人： Peter Murer ,  Jean-Pierre Wolf ,  Stephan Burkhardt ,  Hansjorg Grutzmacher ,  Daniel Stein ,  Kurt Dietliker

    IPC分类号： C07F9/50 ,  C07C69/66

    CPC分类号： G03F7/029 ,  C07F9/5036 ,  C07F9/5337 ,  C07F9/5537 ,  C07F9/65515 ,  C07F9/6552

    摘要： The invention relates to a process for the preparation of (bis)acylphosphanes of formula I, wherein n and m are each independently of the other 1 or 2; R1 if n=1, is e.g. unsubstituted or substituted C1-C18alkyl or C2-C18alkenyl, or phenyl, R1 if n=2, is e.g. a divalent radical of the monovalent radical defined above; R2 is e.g. C1-C18alkyl, C3-C12cycloalkyl, C2-C18alkenyl, mesityl, phenyl, naphthyl; R3 is one of the radicals defined under R1; the process comprises the steps a) contacting e.g. elemental phosphorous [P]∞, P(Hal)3 with a reducing metal optionally in the presence of a catalyst or an activator in a solvent to obtain metal phosphides Me3P or Me′3P2, wherein Me is an alkali metal and Me′ is an earth alkali metal or to obtain metal polyphosphides b) optionally adding a proton source, optionally in the presence of a catalyst or an activator to obtain metal dihydrogen phosphides MePH2; c) subsequent acylation reaction with m acid halides of formula III or m carboxylic acid esters of formula IV or, in case that in formula I m=1, with one carboxylic ester of formula IV followed by one acid halide of formula III or vice versa, wherein R is the residue of an alcohol and R2 is as defined above; d) alkylation reaction subsequent reaction with an electrophilic agent R1Hal or other electrophilic agents to obtain the compounds of formula I. An oxidation step may follow to obtain mono- and bisacylphosphane oxides or mono- and bisacylphosphane sulfides, which are used as photoinitiators.

    CHARGED PARTICLES
    8.
    发明申请
    CHARGED PARTICLES 有权
    充电颗粒

    公开(公告)号：US20120229884A1

    公开(公告)日：2012-09-13

    申请号：US13376874

    申请日：2010-06-11

    申请人： Pascal Hayoz ,  Bernd Lamatsch ,  Achim Lamatsch (Sole Heir) ,  Margherita Fontana ,  Stephan Burkhardt ,  Laurent Michau ,  Urs Lehmann ,  Philippe Bugnon

    发明人： Pascal Hayoz ,  Bernd Lamatsch ,  Achim Lamatsch (Sole Heir) ,  Margherita Fontana ,  Stephan Burkhardt ,  Laurent Michau ,  Urs Lehmann ,  Philippe Bugnon

    IPC分类号： G02F1/167 ,  C07F7/10 ,  C07F9/54 ,  G02B1/04 ,  C09D11/00 ,  B82Y30/00

    CPC分类号： C09B69/008 ,  C09B69/04 ,  G02F1/167 ,  G02F2001/1678

    摘要： Disclosed is a composition comprising a charged particle of volume 5 nm3 to 50 million nm3 preferably having an inorganic core of SiO2, AI2O3, and/or TiO2, or a core essentially consisting of an organic pigment and/or pigment derivative, and a counter ion which is separable from the particle and is not covalently linked to the particle, said counter ion comprising a silicon atom which is directly bound to a carbon atom. Preferably, said charged particle comprises a dye attached to said inorganic core and said counter ion comprises a (poly)siloxane moiety linked via suitable bridge members to a quaternary, positively charged, nitrogen or phosphorus atom, or to a moiety carrying an anionic functional group. Said composition may be used e.g. in the form of a homogenous dispersion in an electrophoretic display.

    摘要翻译： 公开了一种组合物，其包含体积为5nm至5000nm的带电粒子，优选具有SiO 2，Al 2 O 3和/或TiO 2的无机核心或基本上由有机颜料和/或颜料衍生物组成的核心，以及抗衡离子 其与颗粒分离并且不与颗粒共价连接，所述反离子包含直接与碳原子结合的硅原子。 优选地，所述带电粒子包括连接到所述无机核的染料，并且所述抗衡离子包含通过合适的桥连构件连接到季，带正电荷，氮或磷原子上的（多）硅氧烷部分，或含有阴离子官能团的部分 。 所述组合物可以例如使用。 以电泳显示器中的均匀色散的形式。