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    High molecular weight polyols, process for preparation and use thereof
    5.
    发明授权
    High molecular weight polyols, process for preparation and use thereof 失效
    高分子量多元醇，其制备方法和用途

    公开(公告)号：US06420320B1

    公开(公告)日：2002-07-16

    申请号：US09656855

    申请日：2000-09-07

    申请人： Philip W. McGraw ,  Robert H. Whitmarsh

    发明人： Philip W. McGraw ,  Robert H. Whitmarsh

    IPC分类号： C10M11104

    CPC分类号： C10M173/02 ,  C08G18/10 ,  C08G18/4837 ,  C08G18/4866 ,  C08G18/718 ,  C08G65/2651 ,  C08G65/336 ,  C10M107/34 ,  C10M145/26 ,  C10M145/28 ,  C10M145/30 ,  C10M2201/02 ,  C10M2209/103 ,  C10M2209/104 ,  C10M2209/105 ,  C10M2209/107 ,  C10N2220/02 ,  C10N2240/08 ,  C10N2250/02 ,  C08G18/307

    摘要： The invention is a high molecular weight polyether polyol prepared by the reaction of one or more compounds having one or more active hydrogen compounds with one or more alkylene oxides in the presence of a catalyst comprising calcium having counterions of carbonate and a C6-10 alkanoate in a solvent or dispersant which does not contain active hydrogen atoms. The polyether polyol prepared preferably has an equivalent weight of from about 10,000 to about 30,000, a polydispersity of 1.3 or less and a residual catalyst level of from more than 0 to about 2000 parts per million (ppm). In another embodiment the invention is a process for preparing such high molecular weight polyether polyols. The process comprises first, contacting one or more compounds having one or more active hydrogen atoms with one or more alkylene oxides in the presence of a catalyst. The catalyst comprises calcium having counterions of carbonate and a C6-10 alkanoate in a solvent, wherein the solvent does not contain active hydrogen atoms. The mixture is exposed to conditions at which the alkylene oxides react with the compound containing more than one active hydrogen atoms such that a polyether polyol is prepared which has an equivalent weight of from about 10,000 to about 30,000, a polydispersity of about 1.3 or less and a residual catalyst level of from more than 0 to about 2,000 (ppm).

    摘要翻译： 本发明是一种高分子量聚醚多元醇，其通过一种或多种具有一种或多种活性氢化合物与一种或多种烯化氧的化合物的反应制备，所述化合物在催化剂存在下，该催化剂包含具有与碳酸酯和C 6-10链烷酸酯的抗衡离子的钙 不含活性氢原子的溶剂或分散剂。 制备的聚醚多元醇的当量重量优选为约10,000至约30,000，多分散性为1.3或更低，残留催化剂含量为大于0至约2000ppm（ppm）。 在另一个实施方案中，本发明是制备这种高分子量聚醚多元醇的方法。 该方法首先在催化剂存在下使具有一个或多个活性氢原子的一种或多种化合物与一种或多种环氧烷接触。 该催化剂包括在溶剂中具有碳酸酯和C 6-10链烷酸酯的抗衡离子的钙，其中溶剂不含活性氢原子。 将混合物暴露于环氧烷与含有多于一个活性氢原子的化合物反应的条件，使得制备的聚醚多元醇的当量为约10,000至约30,000，多分散度为约1.3或更小，以及 残余催化剂含量大于0至约2,000（ppm）。

    High molecular weight polyols, process for preparation and use thereof
    6.
    发明授权
    High molecular weight polyols, process for preparation and use thereof 失效
    高分子量多元醇，其制备方法和用途

    公开(公告)号：US06362140B1

    公开(公告)日：2002-03-26

    申请号：US09656603

    申请日：2000-09-07

    申请人： Philip W. McGraw ,  Robert H. Whitmarsh

    发明人： Philip W. McGraw ,  Robert H. Whitmarsh

    IPC分类号： C10M10734

    CPC分类号： C10M173/02 ,  C08G18/10 ,  C08G18/4837 ,  C08G18/4866 ,  C08G18/718 ,  C08G65/2651 ,  C08G65/336 ,  C10M107/34 ,  C10M145/26 ,  C10M145/28 ,  C10M145/30 ,  C10M2201/02 ,  C10M2209/103 ,  C10M2209/104 ,  C10M2209/105 ,  C10M2209/107 ,  C10N2220/02 ,  C10N2240/08 ,  C10N2250/02 ,  C08G18/307

    摘要： The invention is a high molecular weight polyether polyol prepared by the reaction of one or more compounds having one or more active hydrogen compounds with one or more alkylene oxides in the presence of a catalyst comprising calcium having counterions of carbonate and a C6-10 alkanoate in a solvent or dispersant which does not contain active hydrogen atoms. The polyether polyol prepared preferably has an equivalent weight of from about 1000 to about 20,000, a polydispersity of 1.3 or less and a residual catalyst level of from about 0 to about 2000 parts per million (ppm). In another embodiment the invention is a process for preparing such high molecular weight polyether polyols. The process comprises first, contacting one or more compounds having one or more active hydrogen atoms with one or more alkylene oxides in the presence of a catalyst. The catalyst comprises calcium having counterions of carbonate and a C6-10 alkanoate in a solvent, wherein the solvent does not contain active hydrogen atoms. The mixture is exposed to conditions at which the alkylene oxides react with the compound containing more than one active hydrogen atoms such that a polyether polyol is prepared which has an equivalent weight of from about 1,000 to about 20,000, a polydispersity of about 1.3 or less and a residual catalyst level of from about 0 to about 1000 (ppm).

    摘要翻译： 本发明是一种高分子量聚醚多元醇，其通过一种或多种具有一种或多种活性氢化合物与一种或多种烯化氧的化合物的反应制备，所述化合物在催化剂存在下，该催化剂包含具有与碳酸酯和C 6-10链烷酸酯的抗衡离子的钙 不含活性氢原子的溶剂或分散剂。 制备的聚醚多元醇的当量重量优选为约1000至约20,000，多分散性为1.3或更低，残留催化剂含量为约0至约2000ppm（ppm）。 在另一个实施方案中，本发明是制备这种高分子量聚醚多元醇的方法。 该方法首先在催化剂存在下使具有一个或多个活性氢原子的一种或多种化合物与一种或多种环氧烷接触。 该催化剂包括在溶剂中具有碳酸酯和C 6-10链烷酸酯的抗衡离子的钙，其中溶剂不含活性氢原子。 将混合物暴露于环氧烷与含有多于一个活性氢原子的化合物反应的条件，使得制备的聚醚多元醇的当量为约1,000至约20,000，多分散度为约1.3或更小，以及 残余催化剂水平为约0至约1000（ppm）。

    Delayed-action, heat activated-urethane catalyst
    7.
    发明授权
    Delayed-action, heat activated-urethane catalyst 失效
    延迟作用，热活化 - 氨基甲酸酯催化剂

    公开(公告)号：US4041019A

    公开(公告)日：1977-08-09

    申请号：US624698

    申请日：1975-10-22

    申请人： Philip W. McGraw ,  George A. Doorakian ,  Randall C. Rains

    发明人： Philip W. McGraw ,  George A. Doorakian ,  Randall C. Rains

    IPC分类号： C08G18/16 ,  C08G18/20 ,  C08G18/14

    CPC分类号： C08G18/2027 ,  C08G18/168

    摘要： New catalysts are described for promoting the reaction of organic isocyanates with organic compounds bearing active hydrogen. These new catalysts correspond to the formula ##STR1## WHEREIN: N IS AN INTEGER OF FROM 1 TO 3; R.sub.1 is an n-valent organic radical;R.sub.2 is hydrogen, hydrocarbyl or inertly-substituted hydrocarbyl;R.sub.3 and R.sub.4 are each independently hydrogen, hydrocarbyl, inertly-substituted hydrocarbyl, or, R.sub.3 and R.sub.4 are joined to form a 5- or 6-membered carbocyclic ring. The catalysts are delayed-action, heat-activated catalysts which are particularly useful in the preparation of polyurethanes.

    摘要翻译： 描述了用于促进有机异氰酸酯与带有活性氢的有机化合物的反应的新型催化剂。 这些新的催化剂对应于公式I WHEREIN：N是从1到3的整数; R1是n价有机基团; R2是氢，烃基或惰性取代的烃基; R 3和R 4各自独立地为氢，烃基，惰性取代的烃基，或者，R 3和R 4连接形成5-或6-元碳环。 催化剂是在制备聚氨酯中特别有用的延迟作用的热活化催化剂。

    Catalyst for making polyurethanes
    10.
    发明授权
    Catalyst for making polyurethanes 失效
    制备聚氨酯的催化剂

    公开(公告)号：US4189543A

    公开(公告)日：1980-02-19

    申请号：US935233

    申请日：1978-08-21

    申请人： George A. Doorakian ,  Lawrence G. Duquette ,  Philip W. McGraw

    发明人： George A. Doorakian ,  Lawrence G. Duquette ,  Philip W. McGraw

    IPC分类号： C08G18/16 ,  C08G18/20

    CPC分类号： C08G18/2027 ,  C08G18/168

    摘要： Compounds of formulas I and II are heat-activated catalysts used in making polyurethanes. ##STR1## wherein R, R.sub.1, and R.sub.2 are each independently H, hydrocarbyl or an inertly-substituted hydrocarbyl; R.sub.3 and R.sub.4 are each independently hydrocarbyl or an inertly-substituted hydrocarbyl; and X is an anion. Upon heating, Compounds I and II catalyze the reaction and may release gaseous by-products which cause the resulting polyurethane compound to foam. For example, the catalyst, t-butyl imidazole-N-carboxylate, when heated to 120.degree. C., catalyzes the reaction between a polyol and a polyisocyanate to give a foamed polyurethane which cured in 16 minutes.

    摘要翻译： 式I和II的化合物是用于制备聚氨酯的热活化催化剂。 其中R，R 1和R 2各自独立地为H，烃基或惰性取代的烃基; R 3和R 4各自独立地为烃基或惰性取代的烃基; X为阴离子。 加热时，化合物I和II催化反应，并可能释放导致所得聚氨酯化合物发泡的气态副产物。 例如，催化剂叔丁基咪唑-N-羧酸酯在加热至120℃时催化多元醇与多异氰酸酯之间的反应，得到在16分钟内固化的发泡聚氨酯。