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公开(公告)号：US06881759B2
公开(公告)日：2005-04-19
申请号：US10806443
申请日：2004-03-23
IPC分类号： C07C29/152 , C07B61/00 , C07C29/151 , C07C31/04 , C07C27/00
CPC分类号： C07C29/1512 , Y02P20/52 , C07C31/04
摘要： The present invention is a novel process for methanol production in a liquid phase reactor from a synthesis gas comprising of hydrogen, carbon dioxide and carbon monoxide. The liquid phase reactor contains a solid catalyst suspended in methanol. In this innovation, methanol acts both as a product and as a suspension medium for the catalyst. The new innovation exploits the condensing conditions for methanol production. By operating at condensing conditions, the methanol partial pressure at equilibrium is higher than the boiling pressure of methanol at the given temperature. Hence the produced methanol of the equilibrium composition condenses creating the potential of more gas to be converted. Since equilibrium is not a limiting factor, high conversions can be obtained.
摘要翻译： 本发明是由氢，二氧化碳和一氧化碳组成的合成气体在液相反应器中生产甲醇的新方法。 液相反应器含有悬浮在甲醇中的固体催化剂。 在这项创新中，甲醇既作为产品又作为催化剂的悬浮介质。 新的创新利用甲醇生产的冷凝条件。 通过在冷凝条件下操作，平衡时的甲醇分压高于在给定温度下甲醇的沸腾压力。 因此，产生的平衡组合物的甲醇会凝结，从而产生更多的待转化气体的潜力。 由于平衡不是限制因素，因此可以获得高转化率。
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公开(公告)号：US06326523B1
公开(公告)日：2001-12-04
申请号：US09536582
申请日：2000-03-28
IPC分类号： C07C5327
CPC分类号： C07C5/42
摘要： Process for the dehydrogenation of a hydrocarbon feed comprising a step of dehydrogenating the hydrocarbon feed and a step of removing hydrogen being formed by dehydrogenation reactions, wherein the dehydrogenation and hydrogen removal steps are performed simultaneously in presence of a dehydrogenation catalyst being combined with a metal compound being reduced in presence of hydrogen.
摘要翻译： 烃原料脱氢的方法，包括使烃进料脱氢的步骤和除去由脱氢反应形成的氢的步骤，其中脱氢和除氢步骤在脱氢催化剂与金属化合物组合的存在下同时进行 在氢存在下还原。
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公开(公告)号：US07329291B2
公开(公告)日：2008-02-12
申请号：US10989306
申请日：2004-11-17
CPC分类号： C01B3/323 , C01B3/326 , C01B2203/0233 , C01B2203/1076 , C01B2203/1223 , Y02P20/52
摘要： Process for production of synthesis gas comprising carbon monoxide, carbon dioxide and hydrogen by reforming of methanol including the steps of: (a) introducing methanol in liquid phase into a reactor containing a solid methanol reforming catalyst suspended in a liquid phase of methanol and water; (b) reacting the liquid phase of methanol and water in presence of the suspended catalyst at a pressure and temperature, where methanol is maintained in the liquid phase; and (c) withdrawing from the reactor a gas phase of synthesis gas being produced during reaction of the liquid methanol and water phase.
摘要翻译： 包括以下步骤生产包括一氧化碳，二氧化碳和氢的合成气的方法包括以下步骤：（a）将液相中的甲醇引入到悬浮在甲醇和水的液相中的固体甲醇重整催化剂的反应器中; （b）在甲醇保持在液相的压力和温度下，在悬浮催化剂存在下使甲醇和水的液相反应; 和（c）从反应器中取出在液体甲醇和水相反应期间产生的合成气的气相。
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4.发明授权Method of removing metal carbonyls from gaseous streams and metal carbonyl sorbent 有权从气流和金属羰基吸附剂中除去羰基金属的方法公开(公告)号：US08728206B2
公开(公告)日：2014-05-20
申请号：US13807136
申请日：2011-05-17
IPC分类号： B01D53/02
CPC分类号： B01J20/08 , B01D53/02 , B01D53/14 , B01D53/64 , B01D2253/1124 , B01D2255/20761 , B01D2255/2092 , B01D2255/405 , B01D2256/16 , B01D2256/20 , B01D2257/60 , B01J20/0237 , B01J20/06 , B01J20/3078 , B01J21/04 , B01J23/005 , B01J23/72 , B01J37/0045 , B01J37/031 , B01J37/08 , B01J37/18
摘要： Method of removing metal carbonyls from a gaseous stream comprising contacting the metal carbonyl containing gaseous stream at elevated temperature with a particulate sorbent comprising modified copper aluminum spinel, wherein the copper aluminium spinel has been modified by a thermal treatment in a reducing atmosphere and a particulate sorbent for use in a method comprising a copper aluminium spinel being modified by thermal treatment in a reducing atmosphere at a temperature of between 250 and 500° C.
摘要翻译： 从气流中除去金属羰基化物的方法，包括使升高的温度下含有金属羰基的气流与包含改性铜铝尖晶石的颗粒吸附剂接触，其中铜铝尖晶石已经通过在还原气氛中的热处理和颗粒吸附剂 用于包括铜铝尖晶石的方法，其通过在还原气氛中在250-500℃的温度下进行热处理而被改性。
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公开(公告)号：US08677762B2
公开(公告)日：2014-03-25
申请号：US12674272
申请日：2008-08-13
IPC分类号： F02C6/18
CPC分类号： C07C29/1518 , C07C41/01 , C10G3/42 , C10G2300/1022 , C10G2400/02 , Y02E20/14 , Y02P30/20 , C07C31/04 , C07C43/043
摘要： A process for the preparation of hydrocarbon products and for the generation of power that includes the steps of (a) providing a synthesis gas having a hydrogen to carbon monoxide ratio of between 0.1 and 1; (b) contacting the synthesis gas with one or more catalysts which together catalyse a reaction of hydrogen and carbon monoxide to oxygenates comprising methanol and dimethyl ether with a dimethyl ether to methanol ratio of higher than 2 and a carbon dioxide content of above 20 mole %; (c) contacting the carbon dioxide containing oxygenate mixture at an inlet temperature of between 240° and 4000° C. with a catalyst being active in the conversion of oxygenate to higher hydrocarbons and a tail gas being rich in carbon dioxide; (d) combusting the carbon dioxide rich tail gas in a gas turbine combustion chamber to flue gas; and (e) expanding the flue gas stream through a gas turbine for the generation of power.
摘要翻译： 一种用于制备烃产物和产生动力的方法，包括以下步骤：（a）提供氢与一氧化碳比为0.1至1的合成气; （b）使合成气与一种或多种催化剂接触，这些催化剂一起催化氢和一氧化碳与包含甲醇和二甲醚的含氧化合物的反应，甲醚与甲醇的比例高于2，二氧化碳含量高于20摩尔％ ; （c）在240℃和4000℃之间的入口温度下与含氧化合物混合物的接触与在含氧化合物转化为高级烃和富含二氧化碳的尾气中具有活性的催化剂接触; （d）将燃气轮机燃烧室中的富含二氧化碳的尾气燃烧成烟道气; 和（e）通过用于发电的燃气轮机扩大烟气流。
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公开(公告)号：US08038906B2
公开(公告)日：2011-10-18
申请号：US12431240
申请日：2009-04-28
CPC分类号： C01B3/36 , C01B3/32 , C01B3/50 , C01B3/52 , C01B2203/0415 , C01B2203/047 , C01B2203/0475 , C07C41/01 , D21C11/125 , C07C43/043
摘要： A process for the adjustment of the composition of a synthesis gas produced in a high temperature black liquor gasifier. The process includes the steps of (a) generating a gasifier effluent stream from black liquor in the gasifier by a blast and optionally an atomising stream; (b) optionally quenching the gasifier effluent stream with a gas stream to form a gas quenched effluent stream; (c) quenching the gasifier effluent of step (a) or the gas quenched effluent gas stream of step (b) with a water stream to form a raw synthesis gas; (d) further cooling and cleaning and separating the raw synthesis gas to form a purified unprocessed synthesis gas with an appropriate H2/CO ratio; (e) partly converting the purified synthesis gas to dimethyl ether in a synthesis section, producing at least a product stream of DME and a hydrogen rich purge stream of processed; (f) splitting and recycling individual or combinations of split streams of the processed or the unprocessed synthesis gas to step a and/or step (b); and recycling a by-product stream of CO2 being further generated in step (e) in part or completely to step (a) and/or step (b).
摘要翻译： 用于调节在高温黑液气化器中生产的合成气的组成的方法。 该方法包括以下步骤：（a）通过鼓风和任选的雾化流从气化器中的黑液生成气化器流出物流; （b）任选地用气流骤冷气化器流出物流以形成气体骤冷流出物流; （c）用水流淬火步骤（a）的气化器流出物或步骤（b）的气体骤冷流出物气流，以形成原始合成气; （d）进一步冷却和清洗并分离原始合成气以形成具有合适H 2 / CO比的纯化未加工合成气; （e）在合成部分中部分地将纯化的合成气转化为二甲醚，至少产生DME的产物流和加氢的富氢吹扫流; （f）将经处理或未经处理的合成气的分流或分离流分离和回收到步骤a和/或步骤（b）; 并且在步骤（e）中再次产生副产物二氧化碳流，部分或完全是步骤（a）和/或步骤（b）。
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公开(公告)号：US06340003B1
公开(公告)日：2002-01-22
申请号：US09732756
申请日：2000-12-11
IPC分类号： F02B4310
CPC分类号： F02B69/04 , F02B3/06 , F02B3/08 , F02B43/10 , F02M27/02 , F02M31/08 , Y02T10/126 , Y02T10/16 , Y02T10/32
摘要： Method of operating a compression engine on dimethylether containing fuel obtained by conversion of methanol primary fuel, comprising the steps of: (a) pressurising the primary methanol fuel in its liquid form to a final engine injection pressure; (b) preheating the pressurised primary fuel by heat contained in engine exhaust gas; (c) introducing and converting the primary fuel at injection temperature of the engine and the injection pressure to dimethylether containing fuel by contact with a methanol dehydration catalyst; and (d) injection the dimethylether containing fuel at the injection pressure and temperature into the engine.
摘要翻译： 在通过甲醇初级燃料转化获得的含二甲醚的燃料上操作压缩发动机的方法，包括以下步骤：（a）将其液体形式的一级甲醇燃料加压至最终的发动机注射压力;（b）预加压的初级燃料 通过发动机废气中包含的热量;（c）通过与甲醇脱水催化剂接触，将发动机的注射温度下的一次燃料和注射压力引入和转化为含二甲醚的燃料; 和（d）将注射压力和温度下的含二甲醚的燃料喷入发动机。
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公开(公告)号：US08637580B2
公开(公告)日：2014-01-28
申请号：US13808240
申请日：2011-05-17
IPC分类号： C07C27/00
CPC分类号： C07C29/1516 , C07C29/1512 , C07C29/32 , C07C31/08 , C07C31/10 , C07C31/12 , C07C31/125
摘要： Process for the preparation of ethanol and/or higher alcohols comprising the steps of: (a) providing an alcohol synthesis gas comprising carbon monoxide and hydrogen in a molar ratio of higher than 0.5; (c) adding an amount of methanol and/or higher alcohols to the synthesis gas to obtain a synthesis gas mixture. (d) converting the synthesis gas mixture from step (c) in presence of one or more catalysts catalysing the conversion of the synthesis gas mixture into a ethanol and/or higher alcohols containing product; and (e) withdrawing the product from step (d), wherein the synthesis gas is purified by removing iron and nickel carbonyl compounds prior or after the addition methanol and/or higher alcohols to the synthesis gas and optionally (I) cooling the withdrawn product in step (e); and (g) contacting the cooled product with a hydrogenation catalyst.
摘要翻译： 制备乙醇和/或高级醇的方法包括以下步骤：（a）提供摩尔比高于0.5的一氧化碳和氢气的醇合成气; （c）向合成气中加入一定量的甲醇和/或高级醇以得到合成气体混合物。 （d）在催化合成气混合物转化为乙醇和/或高级醇的产物的一种或多种催化剂的存在下，转化来自步骤（c）的合成气混合物; 和（e）从步骤（d）中取出产物，其中通过在向合成气中加入甲醇和/或高级醇之前或之后除去铁和镍羰基化合物来纯化合成气，并且任选地（I）冷却所提取的产物 在步骤（e）中; 和（g）使冷却的产物与氢化催化剂接触。
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公开(公告)号：US08258194B2
公开(公告)日：2012-09-04
申请号：US12809016
申请日：2009-02-12
IPC分类号： C07C27/00
CPC分类号： B01J8/0285 , B01J8/067 , B01J2208/00115 , B01J2208/00123 , B01J2208/00132 , B01J2208/00141 , B01J2208/0015 , C10G2/34 , C10G2/341 , C10G2300/4006 , C10G2300/4056
摘要： Method and reactor for performing Fischer-Tropsch (FT) synthesis with controlled steam partial pressure by introducing cool points in the FT reactor, typically in form of cooled solid surfaces. At the surface, the low temperature will force condensation of the water into a liquid film. Thereby, the partial pressure of steam in the gas and reactor will not exceed significantly the vapor partial pressure at the liquid film and water from the gas stream will be removed as it is produced, i.e. steam induced deactivation is avoided. In addition, the decrease of hydrogen and carbon monoxide partial pressures due to dilution by steam will be kept low ensuring a constant high reaction rate.
摘要翻译： 通过在FT反应器中引入冷点，通常以冷却的固体表面的形式，通过控制蒸汽分压进行费 - 托（FT）合成的方法和反应器。 表面上，低温会使水冷凝成液膜。 因此，气体和反应器中的蒸汽的分压不会显着地超过液体膜处的蒸气分压，并且来自气流的水将在产生时被去除，即避免蒸汽诱导的失活。 另外，由于蒸汽稀释而导致的氢气和一氧化碳分压的降低将保持较低，从而确保恒定的高反应速率。
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公开(公告)号：US20110314834A1
公开(公告)日：2011-12-29
申请号：US12674272
申请日：2008-08-13
IPC分类号： F02C6/18
CPC分类号： C07C29/1518 , C07C41/01 , C10G3/42 , C10G2300/1022 , C10G2400/02 , Y02E20/14 , Y02P30/20 , C07C31/04 , C07C43/043
摘要： A process for the preparation of hydrocarbon products and for the generation of power comprising the steps of (a) providing a synthesis gas having a hydrogen to carbon monoxide ratio of between 0.1 and 1; (b) contacting the synthesis gas with one or more catalysts which together catalyse a reaction of hydrogen and carbon monoxide to oxygenates comprising methanol and dimethyl ether with a dimethyl ether to methanol ratio of higher than 2 and a carbon dioxide content of above 20 mole %; (c) contacting the carbon dioxide containing oxygenate mixture at an inlet temperature of between 240 and 4000 C with a catalyst being active in the conversion of oxygenate to higher hydrocarbons and a tail gas being rich in carbon dioxide; (d) combusting the carbon dioxide rich tail gas, optionally admixed with fresh carbon monoxide rich synthesis gas in a gas turbine combustion chamber to flue gas; and (e) expanding the flue gas stream through a gas turbine for the generation of power.
摘要翻译： 一种用于制备烃产物和产生动力的方法，包括以下步骤：（a）提供氢与一氧化碳比为0.1至1的合成气; （b）使合成气与一种或多种催化剂接触，这些催化剂一起催化氢和一氧化碳与包含甲醇和二甲醚的含氧化合物的反应，甲醚与甲醇的比例高于2，二氧化碳含量高于20摩尔％ ; （c）在240至4000℃的入口温度下使含二氧化碳混合物与含氧化合物转化为高级烃和富含二氧化碳的尾气有活性的催化剂接触; （d）燃烧富含二氧化碳的尾气，任选地与燃气轮机燃烧室中的新鲜的富含一氧化碳的合成气混合成烟道气; 和（e）通过用于发电的燃气轮机扩大烟气流。
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