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    Emissive polymeric materials for optoelectronic devices
    6.
    发明授权
    Emissive polymeric materials for optoelectronic devices 有权
    用于光电器件的发射聚合材料

    公开(公告)号：US07973126B2

    公开(公告)日：2011-07-05

    申请号：US11957579

    申请日：2007-12-17

    申请人： Joseph John Shiang ,  Kelly Scott Chichak ,  James Anthony Cella ,  Larry Neil Lewis ,  Kevin Henry Janora

    发明人： Joseph John Shiang ,  Kelly Scott Chichak ,  James Anthony Cella ,  Larry Neil Lewis ,  Kevin Henry Janora

    IPC分类号： C08G79/00 ,  H01L51/54 ,  C09K11/06

    CPC分类号： C08G61/12 ,  C08G2261/142 ,  C08G2261/1526 ,  C08G2261/3142 ,  C08G2261/3162 ,  H01L51/0039 ,  H01L51/5012 ,  Y10S428/917

    摘要： Polymers including at least one structural unit derived from a compound of formula I or including at least one pendant group of formula II may be used in optoelectronic devices wherein R1, R3, R4 and R6 are independently hydrogen, alkyl, alkoxy, oxaalkyl, alkylaryl, aryl, arylalkyl, heteroaryl, substituted alkyl; substituted alkoxy, substituted oxaalkyl, substituted alkylaryl, substituted aryl, substituted arylalkyl, or substituted heteroaryl; R1a is hydrogen or alkyl; R2 is alkylene, substituted alkylene, oxaalkylene, CO, or CO2; R2a is alkylene; R5 is independently at each occurrence hydrogen, alkyl, alkylaryl, aryl, arylalkyl, alkoxy, carboxy, substituted alkyl; substituted alkylaryl, substituted aryl, substituted arylalkyl, or substituted alkoxy, X is halo, triflate, —B(OR1a)2, or  located at the 2, 5- or 2, 7-positions; and L is derived from phenylpyridine, tolylpyridine, benzothienylpyridine, phenylisoquinoline, dibenzoquinozaline, fluorenylpyridine, ketopyrrole, 2-(1-naphthyl)benzoxazole)), 2-phenylbenzoxazole, 2-phenylbenzothiazole, coumarin, thienylpyridine, phenylpyridine, benzothienylpyridine, 3-methoxy-2-phenylpyridine, thienylpyridine, phenylimine, vinylpyridine, pyridylnaphthalene, pyridylpyrrole, pyridylimidazole, phenylindole, derivatives thereof or combinations thereof.

    摘要翻译： 包括至少一种衍生自式I化合物或包含至少一个式II侧基的结构单元的聚合物可用于其中R 1，R 3，R 4和R 6独立地为氢，烷基，烷氧基，氧杂烷基，烷芳基， 芳基，芳基烷基，杂芳基，取代的烷基; 取代的烷氧基，取代的氧杂烷基，取代的烷基芳基，取代的芳基，取代的芳基烷基或取代的杂芳基; R1a是氢或烷基; R2是亚烷基，取代的亚烷基，氧杂亚烷基，CO或CO 2; R2a是亚烷基; R5各自独立地为氢，烷基，烷基芳基，芳基，芳基烷基，烷氧基，羧基，取代的烷基; 取代的烷基芳基，取代的芳基，取代的芳基烷基或取代的烷氧基，X是卤素，三氟甲磺酸酯，-B（OR1a）2，或位于2,5-或2,7-位; 苯基吡啶，苯并噻吩并吡啶，二苯并喹嗪，芴基吡啶，酮吡咯，2-（1-萘基）苯并恶唑）），2-苯基苯并恶唑，2-苯基苯并噻唑，香豆素，噻吩基吡啶，苯基吡啶，苯并噻吩基吡啶，3-甲氧基 - 2-苯基吡啶，噻吩基吡啶，苯基亚胺，乙烯基吡啶，吡啶基萘，吡啶基吡咯，吡啶基咪唑，苯基吲哚，其衍生物或其组合。

    Method of making organic light emitting devices
    7.
    发明授权
    Method of making organic light emitting devices 有权
    制造有机发光装置的方法

    公开(公告)号：US07910386B2

    公开(公告)日：2011-03-22

    申请号：US11637582

    申请日：2006-12-12

    申请人： Joseph John Shiang ,  Kevin Henry Janora ,  Gautam Parthasarathy ,  James Anthony Cella ,  Kelly Scott Chichak

    发明人： Joseph John Shiang ,  Kevin Henry Janora ,  Gautam Parthasarathy ,  James Anthony Cella ,  Kelly Scott Chichak

    IPC分类号： H01L29/72

    CPC分类号： H01L51/0043 ,  H01L51/0003 ,  H01L51/0035 ,  H01L51/0039 ,  H01L51/005 ,  H01L51/0085 ,  H01L51/56 ,  Y10T428/31511

    摘要： The present invention provides a method for the preparation of organic light-emitting devices comprising a bilayer structure made by forming a first film layer comprising an electroactive material and an INP precursor material, and exposing the first film layer to a radiation source under an inert atmosphere to generate an interpenetrating network polymer composition comprising the electroactive material. At least one additional layer is disposed on the reacted first film layer to complete the bilayer structure. The bilayer structure is comprised within an organic light-emitting device comprising standard features such as electrodes and optionally one or more additional layers serving as a bipolar emission layer, a hole injection layer, an electron injection layer, an electron transport layer, a hole transport layer, exciton-hole transporting layer, exciton-electron transporting layer, a hole transporting emission layer, or an electron transporting emission layer.

    摘要翻译： 本发明提供一种制备有机发光器件的方法，其包括通过形成包含电活性材料和INP前体材料的第一膜层制备的双层结构，并在惰性气氛下将第一膜层暴露于辐射源 以产生包含电活性材料的互穿网络聚合物组合物。 在反应的第一膜层上设置至少一个附加层以完成双层结构。 双层结构包括在包括标准特征的有机发光器件中，例如电极和可选地用作双极型​​发射层的一个或多个附加层，空穴注入层，电子注入层，电子传输层，空穴传输 层，激子 - 空穴传输层，激子 - 电子传输层，空穴传输发射层或电子传输发射层。

    Optoelectronic devices with multilayered structures
    8.
    发明授权
    Optoelectronic devices with multilayered structures 有权
    具有多层结构的光电器件

    公开(公告)号：US07830081B2

    公开(公告)日：2010-11-09

    申请号：US11748195

    申请日：2007-05-14

    申请人： Larry Neil Lewis ,  Kelly Scott Chichak ,  James Anthony Cella ,  Joseph John Shiang

    发明人： Larry Neil Lewis ,  Kelly Scott Chichak ,  James Anthony Cella ,  Joseph John Shiang

    IPC分类号： C08G77/398 ,  H01J1/62

    CPC分类号： C08G77/58 ,  G02B1/043 ,  C08L83/04

    摘要： Optoelectronic devices include polysiloxanes derived from hydrosilation of an organometallic compound of formula L2MZ,wherein L and Z are independently bidentate ligands; at least one of L and Z comprises alkenyl, alkenylaryl, alkenyloxy, alkenyloxyaryl, alkynyl, alkynylaryl, alkynyloxy, alkynyloxyaryl, substituted alkenyl, substituted alkenylaryl, substituted alkenyloxy, substituted alkenyloxyaryl, substituted alkynyl, substituted alkynylaryl, substituted alkynyloxy, substituted alkynyloxyaryl, acrylate, methacrylate, or a combination thereof; and M is Zr, Nb, Mo, Tc, Ru, Rh, Pd, Ag, Cd, Hf, Ta, W, Re, Os, Ir, Pt, Au, Hg, Ga, Ge, In, Sn, Sb, Tl, Pd, Bi, Po, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, or Lu.

    摘要翻译： 光电器件包括衍生自式L2MZ的有机金属化合物的氢化硅石的聚硅氧烷，其中L和Z独立地是二齿配体; L和Z中的至少一个包括烯基，烯基芳基，烯氧基，烯基氧基芳基，炔基，炔基芳基，炔氧基，炔氧基芳基，取代的烯基，取代的烯基芳基，取代的烯氧基，取代的烯基氧基芳基，取代的炔基，取代的炔基芳基，取代的炔氧基，取代的炔氧基芳基，丙烯酸酯， 甲基丙烯酸酯或其组合; 并且M是Zr，Nb，Mo，Tc，Ru，Rh，Pd，Ag，Cd，Hf，Ta，W，Re，Os，Ir，Pt，Au，Hg，Ga，Ge，In，Sn，Sb， ，Pd，Bi，Po，La，Ce，Pr，Nd，Pm，Sm，Eu，Gd，Tb，Dy，Ho，Er，Tm，Yb或Lu。

    Hybrid electroluminescent devices
    9.
    发明授权
    Hybrid electroluminescent devices 有权
    混合电致发光器件

    公开(公告)号：US07768210B2

    公开(公告)日：2010-08-03

    申请号：US11753770

    申请日：2007-05-25

    申请人： Joseph John Shiang ,  Anil Raj Duggal ,  Joseph Darryl Michael

    发明人： Joseph John Shiang ,  Anil Raj Duggal ,  Joseph Darryl Michael

    IPC分类号： F21S4/00

    CPC分类号： H01L27/3225 ,  F21K9/00 ,  H01L27/3204 ,  H01L2251/564

    摘要： A hybrid electroluminescent (EL) device comprises at least one inorganic diode element and at least one organic EL element that are electrically connected in series. The absolute value of the breakdown voltage of the inorganic diode element is greater than the absolute value of the maximum reverse bias voltage across the series. The inorganic diode element can be a power diode, a Schottky barrier diode, or a light-emitting diode.

    摘要翻译： 混合电致发光（EL）装置包括至少一个无机二极管元件和至少一个串联电连接的有机EL元件。 无机二极管元件的击穿电压的绝对值大于该系列的最大反向偏置电压的绝对值。 无机二极管元件可以是功率二极管，肖特基势垒二极管或发光二极管。

    FUNCTIONALIZED POLYFLUORENES FOR USE IN OPTOELECTRONIC DEVICES
    10.
    发明申请
    FUNCTIONALIZED POLYFLUORENES FOR USE IN OPTOELECTRONIC DEVICES 有权
    用于光电器件的功能化聚偏氟乙烯

    公开(公告)号：US20100144976A1

    公开(公告)日：2010-06-10

    申请号：US12328805

    申请日：2008-12-05

    申请人： Kelly Scott Chichak ,  Larry Neil Lewis ,  James Anthony Cella ,  Joseph John Shiang

    发明人： Kelly Scott Chichak ,  Larry Neil Lewis ,  James Anthony Cella ,  Joseph John Shiang

    IPC分类号： C08F212/32 ,  C08F4/72

    CPC分类号： C08G61/02 ,  C08G2261/1412 ,  C08G2261/1424 ,  C08G2261/143 ,  C08G2261/148 ,  C08G2261/1526 ,  C08G2261/5242 ,  C08G2261/95 ,  C09K11/06 ,  C09K2211/185 ,  H01L51/0039 ,  H01L51/0085 ,  H05B33/14

    摘要： The present invention relates to process comprising reacting a polyfluorenes comprising at least one structural group of formula I with an iridium (III) compound of formula II wherein R1 and R2 are independently alkyl, substituted alkyl, aryl, substituted aryl or a combination thereof; R5is H or CHO; R3 and R4 are independently hydrogen, alkyl, substituted alkyl, aryl, substituted aryl or a combination thereof; R11 and R12 taken together form a substituted or unsubstituted monocyclic or bicyclic heteroaromatic ring; R13 is independently at each occurrence halo, nitro, hydroxy, amino, alkyl, aryl, arylalkyl, alkoxy, substituted alkoxy, substituted alkyl, substituted aryl, or substituted arylalkyl; Ar is aryl, heteroaryl, substituted aryl, substituted heteroaryl, or a combination thereof; X is selected from a direct bond, alky, substituted alkyl, and combinations thereof; Y is CHO or NH2; Z is CHO or NH2 where Z does not equal Y; and p is 0, 1 or 2. The invention also relates to the polyfluorenes, which are products of the reaction, and the use of the polyfluorenes in optoelectronic devices.

    摘要翻译： 本发明涉及包括使包含至少一个式I结构基团的聚芴与式II的铱（III）化合物反应的方法，其中R 1和R 2独立地为烷基，取代的烷基，芳基，取代的芳基或其组合; R5is H或CHO; R3和R4独立地是氢，烷基，取代的烷基，芳基，取代的芳基或其组合; R11和R12一起形成取代或未取代的单环或双环杂芳环; R13各自独立地为卤素，硝基，羟基，氨基，烷基，芳基，芳基烷基，烷氧基，取代的烷氧基，取代的烷基，取代的芳基或取代的芳基烷基; Ar是芳基，杂芳基，取代的芳基，取代的杂芳基或其组合; X选自直接键，烷基，取代的烷基及其组合; Y为CHO或NH2; Z是CHO或NH2，其中Z不等于Y; 并且p为0,1或2.本发明还涉及作为反应产物的聚芴以及聚芴在光电器件中的应用。