公开(公告)号：US3818059A

公开(公告)日：1974-06-18

申请号：US19752771

申请日：1971-11-10

Applicant: ROUSSEL UCLAF

Inventor： HAINAUT D ,  TOROMANOFF E ,  DEMOUTE J

IPC: C07C45/69 ,  C07C49/203 ,  C07C51/09 ,  C07C51/353 ,  C07C69/587 ,  C07F1/02 ,  C07F9/40 ,  C07F9/54 ,  C07C51/00 ,  C07C57/02 ,  C07C69/52

CPC classification number: C07F9/5428 ,  C07C45/69 ,  C07C49/203 ,  C07C51/09 ,  C07C51/353 ,  C07C69/587 ,  C07F1/02 ,  C07F9/4006 ,  C07C57/52 ,  C07C57/03

Abstract: A novel process for the preparation of alkyl 3,11-dimethyl-7ethyl-2,6,10-tridecatrienoate wherein alkyl is a hydrocarbon of one to five carbon atoms in a semi-stereospecific manner which are useful intermediates for the preparation of juvenile hormone and to novel intermediates therefor.

Abstract translation: 一种制备3,11-二甲基-7-乙基-2,2,10-十三碳三烯酸烷基酯的新方法，其中烷基是半立体特异性方式的1至5个碳原子的烃，其是制备 幼体激素及其新型中间体。

公开(公告)号：US3832353A

公开(公告)日：1974-08-27

申请号：US27510772

申请日：1972-07-25

Applicant: ROUSSEL UCLAF

Inventor： DEMOUTE J ,  HAINAUT D ,  TOROMANOFF E

IPC: A61K31/00 ,  A61M25/02 ,  C07C17/093 ,  C07D263/32 ,  C07D277/22 ,  C07D277/24 ,  C07D277/30 ,  C07F3/02 ,  C07D65/08

CPC classification number: C07D277/22 ,  A61K31/00 ,  A61M25/02 ,  C07C17/093 ,  C07D263/32 ,  C07D277/24 ,  C07D277/30 ,  C07F3/02 ,  C07C21/14

Abstract: WHEREIN N IS O OR 1 AND ESPECIALLY THE Z ISOMERS WHICH HAVE REMARKABLE INSECTICIDAL PROPERTIES AND ARE INTERMEDIATES IN THE SYNTHESIS OF JUVENILE HORMONE AND THEIR PREPARATION.
THIOPYRAN

1-(O=)N,4-(CH3-CH2-C(-CH3)=CH-CH2-CH2-),5,6-DIHYDRO-2H-

NOVEL 2H-THIAPYRANS OF THE FORMULA:

公开(公告)号：US3798236A

公开(公告)日：1974-03-19

申请号：US3798236D

申请日：1972-07-25

Applicant: ROUSSEL UCLAF

Inventor： HAINAUT D ,  TOROMANOFF E ,  DEMOUTE J

IPC: A61K31/00 ,  A61M25/02 ,  C07C17/093 ,  C07D263/32 ,  C07D277/22 ,  C07D277/24 ,  C07D277/30 ,  C07F3/02 ,  C07D65/08

CPC classification number: C07D277/22 ,  A61K31/00 ,  A61M25/02 ,  C07C17/093 ,  C07D263/32 ,  C07D277/24 ,  C07D277/30 ,  C07F3/02 ,  C07C21/14

Abstract: PRODUCTS HAVING THE FORMULA:

1-((O)N-),2-(ALK-OOC-CH=C(-CH3)-CH2-),4-(CH3-CH2-C(-CH3)=

CH-CH2-CH2-)-5,6-DIHYDRO-2H-THIOPYRAN

WHEREIN N REPRESENTS AN INTEGER FROM 0 TO 1 AND ALK REPRESENTS AN ALKYL HAVING FROM 1 TO 5 CARBON ATOMS. THESE COMPOUNDS POSSESS REMARKABLE INSECTICIDAL PROPERTIES AND ARE INTERMEDIATES IN THE SYNTHESIS OF THE JUVENILE HORMONE.