摘要:
The invention relates to mixtures comprising of(a) a polyisocyanate in the form of discrete particles having diameters of 0.1 to 150 microns which are deactivated at their surface such that from 0.5 to 20 equivalent percent of the total isocyanate groups present are deactivated; and(b) a polyol.These mixtures are useful as coatings and adhesives as well as gasket materials and are particularly useful as undercoating materials for automotive vehicles.
摘要:
A process for coating electrically conductive objects comprisingA. immersing said object as the anode of an electric current in an aqueous polyurethane dispersion prepared by(1) forming a polyurethane solution by reacting an organic polyisocyanate in the presence of an organic solvent with(a) an acrylic ester diol having a molecular weight of between 146 and 3,000;(b) an organic polyhydroxyl compound other than (a) having a molecular weight between 400 and 5,000 selected from the group consisting of polyester, polyols, polyether polyols, polycarbonates, polylactones, and mixtures thereof; and(c) a chain extender selected from the group consisting of diols, triols, diamines, aminoalcohols, having a molecular weight between 62 and 400, water, and mixtures thereof;(2) forming an anionic polyurethane addition product by reacting said polyurethane solution with a mercaptocarboxylic acid salt in the presence of a solvent;(3) adding water; and(4) removing the organic solvent, andB. passing an electric current between the anode and a cathode which is also dispersed in said dispersion, andC. irradiating said object with ultraviolet radiation or electron rays.The process can be used for coating metals such as iron, steel and aluminum.
摘要:
Dispersions of finely divided synthetic resins in plasticizers, optionally with pigments, fillers and further auxiliaries, contain 0.01 to 30% by weight, relative to the total weight of synthetic resin and plasticizer, of an isocyanate-free reaction product of a monoamine, if appropriate combined with a polyamine compound, with a monoisocyanate and/or polyisocyanate or a polyamine compound with a monoisocyanate, if appropriate combined with a polyisocyanate.
摘要:
Described are tape-type magnetic recording media (I) including a non-magnetic substrate (III), at least one film applied to the substrate and, in at least one of these films, an inorganic acicular pigment (II) suitable for use as a supporting pigment, the ratio of the mean length to the mean diameter of the pigment (II) being at least 3 and the mean modulus of elasticity of the films being not less than 15 GPa in the longitudinal direction of the tape-type recording medium (I).
摘要:
Magnetic recording media consist of a nonmagnetic base and at least one matnetizable layer which is firmly applied thereon and is based on a magnetic material finely dispersed in a binder, consisting of not less than 50% by weight of a polyurethane, and further conventional additives, wherein the magnetizable layer also contains a saturated, branched hydrocarbon.
摘要:
In magnetic recording media consisting of a non-magnetic base and, bonded on top of this, one or more magnetizable layers based on magnetic material finely dispersed in a polymer binder, a lubricant and further conventional additives, the lubricant used is a triethanolamine esterified with oleic acid.
摘要:
A process for the preparation of a magnetic recording medium by dispersing pulverulent magnetic material in a binder mixture which is dissolved in an organic solvent and essentially consists of an elastomeric polyurethane and a high molecular weight hydroxyl-containing polymer, with addition of dispersing assistants and conventional additives, applying a layer of the dispersion, to which a diisocyanate and/or polyisocyanate has first been added, to a base material and the solidifying the layer and crosslinking the binder matrix, wherein the diisocyanate and/or polyisocyanate is added to the dispersion and, before applying the dispersion to the base, from 15 to 55% of the NCO groups present react with the hydroxyl-containing polymer of the binder mixture.
摘要:
Magnetic recording media comprise a non-magnetic base which is provided with a magnetic layer consisting of finely divided anisotropic magnetic material which is dispersible in binders and additives, the binder being a mixture of (1) a high molecular weight thermoplastic linear polyurethane, (2) a polyvinylformal binder, a phenoxy resin, a cellulose ester or a vinyl chloride copolymer and (3) an OH-containing polyurethane which is crosslinked with polyisocyanates.
摘要:
Magnetic recording media which have a thin backing coating and consist of a non-magnetic flexible base and a magnetic layer which is applied to one side of the base and comprises magnetic material finely dispersed in an organic binder are produced by applying a dispersion of finely divided non-magnetizable conductive and non-conductive solids and conventional additives in a solution of a polymeric binder in an organic solvent to that side of the base which is opposite the magnetic layer by means of a knife-coater, and then drying the layer, a high molecular weight organic compound which acts as a thickener being added to the backing coating dispersion.
摘要:
The invention relates to magnetic recording media comprising a non-magnetic base and, applied thereto, a firmly adhering magnetic coating based on a finely divided magnetic pigment dispersed in a binder which contains at least 50 percent by weight of a special polyurethane elastomer.This polyurethane elastomer is a thermoplastic polyurethane which is soluble in tetrahydrofuran and free from isocyanate groups, and which has been manufactured from (A) 1 mole of one or more hydroxyl-containing polyesters and/or hydroxyl-containing polyethers of molecular weight from 600 to 4,000, (B) from 3.5 to 15 moles of a branched-chain aliphatic diol of 4 to 10 carbon atoms or a mixture of aliphatic diols of 2 to 10 carbon atoms, of which at least 50 mole percent is a branched-chain aliphatic diol of 4 to 10 carbon atoms, (C) from 0 to 1 mole, but not more than 15 mole percent of the aliphatic diols according to B, of an aliphatic polyol with from 3 to 6 OH groups and 3 to 18 carbon atoms, and (D) from 4.5 to 18 moles of a diisocyanate of 6 to 30 carbon atoms, the amount of NCO groups being approximately equivalent to the amount of OH groups of the sum of the components A to C.Magnetic recording media which contain such a polyurethane in the magnetic coating are distinguished by high surface hardness coupled with a markedly improved orientation ratio, a higher packing density and more uniform dispersion of the magnetic particles in the coating.