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    Process for the preparation of iridium acetate
    1.
    发明授权
    Process for the preparation of iridium acetate 有权
    乙酸铱的制备方法

    公开(公告)号：US07951969B2

    公开(公告)日：2011-05-31

    申请号：US11915084

    申请日：2006-05-24

    申请人： Ralf Karch ,  Bernd Kayser ,  Andreas Rivas-Nass ,  Jürgen Bodo Widmer ,  Roland Winde ,  Eileen Wörner

    发明人： Ralf Karch ,  Bernd Kayser ,  Andreas Rivas-Nass ,  Jürgen Bodo Widmer ,  Roland Winde ,  Eileen Wörner

    IPC分类号： C07F15/00 ,  B01J31/00

    CPC分类号： C07C51/412 ,  C07C53/10

    摘要： The present invention relates to a process for the preparation of indium acetate comprising the steps: (a) reacting an indium compound with an alkaline compound in a protic solvent to obtain an iridium containing precipitate, where the reaction is conducted in the presence of at least one component (i) selected from oxalic acid, a salt of oxalic acid, formic acid and a salt of formic acid, (b) reacting the precipitate in the presence of at least (i) one compound selected from oxalic acid, a salt of oxalic acid, formic acid and a salt of formic acid, and (ii) CH3CO2H and/or CH3(CO)O(CO)CH3 to give an iridium acetate containing solution. The invention also relates to indium acetate having a low halide content, to an indium containing precipitate and to uses of the iridium containing precipitate of the present invention and the iridium acetate of the present invention.

    摘要翻译： 本发明涉及一种制备醋酸铟的方法，包括以下步骤：（a）在质子溶剂中使铟化合物与碱性化合物反应，得到含铱的沉淀物，其中反应在至少存在下进行 一种选自草酸，草酸盐，甲酸和甲酸盐的组分（i），（b）在至少（i）一种选自草酸，草酸， 草酸，甲酸和甲酸盐，和（ii）CH 3 CO 2 H和/或CH 3（CO）O（CO）CH 3，得到含铱铱的溶液。 本发明还涉及具有低卤化物含量的醋酸铟，含铟沉淀物以及本发明的含铱沉淀物和本发明的乙酸铱的用途。

    Process for the Preparation of Iridium Acetate
    2.
    发明申请
    Process for the Preparation of Iridium Acetate 有权
    制备铱铱的方法

    公开(公告)号：US20100234628A1

    公开(公告)日：2010-09-16

    申请号：US11915084

    申请日：2006-05-24

    申请人： Ralf Karch ,  Bernd Kayser ,  Andreas Rivas-Nass ,  Jurgen Bodo Widmer ,  Roland Winde ,  Eileen Worner

    发明人： Ralf Karch ,  Bernd Kayser ,  Andreas Rivas-Nass ,  Jurgen Bodo Widmer ,  Roland Winde ,  Eileen Worner

    IPC分类号： C07F15/00 ,  C07C51/12 ,  C07C45/69 ,  C07F7/08 ,  C01B7/00

    CPC分类号： C07C51/412 ,  C07C53/10

    摘要： The present invention relates to a process for the preparation of indium acetate comprising the steps: (a) reacting an indium compound with an alkaline compound in a protic solvent to obtain an iridium containing precipitate, where the reaction is conducted in the presence of at least one component (i) selected from oxalic acid, a salt of oxalic acid, formic acid and a salt of formic acid, (b) reacting the precipitate in the presence of at least (i) one compound selected from oxalic acid, a salt of oxalic acid, formic acid and a salt of formic acid, and (ii) CH3CO2H and/or CH3(CO)O(CO)CH3 to give an iridium acetate containing solution. The invention also relates to indium acetate having a low halide content, to an indium containing precipitate and to uses of the iridium containing precipitate of the present invention and the iridium acetate of the present invention.

    摘要翻译： 本发明涉及一种制备醋酸铟的方法，包括以下步骤：（a）在质子溶剂中使铟化合物与碱性化合物反应，得到含铱的沉淀物，其中反应在至少存在下进行 一种选自草酸，草酸盐，甲酸和甲酸盐的组分（i），（b）在至少（i）一种选自草酸，草酸， 草酸，甲酸和甲酸盐，和（ii）CH 3 CO 2 H和/或CH 3（CO）O（CO）CH 3，得到含铱铱的溶液。 本发明还涉及具有低卤化物含量的醋酸铟，含铟沉淀物以及本发明的含铱沉淀物和本发明的乙酸铱的用途。

    METHOD FOR PREPARATION OF RUTHENIUM-INDENYLIDENE CARBENE CATALYSTS
    4.
    发明申请
    METHOD FOR PREPARATION OF RUTHENIUM-INDENYLIDENE CARBENE CATALYSTS 有权
    制备亚苄基碳二亚胺催化剂的方法

    公开(公告)号：US20110190524A1

    公开(公告)日：2011-08-04

    申请号：US13122248

    申请日：2009-10-02

    申请人： Roland Winde ,  Ralf Karch ,  Andreas Rivas-Nass ,  Angelino Doppiu ,  Gerhard Peter ,  Eileen Woerner

    发明人： Roland Winde ,  Ralf Karch ,  Andreas Rivas-Nass ,  Angelino Doppiu ,  Gerhard Peter ,  Eileen Woerner

    IPC分类号： C07F15/00

    CPC分类号： C07F15/0046

    摘要： The present invention is directed to a method for the preparation of ruthenium indenylidene carbene catalysts of the type (L)(L′)X2Ru(II)(aryl-indenylidene). The method comprises the steps of reacting the precursor compound Ru(PPh3)nX2 (n=3-4) with a propargyl alcohol derivative in an cyclic diether solvent such as 1,4-dioxane at temperatures in the range of 80 to 130° C. and reaction times of 1 to 60 minutes. Optionally, additional neutral electron donor ligands such as PCy3, phobane ligands or NHC ligands are added to the reaction mixture for ligand exchange. The method includes a precipitation step for purification, after which the product is isolated. The ruthenium-indenylidene carbene catalysts are obtained in high purity and are used as catalysts for metathesis reactions (RCM, ROMP and CM) and as precursors for the synthesis of modified ruthenium carbene catalysts.

    摘要翻译： 本发明涉及一种（L）（L'）X2Ru（II）（芳基 - 亚茚基）类型的钌亚茚基碳烯催化剂的制备方法。 该方法包括以下步骤：使前体化合物Ru（PPh 3）n X 2（n = 3-4）与炔丙醇衍生物在环状二醚溶剂如1,4-二恶烷中的反应温度范围为80-130℃ ，反应时间为1〜60分钟。 任选地，向反应混合物中加入另外的中性电子给体配体如PCy3，phobane配体或NHC配体用于配体交换。 该方法包括用于纯化的沉淀步骤，之后分离产物。 获得高纯度的钌 - 亚茚基碳烯催化剂，并用作复分解反应（RCM，ROMP和CM）的催化剂，并用作合成改性钌卡宾催化剂的前体。

    Process for preparing dienyl-ruthenium complexes
    9.
    发明授权
    Process for preparing dienyl-ruthenium complexes 有权
    二烯基钌配合物的制备方法

    公开(公告)号：US08829220B2

    公开(公告)日：2014-09-09

    申请号：US12995537

    申请日：2009-05-30

    申请人： Angelino Doppiu ,  Andreas Rivas-Nass ,  Ralf Karch ,  Roland Winde

    发明人： Angelino Doppiu ,  Andreas Rivas-Nass ,  Ralf Karch ,  Roland Winde

    IPC分类号： C07F15/00 ,  C07F17/02

    CPC分类号： C07F15/0046 ,  C07F17/02

    摘要： The present invention relates to a single-stage process for preparing dienyl-ruthenium complexes of the formula Ru(+II)(dienyl)2, wherein an Ru(II) starting compound of the formula Ru(X)p(Y)q is reacted with a diene ligand in the presence of an inorganic and/or organic base in a single-stage process. Here, polar organic solvents, preferably mixtures of polar organic solvents with water, are used. The dienyl-ruthenium complexes prepared according to the invention are used as precursors for homogeneous catalysts, for producing functional coatings and for therapeutic applications.

    摘要翻译： 本发明涉及制备式Ru（+ II）（二烯基）2的二烯基 - 钌络合物的单阶段方法，其中式Ru（X）p（Y）q的Ru（II）起始化合物为 在单级方法中在无机和/或有机碱的存在下与二烯配体反应。 这里，使用极性有机溶剂，优选极性有机溶剂与水的混合物。 根据本发明制备的二烯基 - 钌络合物用作均相催化剂的前体，用于制备功能性涂层和用于治疗应用。

    Process for preparing ruthenium(0)-olefin complexes
    10.
    发明授权
    Process for preparing ruthenium(0)-olefin complexes 有权
    制备钌（O） - 烯烃络合物的方法

    公开(公告)号：US08716509B2

    公开(公告)日：2014-05-06

    申请号：US13505796

    申请日：2010-11-11

    申请人： Angelino Doppiu ,  Andreas Rivas-Nass ,  Ralf Karch ,  Roland Winde ,  Eileen Woerner

    发明人： Angelino Doppiu ,  Andreas Rivas-Nass ,  Ralf Karch ,  Roland Winde ,  Eileen Woerner

    IPC分类号： C07F15/00 ,  C23C16/00

    CPC分类号： C23C16/18 ,  A61K31/28 ,  B01J31/00

    摘要： The present invention relates to a process for preparing ruthenium(0)-olefin complexes of the (arene)(diene)Ru(0) type by reacting a ruthenium starting compound of the formula Ru(+II)(X)p(Y)q (in which X=an anionic group, Y=an uncharged two-electron donor ligand, p=1 or 2, q=an integer from 1 to 6), with a cyclohexadiene derivative or a diene mixture comprising a cyclohexadiene derivative, in the presence of a base. In this process, the arene bound in the (arene)(diene)Ru(0) complex is formed from this cyclohexadiene derivative by oxidation. Suitable ruthenium(II) starting compounds are, for example, RuCl2(acetonitrile)4, RuCl2(pyridine)4 or RuCl2(DMSO)4. The bases used are inorganic or organic bases. The ruthenium(0)-olefin complexes prepared by the process according to the invention have a high purity and can be used as precursors for homogeneous catalysts, for preparation of functional ruthenium- or ruthenium oxide-containing layers and for therapeutic applications.

    摘要翻译： 本发明涉及一种制备（芳烃）（二烯）Ru（O）型钌（O） - 烯烃络合物的方法，通过使式钌（+ II）（X）p（Y） q（其中X =阴离子基团，Y =不带电荷的双电子供体配体，p = 1或2，q = 1至6的整数）与环己二烯衍生物或包含环己二烯衍生物的二烯混合物 一个基地的存在。 在该方法中，通过氧化由该环己二烯衍生物形成（芳烃）（二烯）Ru（O）络合物中的芳烃。 合适的钌（II）起始化合物是例如RuCl 2（乙腈）4，RuCl 2（吡啶）4或RuCl 2（DMSO）4。 使用的碱是无机或有机碱。 通过本发明方法制备的钌（O） - 烯烃络合物具有高纯度，可用作均相催化剂的前体，用于制备功能性含钌或氧化钌层并用于治疗应用。