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1.发明授权Copolymerization of 1,4-dioxan-2-one and a cyclic ester monomer producing thermal stabilized 1,4-dioxan-2-one (co)polymers 有权1,4-二恶烷-2-酮与产生热稳定化1,4-二恶烷-2-酮（共）聚合物的环酯单体的共聚合公开(公告)号：US07361727B2
公开(公告)日：2008-04-22
申请号：US11199536
申请日：2005-08-08
IPC分类号： C08G63/78
CPC分类号： C08G63/681 , C08G63/08 , C08G63/823 , C08K5/057 , C08L67/04 , Y10S521/916 , C08L2666/02
摘要： A polymerization process to derive a thermal-stabilized poly(1,4-dioxan-2-one) and cyclic ester monomer copolymer using a coordination-insertion catalyst/initiator. 1,4-dioxan-2-one and cyclic ester monomer, each containing less than 100-ppm water and having an acid value less than 0.5 mg KOH/g, and preferably less than 0.2 mg KOH/g, are copolymerized. Preferably the cyclic ester monomer is ε-caprolactone and the reaction is in an extruder.
摘要翻译： 使用配位插入催化剂/引发剂得到热稳定化的聚（1,4-二恶烷-2-酮）和环状酯单体共聚物的聚合方法。 共聚含有少于100ppm水，酸值小于0.5mg KOH / g，优选小于0.2mg KOH / g的1,4-二恶烷-2-酮和环酯单体。 优选地，环酯单体是ε-己内酯，并且反应在挤出机中。
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2.发明申请Copolymerization of 1,4-dioxan-2-one and a cyclic ester monomer producing thermal stabilized 1, 4-dioxan-2-one (co) polymers 有权产生热稳定的1,4-二恶烷-2-酮（共）聚合物的1,4-二恶烷-2-酮和环酯单体的共聚合公开(公告)号：US20060036060A1
公开(公告)日：2006-02-16
申请号：US11199536
申请日：2005-08-08
IPC分类号： C08G63/87
CPC分类号： C08G63/681 , C08G63/08 , C08G63/823 , C08K5/057 , C08L67/04 , Y10S521/916 , C08L2666/02
摘要： A polymerization process to derive a thermal-stabilized poly(1,4-dioxan-2-one) and cyclic ester monomer copolymer using a coordination-insertion catalyst/initiator. 1,4-dioxan-2-one and cyclic ester monomer, each containing less than 100-ppm water and having an acid value less than 0.5 mg KOH/g, and preferably less than 0.2 mg KOH/g, are copolymerized. Preferably the cyclic ester monomer is ε-caprolactone and the reaction is in an extruder.
摘要翻译： 使用配位插入催化剂/引发剂得到热稳定化的聚（1,4-二恶烷-2-酮）和环状酯单体共聚物的聚合方法。 共聚含有少于100ppm水，酸值小于0.5mg KOH / g，优选小于0.2mg KOH / g的1,4-二恶烷-2-酮和环酯单体。 优选地，环酯单体是ε-己内酯，并且反应在挤出机中。
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公开(公告)号：US09249253B2
公开(公告)日：2016-02-02
申请号：US12442481
申请日：2007-09-27
申请人： Philippe Dubois , Philippe Coszach , Gloria Vendrell , Philippe Degee , Michael Alexandre , Ibrahim Barakat , Jean Marie Raquez
发明人： Philippe Dubois , Philippe Coszach , Gloria Vendrell , Philippe Degee , Michael Alexandre , Ibrahim Barakat , Jean Marie Raquez
CPC分类号： C08G18/4283 , C08G18/0895 , C08G18/10 , C08G18/3206 , C08G18/3228 , C08G18/3231 , C08G18/428 , C08G2230/00 , C08G18/3225
摘要： The process of obtaining a polylactide-urethane copolymer is described which includes contacting an α, ω dihydroxyl polylactide prepolymer of general formula I wherein X is NH or O, R is an alkyl or an aryl group, n and n′ are integer numbers which are substantially the same and are in the range from 20 to 140, with a diisocyanate compound of general formula II O═C═N—R′—N═C═O wherein R′ is an alkyl or an aryl group and with an amine or an alcohol of general formula III R″X′]2 wherein R″ is an alkyl or an aryl group and X′ is NH2 or OH, and with the proviso that at least one of R or R″ is an aryl group.
摘要翻译： 描述了获得聚丙交酯 - 氨基甲酸酯共聚物的方法，该方法包括使通式I的α，ω二羟基聚丙交酯预聚物，其中X是NH或O，R是烷基或芳基，n和n'是整数， 基本相同并且在20至140的范围内，与通式II的二异氰酸酯化合物O = C = N-R'-N = C = O，其中R'为烷基或芳基，并与胺或 通式III R“X”] 2的醇，其中R“是烷基或芳基，X'是NH 2或OH，条件是R”或R“中的至少一个是芳基。
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公开(公告)号：US20100113734A1
公开(公告)日：2010-05-06
申请号：US12442478
申请日：2007-09-27
申请人： Philippe Dubois , Philippe Coszach , Gloria Vendrell , Fabrice Stassin , Caroline Jourdanne , Luc Lienard , Philippe Degee , Ibrahim Barakat , Michael Alexandre , Jean Marie Raquez
发明人： Philippe Dubois , Philippe Coszach , Gloria Vendrell , Fabrice Stassin , Caroline Jourdanne , Luc Lienard , Philippe Degee , Ibrahim Barakat , Michael Alexandre , Jean Marie Raquez
IPC分类号： C08G18/00
CPC分类号： C08G18/0895 , C08G18/244 , C08G18/428 , C08G18/73 , C08G63/08 , C08G63/6852 , C08G63/912 , C08G2230/00
摘要： A process for producing polylactide-urethane copolymers, which comprises the step of contacting a polylactide having terminal hydroxyl groups, produced by contacting at least one lactide monomer with a diol or diamine, with a diisocyanate compound optionally in the presence of a second diol or diamine in the presence of a catalytic system under polymerisation conditions characterised in that the polylactide and the polylactide-urethane copolymers are produced by reactive extrusion.
摘要翻译： 一种生产聚丙交酯 - 氨基甲酸酯共聚物的方法，其包括使具有末端羟基的聚交酯与通过使二醇或二胺与至少一种丙交酯单体接触的方法与二异氰酸酯化合物任选地在第二种二醇或二胺 在聚合条件下的催化体系存在下，其特征在于聚丙交酯和聚丙交酯 - 聚氨酯共聚物通过反应性挤出制备。
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公开(公告)号：US20100016538A1
公开(公告)日：2010-01-21
申请号：US12442481
申请日：2007-09-27
申请人： Philippe Dubois , Philippe Coszach , gloria Vendrell , Philippe Degee , Michael Alexandre , Ibrahim Barakat , Jean Marie Raquez
发明人： Philippe Dubois , Philippe Coszach , gloria Vendrell , Philippe Degee , Michael Alexandre , Ibrahim Barakat , Jean Marie Raquez
IPC分类号： C08G18/34
CPC分类号： C08G18/4283 , C08G18/0895 , C08G18/10 , C08G18/3206 , C08G18/3228 , C08G18/3231 , C08G18/428 , C08G2230/00 , C08G18/3225
摘要： A polylactide-urethane copolymer obtainable by a process, which comprises the step of contacting: an α, ω dihydroxyl polylactide prepolymer of general formula I wherein: X is NH or O, R is an alkyl or an aryl group, n and n′ are integer numbers which are substantially the same and which are comprised in the range from 20 to 140, a diisocyanate compound of general formula II O═C═N—R′—N═C═O wherein: R′ is an alkyl or an aryl group and an amine or an alcohol of general formula III R″[X′]2 wherein: R″ is an alkyl or an aryl group and X′ is NH2 or OH with the proviso that at least one of R or R″ is an aryl group
摘要翻译： 可通过以下方法获得的聚丙交酯 - 氨基甲酸酯共聚物，该方法包括使通式I的α，ω-二羟基聚丙交酯预聚物与下列步骤接触：其中：X为NH或O，R为烷基或芳基，n和n'为 基本相同且为20〜140的整数，通式II的二异氰酸酯化合物OCN-R'-NCO其中：R'为烷基或芳基，以及胺或醇 通式III R''[X'] 2其中：R“是烷基或芳基，X'是NH 2或OH，条件是R或R”中的至少一个是芳基
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公开(公告)号：US08119713B2
公开(公告)日：2012-02-21
申请号：US12525893
申请日：2008-02-01
申请人： Philippe Dubois , Marius Murariu , Michael Alexandre , Philippe Degee , Serge Bourbigot , Rene Delobel , Gaelle Fontaine , Eric Devaux
发明人： Philippe Dubois , Marius Murariu , Michael Alexandre , Philippe Degee , Serge Bourbigot , Rene Delobel , Gaelle Fontaine , Eric Devaux
IPC分类号： C08K3/30
CPC分类号： C08K3/30 , C08K3/346 , C08K2003/3045 , C08L67/04 , C08L2666/84 , C08L2666/62
摘要： A polylactide-based polymer or copolymer (PLA) compositions with improved flame retardancy properties as obtained by conventional melt-blending of PLA polyester matrix (1) with both calcium sulfate (2) and organo-modified layered silicates (OMLS) (3). Combination of CaSO4 and OMLS exhibits synergistic effects on PLA flame retardancy by both significantly increasing the time to ignition and decreasing the heat release rate per unit area, and promoting non-dripping properties. Moreover, all other properties of PLA remain almost unchanged or are improved as regards to pristine PLA, especially thermal and mechanical properties.
摘要翻译： 通过PLA聚酯基体（1）与硫酸钙（2）和有机改性层状硅酸盐（OMLS）（3）的常规熔融共混获得的具有改进的阻燃性能的聚丙交酯类聚合物或共聚物（PLA）组合物。 CaSO 4和OMLS的组合通过显着增加点火时间和降低每单位面积的放热速率以及促进非滴落性能，对PLA阻燃性具有协同效应。 此外，PLA的所有其他性能几乎保持不变，或者改善了原始PLA，特别是热和机械性能。
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公开(公告)号：US20100184894A1
公开(公告)日：2010-07-22
申请号：US12525893
申请日：2008-02-01
申请人： Philippe Dubois , Marius Murariu , Michael Alexandre , Philippe Degee , Serge Bourbigot , Rene Delobel , Gaelle Fontaine , Eric Devaux
发明人： Philippe Dubois , Marius Murariu , Michael Alexandre , Philippe Degee , Serge Bourbigot , Rene Delobel , Gaelle Fontaine , Eric Devaux
IPC分类号： C08K3/30
CPC分类号： C08K3/30 , C08K3/346 , C08K2003/3045 , C08L67/04 , C08L2666/84 , C08L2666/62
摘要： A polylactide-based polymer or copolymer (PLA) compositions with improved flame retardancy properties as obtained by conventional melt-blending of PLA polyester matrix (1) with both calcium sulfate (2) and organo-modified layered silicates (OMLS) (3). Combination of CaSO4 and OMLS exhibits synergistic effects on PLA flame retardancy by both significantly increasing the time to ignition and decreasing the heat release rate per unit area, and promoting non-dripping properties. Moreover, all other properties of PLA remain almost unchanged or are improved as regards to pristine PLA, especially thermal and mechanical properties.
摘要翻译： 通过PLA聚酯基体（1）与硫酸钙（2）和有机改性层状硅酸盐（OMLS）（3）的常规熔融共混获得的具有改进的阻燃性能的聚丙交酯类聚合物或共聚物（PLA）组合物。 CaSO 4和OMLS的组合通过显着增加点火时间和降低每单位面积的放热速率以及促进非滴落性能，对PLA阻燃性具有协同效应。 此外，PLA的所有其他性能几乎保持不变，或者改善了原始PLA，特别是热和机械性能。
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8.发明授权Marine anti-biofouling release coating of polysiloxane and cylindrical nanofiller 有权聚硅氧烷和圆柱形纳米填料的海洋抗生物污垢释放涂层公开(公告)号：US08080285B2
公开(公告)日：2011-12-20
申请号：US12444511
申请日：2007-10-18
CPC分类号： C09D5/1618 , C08K3/346 , C08L83/04 , C08L2205/14 , C09D5/1675 , C09D7/61 , C09D7/70 , C09D183/02 , C09D183/04 , Y10S977/783 , C08L83/00 , C08L2666/58 , C08K3/041
摘要： The present invention relates to the use of a composition comprising a polysiloxane-based polymer and at least one cylindrical nanofiller as a marine anti-biofouling and/or fouling release coating.
摘要翻译： 本发明涉及包含聚硅氧烷基聚合物和至少一种圆柱形纳米填料的组合物作为海洋抗生物污垢和/或防污涂层的用途。
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公开(公告)号：US20100130665A1
公开(公告)日：2010-05-27
申请号：US12444511
申请日：2007-10-18
IPC分类号： C09D5/16
CPC分类号： C09D5/1618 , C08K3/346 , C08L83/04 , C08L2205/14 , C09D5/1675 , C09D7/61 , C09D7/70 , C09D183/02 , C09D183/04 , Y10S977/783 , C08L83/00 , C08L2666/58 , C08K3/041
摘要： The present invention relates to the use of a composition comprising a polysiloxane-based polymer and at least one cylindrical nanofiller as a marine anti-biofouling and/or fouling release coating.
摘要翻译： 本发明涉及包含聚硅氧烷基聚合物和至少一种圆柱形纳米填料的组合物作为海洋抗生物污垢和/或防污涂层的用途。
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10.发明授权
公开(公告)号：US6166169A
公开(公告)日：2000-12-26
申请号：US232144
申请日：1999-01-15
CPC分类号： C08K5/13 , C08G63/78 , C08G63/823 , C08K5/524 , C08L67/00
摘要： An aliphatic polyester and/or copolyester, obtained from a polyreaction of at least one monomer from the group comprising lactides, lactones, cyclic carbonates and cyclic anhydrides. To be able to prepare the aliphatic polyester and/or copolyester a reaction mixture is used which contains at least one catalyst of the general formula (M) (X.sub.1, X.sub.2 . . . X), M being a metal selected from the group 3 to 12 of the periodic system (X.sub.1, X.sub.2 . . . X.sub.m) being a substituent selected from one of the families of alkyls, aryls, oxides, carboxylates, halogenides, alkoxides and compounds with elements from group 15 and/or 16 of the periodic system, m being an integer in the range of from 1 to 6, and n being an integer in the range of from 0 to 6, and which also contains a co-catalyst of the general formula (Y) (R.sub.1, R.sub.2 . . . R.sub.q).sub.p, Y being an element selected from the group 15 or 16 of the periodic system. (R.sub.1, R.sub.2 . . . R.sub.q) being a substituent selected from one of the families of the alkyls, aryls, oxides, halogenides, oxyalkyls, aminoalkyls, thiolkyls, phenoxides, aminioaryls, thioaryls, and q and p corresponding to the values for m and n.
摘要翻译： 由至少一种包含丙交酯，内酯，环状碳酸酯和环状酸酐的单体的多元反应获得的脂族聚酯和/或共聚酯。 为了能够制备脂肪族聚酯和/或共聚酯，使用含有至少一种通式（M）的催化剂（X1，X2 ... X）的反应混合物，M是选自组3 周期性系统（X1，X2 ... Xm）的12位是选自烷基，芳基，氧化物，羧酸盐，卤化物，醇盐和具有周期系统的第15和/或16族元素的化合物之一的取代基 m为1〜6的整数，n为0〜6的整数，并且还含有通式（Y）（R1，R2，...）的助催化剂。 R q）p，Y是选自周期系统的组15或16的元素。 （R1，R2 ... Rq）是选自烷基，芳基，氧化物，卤化物，烷氧基，氨基烷基，硫代烷基，苯氧基，氨基芳基，硫代芳基中的一个族的取代基，对应于m的值的q和p 和n。
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