摘要:
A process for producing polylactide-urethane copolymers, which comprises the step of contacting a polylactide having terminal hydroxyl groups, produced by contacting at least one lactide monomer with a diol or diamine, with a diisocyanate compound optionally in the presence of a second diol or diamine in the presence of a catalytic system under polymerisation conditions characterised in that the polylactide and the polylactide-urethane copolymers are produced by reactive extrusion.
摘要:
The process of obtaining a polylactide-urethane copolymer is described which includes contacting an α, ω dihydroxyl polylactide prepolymer of general formula I wherein X is NH or O, R is an alkyl or an aryl group, n and n′ are integer numbers which are substantially the same and are in the range from 20 to 140, with a diisocyanate compound of general formula II O═C═N—R′—N═C═O wherein R′ is an alkyl or an aryl group and with an amine or an alcohol of general formula III R″X′]2 wherein R″ is an alkyl or an aryl group and X′ is NH2 or OH, and with the proviso that at least one of R or R″ is an aryl group.
摘要翻译:描述了获得聚丙交酯 - 氨基甲酸酯共聚物的方法,该方法包括使通式I的α,ω二羟基聚丙交酯预聚物,其中X是NH或O,R是烷基或芳基,n和n'是整数, 基本相同并且在20至140的范围内,与通式II的二异氰酸酯化合物O = C = N-R'-N = C = O,其中R'为烷基或芳基,并与胺或 通式III R“X”] 2的醇,其中R“是烷基或芳基,X'是NH 2或OH,条件是R”或R“中的至少一个是芳基。
摘要:
A polylactide-urethane copolymer obtainable by a process, which comprises the step of contacting: an α, ω dihydroxyl polylactide prepolymer of general formula I wherein: X is NH or O, R is an alkyl or an aryl group, n and n′ are integer numbers which are substantially the same and which are comprised in the range from 20 to 140, a diisocyanate compound of general formula II O═C═N—R′—N═C═O wherein: R′ is an alkyl or an aryl group and an amine or an alcohol of general formula III R″[X′]2 wherein: R″ is an alkyl or an aryl group and X′ is NH2 or OH with the proviso that at least one of R or R″ is an aryl group
摘要:
A polylactide-based polymer or copolymer (PLA) compositions with improved flame retardancy properties as obtained by conventional melt-blending of PLA polyester matrix (1) with both calcium sulfate (2) and organo-modified layered silicates (OMLS) (3). Combination of CaSO4 and OMLS exhibits synergistic effects on PLA flame retardancy by both significantly increasing the time to ignition and decreasing the heat release rate per unit area, and promoting non-dripping properties. Moreover, all other properties of PLA remain almost unchanged or are improved as regards to pristine PLA, especially thermal and mechanical properties.
摘要翻译:通过PLA聚酯基体(1)与硫酸钙(2)和有机改性层状硅酸盐(OMLS)(3)的常规熔融共混获得的具有改进的阻燃性能的聚丙交酯类聚合物或共聚物(PLA)组合物。 CaSO 4和OMLS的组合通过显着增加点火时间和降低每单位面积的放热速率以及促进非滴落性能,对PLA阻燃性具有协同效应。 此外,PLA的所有其他性能几乎保持不变,或者改善了原始PLA,特别是热和机械性能。
摘要:
A polylactide-based polymer or copolymer (PLA) compositions with improved flame retardancy properties as obtained by conventional melt-blending of PLA polyester matrix (1) with both calcium sulfate (2) and organo-modified layered silicates (OMLS) (3). Combination of CaSO4 and OMLS exhibits synergistic effects on PLA flame retardancy by both significantly increasing the time to ignition and decreasing the heat release rate per unit area, and promoting non-dripping properties. Moreover, all other properties of PLA remain almost unchanged or are improved as regards to pristine PLA, especially thermal and mechanical properties.
摘要翻译:通过PLA聚酯基体(1)与硫酸钙(2)和有机改性层状硅酸盐(OMLS)(3)的常规熔融共混获得的具有改进的阻燃性能的聚丙交酯类聚合物或共聚物(PLA)组合物。 CaSO 4和OMLS的组合通过显着增加点火时间和降低每单位面积的放热速率以及促进非滴落性能,对PLA阻燃性具有协同效应。 此外,PLA的所有其他性能几乎保持不变,或者改善了原始PLA,特别是热和机械性能。
摘要:
This invention relates to a method for producing carbon nanotubes in a dispersed state. The method comprises a stage whereby polymerization is carried out from at least one so-called monomer of interest, in the presence of a catalytic system. The catalytic system comprises a co-catalyst/catalyst catalytic couple that is supported by a catalyst carrier, which corresponds to said carbon nanotubes. The invention also relates to composite materials obtained by said method, and to a catalytic system for implementing said method. The invention further relates to the use of the inventive method and products in a field of polymers, especially that of nanotechnologies.
摘要:
The present invention is related to nanocomposites comprising polymers, carbon nanotubes and layered silicate nanoparticles. The present invention also concerns methods for obtaining said nanocomposites as well as their uses.
摘要:
This invention relates to a method for producing carbon nanotubes in a dispersed state. The method comprises a stage whereby polymerization is carried out from at least one so-called monomer of interest, in the presence of a catalytic system. The catalytic system comprises a co-catalyst/catalyst catalytic couple that is supported by a catalyst carrier, which corresponds to said carbon nanotubes. The invention also relates to composite materials obtained by said method, and to a catalytic system for implementing said method. The invention further relates to the use of the inventive method and products in a field of polymers, especially that of nanotechnologies.
摘要:
The invention relates to a method for producing carbon nanotubes in a dispersed state. The method comprises a stage whereby polymerization is carried out from at least one so-called monomer of interest, in the presence of a catalytic system. The catalytic system comprises a cocatalyst/catalyst catalytic couple that is supported by a catalyst carrier, which corresponds to said carbon nanotubes. The invention also relates to composite materials obtained by said method, and to a catalytic system for implementing said method. The invention further relates to the use of the inventive method and products in the field of polymers, especially that of nanotechnologies.
摘要:
The present invention concerns a fireproof composition consisting of reticulated polysiloxane and raw carbon nanotubes with a “bound rubber” value greater than or equal to 15 grams of carbon nanotube, said carbon nanotubes representing between 0.05 and 1% of the total weight of said composition.