Abstract:
An energy-curable polymer-forming composition for making a pressure sensitive adhesive includes an unsaturated oligomer resin and an adhesive promoter which increases the peel strength of the adhesive without reducing its tack. The composition also includes a tackifier and various other optional components such as photoinitiator, chain extender, reactive diluent and the like.
Abstract:
A process for forming an emulsion of an energy-curable component by passing the energy-curable component, water and optionally a surfactant through an in-line mixing zone. The in-line mixing zone can be a static mixing zone or a high shear in-line mixing zone having a rotor-stator assembly. The emulsion can be prepared contemporaneously (just-in-time) with its use.
Abstract:
A radiation-polymerizable composition contains at least one radiation curable acrylate resin oligomer prepared by reacting an alkoxylated polyol with a first acid component which includes an ethylenically unsaturated carboxylic acid; and a rheology modifier prepared by reacting a diepoxide with a second acid component which includes an ethylenically unsaturated carboxylic acid or reactive derivative thereof in the presence of a polyamide based on a polymerized fatty acid. The ethylenically unsaturated carboxylic acids of the first and second acid components are preferably acrylic acid or methacrylic acids. The diepoxide is preferably a diglycidyl ether such as bisphenol A. Colorants such as pigments or dyes optionally may be incorporated into the composition to form a printing ink which is curable by ultraviolet (UV) or electron beam radiation.
Abstract:
An energy-curable polymer-forming composition for making a pressure sensitive adhesive includes an unsaturated oligomer resin and an adhesive promoter which increases the peel strength of the adhesive without reducing its tack. The composition also includes a tackifier and various other optional components such as photoinitiator, chain extender, reactive diluent and the like.
Abstract:
A composition comprising the reaction product of: a) a polycarboxylic member selected from the group consisting of polycarboxylic acids comprised of a diacid having more than about 12 carbon atoms and reactive derivatives thereof (e.g. alkyl esters thereof wherein the alkyl group has from 1 to 4 carbon atoms), b) an ethylenically unsaturated member selected from the group consisting of ethylenically unsaturated mono-carboxylic acids and reactive derivatives thereof, (e.g. alkyl esters thereof wherein the alkyl group thereof has from 1 to 4 carbon atoms), and c) an ethoxylated alkanetriol having an average degree of ethoxylation per hydroxyl of less than about 2 and comprised predominantly of ethoxylated alkanetriol species having one ethoxylate group per hydroxyl. This composition is useful as a polymerizable component, particularly for UV curable coatings and inks.
Abstract:
A compound having the formula:((CH.sub.2 .dbd.CR.sup.1 --C(O)O--) .sub.x R.sup.2 --(O--C(O)R.sup.3).sub.y --O--C(O)).sub.n --R.sup.4 --(C(O)OM) .sub.mwherein:R.sup.1 is hydrogen or methyl,R.sup.2 is an alkylene group or substituted alkylene group (typically having less than six carbon atoms, more typically two or three carbon atoms),R.sup.3 is an alkylene group or substituted alkylene group (typically having less than ten carbon atoms, more typically from four to six carbon atoms),R.sup.4 is an aromatic radical (e.g. the residue of an aromatic polycarboxylic polyanhydride having a functionality of one half the sum of n and m),n and m are integers from two to four (typically two or three),x is an integer from one to three, andy is an integer from one to five.Among the compounds which fall within the above formula are those in which R.sup.1 is hydrogen, R.sup.2 is an ethylene group, R.sup.3 is a pentamethylene group, and R.sup.4 is the residue of benzene tetracarboxylic dianhydride or benzophenone tetracarboxylic dianhydride, n and m are each two, x is one, and y is two. This invention also relates to a polymerizable composition comprising a compound as set forth above and to a method of coating a substrate comprising polymerizing a composition comprised of the compound set forth above while in contact with a substrate.