Radiation-polymerizable composition and printing inks containing same
    3.
    发明授权
    Radiation-polymerizable composition and printing inks containing same 失效
    可辐射聚合组合物和含有它们的印刷油墨

    公开(公告)号:US06239189B1

    公开(公告)日:2001-05-29

    申请号:US09049600

    申请日:1998-03-27

    Abstract: A radiation-polymerizable composition contains at least one radiation curable acrylate resin oligomer prepared by reacting an alkoxylated polyol with a first acid component which includes an ethylenically unsaturated carboxylic acid; and a rheology modifier prepared by reacting a diepoxide with a second acid component which includes an ethylenically unsaturated carboxylic acid or reactive derivative thereof in the presence of a polyamide based on a polymerized fatty acid. The ethylenically unsaturated carboxylic acids of the first and second acid components are preferably acrylic acid or methacrylic acids. The diepoxide is preferably a diglycidyl ether such as bisphenol A. Colorants such as pigments or dyes optionally may be incorporated into the composition to form a printing ink which is curable by ultraviolet (UV) or electron beam radiation.

    Abstract translation: 辐射聚合性组合物含有至少一种通过使烷氧基化多元醇与包含烯属不饱和羧酸的第一酸组分反应而制备的可辐射固化的丙烯酸酯树脂低聚物; 和通过在聚酰胺基于聚合的脂肪酸存在下使二环氧化物与包含烯属不饱和羧酸或其活性衍生物的第二酸组分反应制备的流变改性剂。 第一和第二酸组分的烯属不饱和羧酸优选为丙烯酸或甲基丙烯酸。 二环氧化物优选为双酚A等二缩水甘油醚。任选地,可以将颜料或染料等着色剂掺入组合物中以形成通过紫外线(UV)或电子束辐射固化的印刷油墨。

    Radiation curable polyesters
    5.
    发明授权
    Radiation curable polyesters 失效
    可辐射固化聚酯

    公开(公告)号:US06232433B1

    公开(公告)日:2001-05-15

    申请号:US08958878

    申请日:1997-10-27

    Applicant: Ramesh Narayan

    Inventor: Ramesh Narayan

    CPC classification number: C09D11/101 C08G63/21 C08G63/676 C09D167/06

    Abstract: A composition comprising the reaction product of: a) a polycarboxylic member selected from the group consisting of polycarboxylic acids comprised of a diacid having more than about 12 carbon atoms and reactive derivatives thereof (e.g. alkyl esters thereof wherein the alkyl group has from 1 to 4 carbon atoms), b) an ethylenically unsaturated member selected from the group consisting of ethylenically unsaturated mono-carboxylic acids and reactive derivatives thereof, (e.g. alkyl esters thereof wherein the alkyl group thereof has from 1 to 4 carbon atoms), and c) an ethoxylated alkanetriol having an average degree of ethoxylation per hydroxyl of less than about 2 and comprised predominantly of ethoxylated alkanetriol species having one ethoxylate group per hydroxyl. This composition is useful as a polymerizable component, particularly for UV curable coatings and inks.

    Abstract translation: 一种组合物,其包含以下物质的反应产物:a)选自由具有大于约12个碳原子的二酸组成的多元羧酸及其活性衍生物(例如其烷基具有1至4个碳原子的烷基酯) 碳原子),b)选自烯属不饱和单羧酸及其活性衍生物(例如其烷基具有1至4个碳原子的烷基酯)的烯属不饱和构件,和c)乙氧基化 每个羟基的平均乙氧基化度小于约2的烷三醇,主要由每个羟基具有一个乙氧基化物的乙氧基化烷基三醇组成。 该组合物可用作可聚合组分,特别是用于UV可固化涂料和油墨。

    Polyester oligomer acrylates
    6.
    发明授权
    Polyester oligomer acrylates 失效
    聚酯低聚物丙烯酸酯

    公开(公告)号:US5912381A

    公开(公告)日:1999-06-15

    申请号:US733682

    申请日:1996-10-17

    CPC classification number: C07C69/76 C08G63/47 C09D167/07

    Abstract: A compound having the formula:((CH.sub.2 .dbd.CR.sup.1 --C(O)O--) .sub.x R.sup.2 --(O--C(O)R.sup.3).sub.y --O--C(O)).sub.n --R.sup.4 --(C(O)OM) .sub.mwherein:R.sup.1 is hydrogen or methyl,R.sup.2 is an alkylene group or substituted alkylene group (typically having less than six carbon atoms, more typically two or three carbon atoms),R.sup.3 is an alkylene group or substituted alkylene group (typically having less than ten carbon atoms, more typically from four to six carbon atoms),R.sup.4 is an aromatic radical (e.g. the residue of an aromatic polycarboxylic polyanhydride having a functionality of one half the sum of n and m),n and m are integers from two to four (typically two or three),x is an integer from one to three, andy is an integer from one to five.Among the compounds which fall within the above formula are those in which R.sup.1 is hydrogen, R.sup.2 is an ethylene group, R.sup.3 is a pentamethylene group, and R.sup.4 is the residue of benzene tetracarboxylic dianhydride or benzophenone tetracarboxylic dianhydride, n and m are each two, x is one, and y is two. This invention also relates to a polymerizable composition comprising a compound as set forth above and to a method of coating a substrate comprising polymerizing a composition comprised of the compound set forth above while in contact with a substrate.

    Abstract translation: 具有下式的化合物:((CH 2 = CR 1 -C(O)O-)xR 2 - (OC(O)R 3)y OC(O))n -R 4 - (C(O)OM)m其中: 或甲基,R 2是亚烷基或取代的亚烷基(通常具有少于6个碳原子,更典型地为2或3个碳原子),R 3是亚烷基或取代的亚烷基(通常具有少于10个碳原子,更典型地 4至6个碳原子),R 4是芳族基团(例如具有n和m的和的一半的官能度的芳族多羧酸聚酐的残基),n和m是2至4的整数(通常为2或3个 ),x为1〜3的整数,y为1〜5的整数。 在上述式中的化合物中,R 1为氢,R 2为亚乙基,R 3为五亚甲基,R 4为苯四甲酸二酐或二苯甲酮四羧酸二酐的残基,n和m分别为2, x是一个,y是两个。 本发明还涉及一种包含上述化合物的可聚合组合物和包衣基质的方法,包括在与基底接触的同时聚合由上述化合物组成的组合物。

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