Prepolymeric polyols containing mesogenic units
    1.
    发明授权
    Prepolymeric polyols containing mesogenic units 失效
    含有介晶单元的预聚多元醇

    公开(公告)号:US5204454A

    公开(公告)日:1993-04-20

    申请号:US732566

    申请日:1991-07-19

    摘要: Prepolymer polyols containing mesogenic moieties useful as reactants for the preparation of resinous materials are disclosed. Synthesized by condensing a polyether polyol with bifunctional mesogenic diacids, or diesters, the compounds of the invention are characterized by their reasonably low melt temperature which renders them suitable as additive materials in polymeric molding compositions and as precursors for the preparation of resinous materials.The liquid crystalline properties of the prepolymers of the invention were found to depend on the type and molecular weight of the glycols and on the molar ratio between the glycols and the mesogenic reactant.

    摘要翻译: 公开了含有用作制备树脂材料的反应物的介晶部分的预聚物多元醇。 通过将聚醚多元醇与双官能介晶二酸或二酯缩合合成,本发明的化合物的特征在于它们合适的低熔融温度,使其适合作为聚合物模塑组合物中的添加剂材料和用作制备树脂材料的前体。 发现本发明的预聚物的液晶性质取决于二醇的类型和分子量以及二元醇与介晶反应物之间的摩尔比。

    Process for the preparation of a block oligocarbonate
    3.
    发明授权
    Process for the preparation of a block oligocarbonate 失效
    制备低聚碳酸酯嵌段的方法

    公开(公告)号:US5294729A

    公开(公告)日:1994-03-15

    申请号:US97743

    申请日:1993-07-27

    IPC分类号: C07C69/96 C07C68/06

    CPC分类号: C07C69/96

    摘要: A process for preparing a block oligocarbonate is disclosed. The oligocarbonate conforms to ##STR1## where R denotes hydrogen or ##STR2## and where A denotes an aromatic carbonate structure conforming to ##STR3## where Ar is an aromatic radical, n is 2-6 and where B is the residue of an aliphatic polyol is disclosed. In the process a high molecular weight aromatic polycarbonate is reacted, in the melt and in the presence of a catalyst, with an aliphatic polyol. The block oligocarbonate is useful as a reactant in a process for the preparation of copolymers.

    摘要翻译: 公开了制备低聚碳酸酯嵌段的方法。 低聚碳酸酯符合RABAR或者IMAGE,其中R表示氢或“IMAGE”,其中A表示符合的芳族碳酸酯结构,其中Ar是芳族基团,n是2-6,其中B是 公开了脂族多元醇。 在此过程中,高分子量芳族聚碳酸酯在熔体和催化剂存在下与脂族多元醇反应。 在制备共聚物的方法中,低聚碳酸酯嵌段可用作反应物。

    Coated substrates having an ultrathin, single-layer or multilayer
coating, a process for their production and polyesters as intermediate
products for the coated substrates
    4.
    发明授权
    Coated substrates having an ultrathin, single-layer or multilayer coating, a process for their production and polyesters as intermediate products for the coated substrates 失效
    具有超薄,单层或多层涂层的涂布基材,其制备方法和聚酯作为涂布基材的中间产品

    公开(公告)号:US5030516A

    公开(公告)日:1991-07-09

    申请号:US404727

    申请日:1989-09-08

    摘要: Coated substrates having an ultrathin, single-layer or multilayer coating of organic polymer material have been found, in which coated substrates the polymer used is a polyester of the structure ##STR1## wherein A is the skeleton of an aliphatic, araliphatic or aromatic diol,B is the skeleton of an aliphatic, araliphatic or aromatic dicarboxylic acid,n assumes values from 2 to 80 andat least one of the substituents R.sup.1 to R.sup.4 represents an aliphatic radical having an essentially normal chain and the other radicals in each case denote hydrogen or methyl, the aliphatic radical having at least 8 C atoms and it being possible for bonding of the aliphatic radical having an essentially normal chain to the skeleton A or B also to take place via groups containing heteroatoms, and, where there are two aliphatic radicals having an essentially normal chain on one skeleton, these radicals are identical, and furthermore R.sup.1 and R.sup.2 together and R.sup.3 and R.sup.4 together may form an alkylene chain.Such coated substrates can be produced by the Langmuir-Blodgett technique. The stated polyesters are novel intermediate products for these coated substrates.

    摘要翻译: 已经发现具有超薄,单层或多层有机聚合物材料涂层的涂布基材,其中涂覆的基材所使用的聚合物是结构式(I)的聚酯,其中A是脂族,芳脂族或 芳族二醇,B是脂族,芳脂族或芳族二羧酸的骨架,n假定为2至80的值,并且至少一个取代基R 1至R 4表示具有基本上正常链的脂族基团,并且在每种情况下其它基团 表示氢或甲基,具有至少8个C原子的脂族基团,并且具有基本上正常链的脂族基团与骨架A或B的键合也可以通过含有杂原子的基团进行,并且其中存在两个 在一个骨架上具有基本上正常链的脂族基团,这些基团是相同的,此外,R 1和R 2一起以及R 3和R 4一起可以形成亚烷基链。 这种涂覆的基材可以通过Langmuir-Blodgett技术生产。 所述聚酯是这些涂覆的基材的新型中间产物。

    Aromatic polyethers containing azo groups
    5.
    发明授权
    Aromatic polyethers containing azo groups 失效
    含有偶氮基团的芳香族聚醚

    公开(公告)号:US5064929A

    公开(公告)日:1991-11-12

    申请号:US531188

    申请日:1990-05-31

    IPC分类号: C08G65/40 G02F1/361

    CPC分类号: C08G65/4012 G02F1/3616

    摘要: A dihalobenzenoid compound is reacted with a dihydric phenol containing an azo group in the presence of a base, an organic solvent and an azeotrope former. Dihydric phenols which do not contain azo groups may also be included in the reaction mixture. This reaction is generally carried out at a temperature of from about 20.degree. to about 250.degree. C. under an inert atmosphere. The polyether obtained is represented by the formula[--O--[E--O].sub.z --E'].sub.x [O--E"--O--E'--].sub.yin which E, E', E", x, y and z have the meaning specified herein.

    摘要翻译: 在碱,有机溶剂和共沸物的存在下,使二卤代苯化合物与含有偶氮基的二元酚反应。 不含偶氮基的二元酚也可以包括在反应混合物中。 该反应通常在惰性气氛下在约20℃至约250℃的温度下进行。 获得的聚醚由式[-O- [EO] z -E'] x [O-E“-O-E' - ] y表示,其中E,E',E”,x,y和 z具有本文规定的含义。

    Coated supports with ultra-thin, single-layer or multi-layer coating,
process for their production and polyurethanes as intermediates for the
coated supports
    6.
    发明授权
    Coated supports with ultra-thin, single-layer or multi-layer coating, process for their production and polyurethanes as intermediates for the coated supports 失效
    具有超薄,单层或多层涂层的涂层支撑,其生产工艺和聚氨酯作为涂层支架的中间体

    公开(公告)号:US4978732A

    公开(公告)日:1990-12-18

    申请号:US387748

    申请日:1989-08-01

    摘要: Coated supports with ultra-thin, single-layer or multi-layer coating of organic polymer material have been found, in which, as polymer, polyurethanes of the structure ##STR1## are used in which A is the skeleton of an aliphatic, araliphatic or aromatic diol,B is the skeleton of an aliphatic, araliphatic or aromatic diisocyanate,n assumes values from 2 to 150 andat least one of the substituents R.sup.1 to R.sup.4 represents an essentially normal-chain aliphatic radical and the others in each case denote hydrogen, the aliphatic radical having at least 4 carbon atoms and the number of carbon atoms from the terminal methyl group of the aliphatic radical via the skeleton A or B up to the urethane linkage being 6 to 40, and it being further possible for R.sup.1 and R.sup.2 jointly to form an alkylene chain and for R.sup.3 and R.sup.4 jointly to form an alkylene chain. Coated supports of this type may be produced by the Langmuir-Blodgett technique. The polyurethanes mentioned are novel intermediates for these coated supports.

    摘要翻译: 已经发现具有超薄,单层或多层有机聚合物材料涂层的涂层载体,其中作为聚合物,使用结构式(I)的聚氨酯,其中A是脂族的骨架 ,芳脂族或芳族二醇,B是脂族,芳脂族或芳族二异氰酸酯的骨架,n假定为2至150,并且至少一个取代基R 1至R 4表示基本上正链的脂族基团,而在每种情况下 表示氢,具有至少4个碳原子的脂族基团和通过骨架A或B从脂肪族基团的末端甲基到氨基甲酸酯键的碳原子数为6〜40,并且还可以为R 1 和R2共同形成亚烷基链,R3和R4共同形成亚烷基链。 这种类型的涂层支撑可以通过Langmuir-Blodgett技术生产。 所提及的聚氨酯是这些涂覆的载体的新型中间体。