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    CATALYTIC CRACKING PROCESS OF A STREAM OF HYDROCARBONS FOR MAXIMIZATION OF LIGHT OLEFINS
    3.
    发明申请
    CATALYTIC CRACKING PROCESS OF A STREAM OF HYDROCARBONS FOR MAXIMIZATION OF LIGHT OLEFINS 有权
    用于最大化烯烃的烃流的催化裂化过程

    公开(公告)号：US20110270009A1

    公开(公告)日：2011-11-03

    申请号：US13058813

    申请日：2009-11-23

    申请人： Aline Barbosa Junqueira de Souza ,  Marcelo Maciel Pereira ,  Lam Yiu Lau ,  Janaina Gorne ,  Andrea de Rezende Pinho

    发明人： Aline Barbosa Junqueira de Souza ,  Marcelo Maciel Pereira ,  Lam Yiu Lau ,  Janaina Gorne ,  Andrea de Rezende Pinho

    IPC分类号： C07C4/02

    CPC分类号： C10G11/05 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2400/20

    摘要： A process is described for maximization of light olefins, preferably ethylene, by the catalytic cracking of feeds of saturated hydrocarbons, with molecular size in the range from 4 to 6 carbon atoms. The process uses a catalyst based on a zeolite of type ZSM-5 with low sodium content and modified with nickel, with concentration by weight of nickel, expressed in the form of oxide, in the range from 0.1% to 20% relative to the weight of zeolite in the catalyst, and operating conditions that involve a temperature between 400° C. and 650° C. and feed partial pressure between 0.1 and 1.0 MPa, so that the product recovered is rich in light olefins, with ethylene/propylene ratio in the range from 0.25 to 2.00.

    摘要翻译： 描述了通过分子尺寸在4至6个碳原子的饱和烃的进料的催化裂化来最大化轻质烯烃（优选乙烯）的方法。 该方法使用基于具有低钠含量并且用镍改性的ZSM-5型沸石的催化剂，以镍的重量计，以氧化物的形式表示，其重量相对于重量为0.1％至20％ 的催化剂中的沸石，以及涉及温度在400℃和650℃之间并且进料分压在0.1和1.0MPa之间的操作条件，使得回收的产物富含轻质烯烃，乙烯/丙烯比率 范围从0.25到2.00。

    METHOD OF PRODUCTION OF LIGHT OLEFINS IN CATALYTIC CRACKING UNITS WITH ENERGY DEFICIENCY
    4.
    发明申请
    METHOD OF PRODUCTION OF LIGHT OLEFINS IN CATALYTIC CRACKING UNITS WITH ENERGY DEFICIENCY 审中-公开
    具有能量缺乏的催化裂化装置中生产轻质烯烃的方法

    公开(公告)号：US20110266197A1

    公开(公告)日：2011-11-03

    申请号：US13059606

    申请日：2009-08-28

    申请人： Andrea de Rezende Pinho ,  Lam Yiu Lau

    发明人： Andrea de Rezende Pinho ,  Lam Yiu Lau

    IPC分类号： C10G11/04 ,  C10G11/00

    CPC分类号： C10G11/02 ,  C10G11/05 ,  C10G11/18

    摘要： The present invention relates to a method of production of light olefins, with the objective of maximizing the production of propylene and in particular ethylene by the use of a special catalyst containing high-silica zeolite, whose composition also includes a dehydrogenating metal, so as to generate light olefins and appreciable deposition of coke on the catalyst. Gains in selectivity for light olefins are observed, and at the same time the energy deficiency of catalytic cracking in petrochemical operations with light hydrocarbons is minimized, avoiding problems due to the need to burn heating oil in the catalyst regenerating section to make up for the energy deficit of the converter.

    摘要翻译： 本发明涉及轻质烯烃的生产方法，其目的是通过使用含有高二氧化硅沸石的特殊催化剂（其组成还包括脱氢金属）使丙烯，特别是乙烯的生产最大化，从而 在催化剂上产生轻质烯烃和可观的焦炭沉积。 观察到对轻质烯烃的选择性的增益，同时在轻烃的石油化学操作中催化裂化的能量缺乏被最小化，避免了由于需要在催化剂再生段中燃烧加热油以弥补能量的问题 转换器的赤字。

    Process for reducing the naphthenic acidity of petroleum oils or their fractions
    6.
    发明授权
    Process for reducing the naphthenic acidity of petroleum oils or their fractions 有权
    降低石油或其馏分的环烷酸性的方法

    公开(公告)号：US07507329B2

    公开(公告)日：2009-03-24

    申请号：US11076010

    申请日：2005-03-10

    申请人： Andrea de Rezende Pinho ,  Raquel Campos Cauby Coutinho ,  Mauri José Baldini Cardoso ,  Elizabeth Marques Moreira ,  Patricia Suemar Mello Duarte Da Cunha ,  Gabriele Poly Alt Pereira Naves

    发明人： Andrea de Rezende Pinho ,  Raquel Campos Cauby Coutinho ,  Mauri José Baldini Cardoso ,  Elizabeth Marques Moreira ,  Patricia Suemar Mello Duarte Da Cunha ,  Gabriele Poly Alt Pereira Naves

    IPC分类号： C10G32/00 ,  C10G32/02 ,  C10G32/04 ,  C10G31/00

    CPC分类号： C10G32/02 ,  B01D17/02 ,  B01D17/042 ,  B01D17/06

    摘要： A process for reducing the naphthenic acidity of petroleum oils or their fractions is described, said process comprising providing a hydrocarbon feed 103/203/303 having between 0.1 and 99 wt % of emulsified/dispersed water in oil, said feed containing salts and a content of naphthenic acids measured as TAN between 0.1 and 10 mg KOH/g oil; directing the said petroleum oil feed and emulsified/dispersed water towards an energy emitter device in the microwave range and submitting said feed 103/203/303 in liquid phase, under pressure between 0.7 and 4.5 MPa at temperatures between 50° C. and 350° C. to the microwave radiation, applied in the range of 1 mm to 30 cm to said feed so that the presence of salts, the applied temperature and the high dielectric constant of the water droplets make that the heat is absorbed on the spot by the water and heat said water preferentially to the oil, while the naphthenic compounds at the interface between the droplets and the oil catch said heat; effecting the decomposition of the carboxylic acids responsible for the naphthenic acidity in the petroleum feed at temperatures around 320° C. and generating CO2; separating with the aid of any known device 106/106′/112/117/208/208′/214/219/310/310′/316/321 any gas phase generated, water and oil; and recovering the hydrocarbon oil stream 108/113/119/210/215/221/312/317/323 having a reduced content in naphthenic acids. The process is designed to be applied to the reduction of naphthenic acids in feeds of petroleum oils and their fractions in the oil production step, in refineries or any industrial installation.

    摘要翻译： 描述了降低石油或其馏分的环烷酸性的方法，所述方法包括提供具有0.1至99重量％的乳化/分散水在油中的所述烃进料103/203/303，所述进料含有盐和含量 以0.1至10mg KOH / g油测量的TAN的环烷酸; 将所述石油进料和乳化/分散的水引导到微波范围内的能量发射器装置，并将液体相中的所述进料103/203/303在压力为0.7-4.5MPa之间的温度下在50℃和350℃之间 C.到微波辐射，施加在所述进料的1mm至30cm的范围内，使得盐的存在，施加的温度和水滴的高介电常数使得热量被现场吸收 水和热将水优先转化为油，而在液滴和油之间的界面处的环烷烃化合物捕获所述热量; 在约320℃的温度下进行负责石油原料中环烷酸性的羧酸的分解并产生CO 2; 借助任何已知装置106/106'/ 214/219/310/310'/ 316/321进行分离，产生任何气相，水和油; 并回收具有降低的环烷酸含量的烃油流108/113/119/210/215/221/312/317/323。 该方法设计用于在石油生产步骤，炼油厂或任何工业装置中降低石油及其馏分的进料中的环烷酸。