公开(公告)号：US07273086B2

公开(公告)日：2007-09-25

申请号：US10974384

申请日：2004-10-26

申请人： Ray T. Richter ,  Brian C. Reynolds ,  Jim N. Hart ,  Patricia A. Stewart ,  James R. Anglin ,  Larry F. Weiserman ,  Thomas J. Kasun

发明人： Ray T. Richter ,  Brian C. Reynolds ,  Jim N. Hart ,  Patricia A. Stewart ,  James R. Anglin ,  Larry F. Weiserman ,  Thomas J. Kasun

IPC分类号： B22D11/07 ,  B28B7/36

CPC分类号： C10M169/04 ,  B22C3/00 ,  B22D11/07 ,  C10M2201/02 ,  C10M2207/2815 ,  C10M2207/2835 ,  C10M2207/301 ,  C10M2207/401 ,  C10N2230/24 ,  C10N2240/404 ,  C10N2240/407 ,  C10N2250/022

摘要： In a lubricant composition suitable for use in the manufacture of aluminum alloys comprising lubricant base selected from the group consisting of solid lubricants, liquid lubricants, grease lubricants, emulsion lubricants, and dispersion lubricants, the improvement wherein the lubricant composition further comprises: an effective amount of water and surfactant. It is believed that mixing oil with water and surfactant provides a method for uniformly distributing the surface oxide at the meniscus for casting applications. Uniform distribution of the oxide at the meniscus reduces vertical fold formation that can lead to cracks in the aluminum ingot. In addition, the mixture promotes uniform heat transfer around the mold. Uniform heat transfer around the mold allows the solidifying aluminum alloy to stay in contact with the mold longer and form stronger ingot shells. A process for continuous or semi-continuous casting of aluminum alloys via the use of this lubricant composition is also disclosed.

摘要翻译： 在适用于制造铝合金的润滑剂组合物中，其包含选自固体润滑剂，液体润滑剂，润滑脂润滑剂，乳液润滑剂和分散润滑剂的润滑剂基料，其中润滑剂组合物还包括：有效量 的水和表面活性剂。 据信，混合油与水和表面活性剂提供了一种在铸造应用的弯液面均匀分布表面氧化物的方法。 在弯液面处的氧化物的均匀分布减少了可能导致铝锭裂纹的垂直折叠形成。 此外，混合物促进模具周围的均匀热传递。 模具周围的均匀传热允许固化铝合金与模具保持更长的接触并形成更强的锭壳。 还公开了通过使用该润滑剂组合物连续或半连续铸造铝合金的方法。

公开(公告)号：US20060089268A1

公开(公告)日：2006-04-27

申请号：US11196857

申请日：2005-08-04

申请人： Patricia A. Stewart ,  James R. Anglin ,  Ray T. Richter ,  Larry F. Wieserman ,  Brian C. Reynolds ,  Dean K. Vinnedge ,  Jim M. Hart

发明人： Patricia A. Stewart ,  James R. Anglin ,  Ray T. Richter ,  Larry F. Wieserman ,  Brian C. Reynolds ,  Dean K. Vinnedge ,  Jim M. Hart

IPC分类号： B22D11/07 ,  B22C3/00 ,  C10M169/04

CPC分类号： B22C3/00 ,  B22D11/07 ,  C10M169/04 ,  C10M2201/02 ,  C10M2207/2815 ,  C10M2207/2835 ,  C10M2207/301 ,  C10M2207/401 ,  C10N2230/24 ,  C10N2240/404 ,  C10N2240/407 ,  C10N2250/022

摘要： In a lubricant composition suitable for use in the manufacture of aluminum alloys comprising a lubricant base, the improvement wherein the lubricant composition further comprises: an effective amount of water, surfactant, and a high viscosity organic material having a low vapor pressure. It is believed that this mixture provides a method for uniformly distributing the surface oxide at the meniscus for casting applications and increasing meniscus stability. Uniform distribution of the oxide and increased stability at the meniscus reduces vertical fold formation that can lead to cracks in the aluminum ingot. In addition, the mixture promotes uniform heat transfer around the mold. Uniform heat transfer around the mold allows the solidifying aluminum alloy to stay in contact with the mold longer and form stronger ingot shells. A process for continuous or semi-continuous casting of aluminum alloys via the use of this lubricant composition is also disclosed.

公开(公告)号：US07111665B2

公开(公告)日：2006-09-26

申请号：US11196857

申请日：2005-08-04

申请人： Patricia A. Stewart ,  James R. Anglin ,  Ray T. Richter ,  Larry F. Wieserman ,  Brian C. Reynolds ,  Dean K. Vinnedge ,  Jim M. Hart

发明人： Patricia A. Stewart ,  James R. Anglin ,  Ray T. Richter ,  Larry F. Wieserman ,  Brian C. Reynolds ,  Dean K. Vinnedge ,  Jim M. Hart

IPC分类号： B22D11/07 ,  B28B7/36

CPC分类号： B22C3/00 ,  B22D11/07 ,  C10M169/04 ,  C10M2201/02 ,  C10M2207/2815 ,  C10M2207/2835 ,  C10M2207/301 ,  C10M2207/401 ,  C10N2230/24 ,  C10N2240/404 ,  C10N2240/407 ,  C10N2250/022

摘要： In a lubricant composition suitable for use in the manufacture of aluminum alloys comprising a lubricant base, the improvement wherein the lubricant composition further comprises: an effective amount of water, surfactant, and a high viscosity organic material having a low vapor pressure. It is believed that this mixture provides a method for uniformly distributing the surface oxide at the meniscus for casting applications and increasing meniscus stability. Uniform distribution of the oxide and increased stability at the meniscus reduces vertical fold formation that can lead to cracks in the aluminum ingot. In addition, the mixture promotes uniform heat transfer around the mold. Uniform heat transfer around the mold allows the solidifying aluminum alloy to stay in contact with the mold longer and form stronger ingot shells. A process for continuous or semi-continuous casting of aluminum alloys via the use of this lubricant composition is also disclosed.

摘要翻译： 在适用于制造包含润滑剂基底的铝合金的润滑剂组合物中，改进之处在于润滑剂组合物还包含：有效量的水，表面活性剂和具有低蒸气压的高粘度有机材料。 据信该混合物提供了用于在用于浇铸应用的弯月面均匀分布表面氧化物并增加弯液面稳定性的方法。 氧化物的均匀分布和在弯月面的增加的稳定性减少了可能导致铝锭裂纹的垂直折叠形成。 此外，混合物促进模具周围的均匀热传递。 模具周围的均匀传热允许固化铝合金与模具保持更长的接触并形成更强的锭壳。 还公开了通过使用该润滑剂组合物连续或半连续铸造铝合金的方法。

公开(公告)号：US07143812B2

公开(公告)日：2006-12-05

申请号：US11197623

申请日：2005-08-04

申请人： John Bahaychick ,  James R. Anglin ,  Patricia A. Stewart ,  Thomas A. Ferrazzoli ,  Larry F. Wieserman

发明人： John Bahaychick ,  James R. Anglin ,  Patricia A. Stewart ,  Thomas A. Ferrazzoli ,  Larry F. Wieserman

IPC分类号： B22D11/07 ,  B28B7/36

CPC分类号： B22C3/00 ,  B22D11/07 ,  C10M169/04 ,  C10M2201/02 ,  C10M2207/2815 ,  C10M2207/2835 ,  C10M2207/301 ,  C10M2207/401 ,  C10N2230/24 ,  C10N2240/404 ,  C10N2240/407 ,  C10N2250/022

摘要： In a lubricant composition suitable for use in the manufacture of aluminum alloys comprising lubricant base selected from the group consisting of solid lubricants, liquid lubricants, grease lubricants, emulsion lubricants, and dispersion lubricants, the improvement wherein the lubricant composition further comprises: an effective amount of water and surfactant or water and a compound comprising phosphates, borates, fluorides, and silicates. It is believed that mixing oil with water and surfactant or one of these compounds provides a method for uniformly distributing the surface oxide at the meniscus for casting applications, thereby reducing vertical fold formation that lead to cracks in aluminum ingots. In addition, the mixture promotes uniform heat transfer around the mold allowing the solidifying aluminum alloy to stay in contact with the mold longer and form stronger ingot shells. A process for continuous or semi-continuous casting of aluminum alloys via the use of this lubricant composition is also disclosed.

摘要翻译： 在适用于制造铝合金的润滑剂组合物中，其包含选自固体润滑剂，液体润滑剂，润滑脂润滑剂，乳液润滑剂和分散润滑剂的润滑剂基料，其中润滑剂组合物还包括：有效量 的水和表面活性剂或水以及包含磷酸盐，硼酸盐，氟化物和硅酸盐的化合物。 据信，将油与水和表面活性剂混合，或者这些化合物之一提供了一种在铸造应用的弯月面均匀分布表面氧化物的方法，从而减少导致铝锭裂纹的垂直折叠形成。 此外，该混合物促进模具周围的均匀热传递，使得固化铝合金与模具保持更长的接触并形成更强的锭壳。 还公开了通过使用该润滑剂组合物连续或半连续铸造铝合金的方法。

公开(公告)号：US06207286B1

公开(公告)日：2001-03-27

申请号：US09271423

申请日：1999-03-17

申请人： James R. Anglin ,  Donald R. Smith

发明人： James R. Anglin ,  Donald R. Smith

IPC分类号： B32B1508

CPC分类号： C10M169/04 ,  B65D1/34 ,  B65D65/42 ,  C10M105/24 ,  C10M107/10 ,  C10M111/04 ,  C10M129/10 ,  C10M137/02 ,  C10M2205/028 ,  C10M2205/0285 ,  C10M2207/023 ,  C10M2207/026 ,  C10M2207/027 ,  C10M2207/1203 ,  C10M2207/1213 ,  C10M2207/125 ,  C10M2207/1253 ,  C10M2207/129 ,  C10M2207/163 ,  C10M2207/183 ,  C10M2207/203 ,  C10M2207/243 ,  C10M2223/02 ,  C10M2223/049 ,  C10M2223/10 ,  C10N2220/02 ,  C10N2240/402 ,  C10N2240/403 ,  C10N2240/404 ,  C10N2240/405 ,  C10N2240/406 ,  C10N2240/407 ,  C10N2240/408 ,  C10N2240/409 ,  Y10T428/31681 ,  Y10T428/31692 ,  Y10T428/31696

摘要： There is disclosed a metal sheet product, more particularly formed food container stock and/or industrial sheet product, which has been treated with an ester-free, lubricant composition that is suitable for direct food contact. This composition consists essentially of: (i) about 10-90 wt. % of a polyalphaolefin; (ii) about 10-90 wt. % of an oleic acid; (iii) about 0-60 wt. % of an isostearic acid; and preferably, about 10-35 wt. % isostearic acid. It should be noted that especially good smudge testing results were observed with the presence of oleic acid. In alternative embodiments, the lubricant composition further includes: (iv) up to about 5 wt. % of an antioxidant, preferably about 0.1-3 wt. % butylated hydroxytoluene; and (v) up to about 10 wt. % of a conductivity enhancer, such as about 2-7 wt. % lecithin. When applied in total deposited weights of about 0.1-30 mg/ft2 per side, this invention produces formed food container stock or industrial sheet having improved formability and relatively lower smudge results when compared to its fatty acid and ester-containing alternatives.

摘要翻译： 公开了一种金属片制品，更具体地形成了已经用适合于直接食物接触的无酯润滑剂组合物处理过的食品容器料和/或工业片材产品。 该组合物基本上由以下组成：（i）约10-90wt。 ％的聚α-烯烃; （ii）约10-90wt。 ％的油酸; （iii）约0-60wt。 ％的异硬脂酸; 优选约10-35wt。 ％异硬脂酸。 应该注意的是，油酸的存在可以观察到特别好的污迹测试结果。 在替代实施方案中，润滑剂组合物还包括：（iv）最多约5wt。 ％的抗氧化剂，优选约0.1-3wt。 ％丁基化羟基甲苯; 和（v）至多约10wt。 ％的电导率增强剂，例如约2-7wt。 ％卵磷脂。 当以每面约0.1-30mg / ft 2的总沉积重量施用时，与其脂肪酸和含酯替代物相比，本发明生产成形食品容器原料或工业片材，其具有改进的成型性和相对较低的污迹结果。

公开(公告)号：US4343747A

公开(公告)日：1982-08-10

申请号：US213676

申请日：1980-12-05

申请人： Yumi P. Ryu ,  Gary M. Singerman ,  James R. Anglin

发明人： Yumi P. Ryu ,  Gary M. Singerman ,  James R. Anglin

IPC分类号： C07F11/00

CPC分类号： C07F11/005 ,  C10M2215/02 ,  C10M2215/04 ,  C10M2215/042 ,  C10M2215/22 ,  C10M2215/221 ,  C10M2215/225 ,  C10M2215/226 ,  C10M2215/26 ,  C10M2215/28 ,  C10M2215/30 ,  C10M2223/045 ,  C10N2210/02 ,  C10N2210/06

摘要： Quaternary ammonium thiomolybdates are prepared in a two-phase reaction system by contacting an aqueous solution of a thiomolybdate salt with a solution of a quaternary ammonium salt in a water-immiscible organic solvent. For example, mixing a solution of dicocodimethylammonium chloride in toluene with an aqueous solution of potassium thiomolybdate results in a toluene solution containing dicocodimethylammonium thiomolybdate.

摘要翻译： 通过使硫钼酸盐的水溶液与季铵盐的溶液与水不混溶的有机溶剂接触，在二相反应体系中制备季铵硫钼酸盐。 例如，将二甲基二甲基氯化铵在甲苯中的溶液与硫钼酸钾的水溶液混合，得到含有二十二烷基硫代钼酸铵的甲苯溶液。

公开(公告)号：US5672401A

公开(公告)日：1997-09-30

申请号：US548996

申请日：1995-10-27

申请人： James R. Anglin ,  Julie A. Urbanski ,  Theresa S. Knighton

发明人： James R. Anglin ,  Julie A. Urbanski ,  Theresa S. Knighton

IPC分类号： B65D25/14 ,  C10M111/04 ,  B32B15/08

CPC分类号： C10M111/04 ,  B65D25/14 ,  C10M2205/00 ,  C10M2205/02 ,  C10M2205/14 ,  C10M2205/143 ,  C10M2205/16 ,  C10M2205/163 ,  C10M2205/17 ,  C10M2205/173 ,  C10M2205/183 ,  C10M2207/2815 ,  C10M2207/2825 ,  C10M2207/2845 ,  C10M2207/2855 ,  C10M2207/40 ,  C10M2207/401 ,  C10M2207/404 ,  C10M2207/4045 ,  C10N2220/02 ,  C10N2240/40 ,  Y10T428/21 ,  Y10T428/213 ,  Y10T428/214 ,  Y10T428/215 ,  Y10T428/31681 ,  Y10T428/31692 ,  Y10T428/31714 ,  Y10T428/31801

摘要： Metal sheet product, more particularly food can stock and beer and beverage can tab, end and body stock, is treated with a lubricant made by blending a mixture consisting essentially of about 25-90 wt.% of: (i) an ester selected from the group consisting of: bis(2-ethylhexyl)sebacate (or DOS), butyl stearate, and an acetylated, partially hydrogenated soybean oil; and (ii) about 10-75 wt.% of a blend consisting essentially of: (a) about 35-65 wt.% of a polyalphaolefin; and (b) about 65-35 wt.% of a microcrystalline wax; with a balance of incidental additives and impurities. With said composition applied thereon, in preferred average thicknesses between about 3-110 mg/ft.sup.2 for can tab stock and between about 3-35 mg/ft.sup.2 for can end and body stock, the invention produces prelubricated can stock in a suitable condition for conversion without further lubrication.

摘要翻译： 金属片材产品，更特别是食品罐头和啤酒和饮料罐头，端部和主体材料，用通过混合基本上由约25-90重量％组成的混合物制成的润滑剂处理：（i）选自 由癸二酸双（2-乙基己基）酯（或DOS），硬脂酸丁酯和乙酰化的部分氢化大豆油组成的组; 和（ii）约10-75重量％的共混物，其基本上由以下组成：（a）约35-65重量％的聚α-烯烃; 和（b）约65-35重量％的微晶蜡; 平衡添加剂和杂质。 在其上施用所述组合物的情况下，对于罐头片材，优选的平均厚度为约3-110mg / ft 2，罐端部和主体坯料为约3-35mg / ft 2，本发明生产适合转化条件的预润滑罐坯料 无需进一步润滑。

公开(公告)号：US5401575A

公开(公告)日：1995-03-28

申请号：US985305

申请日：1992-12-04

申请人： James R. Anglin ,  Theresa S. Knighton ,  H. Gray Reavis, Jr.

发明人： James R. Anglin ,  Theresa S. Knighton ,  H. Gray Reavis, Jr.

IPC分类号： C10M111/02 ,  B32B15/08 ,  B32B15/04

CPC分类号： C10M111/02 ,  C10M2205/14 ,  C10M2205/143 ,  C10M2205/16 ,  C10M2205/163 ,  C10M2205/17 ,  C10M2205/173 ,  C10M2205/183 ,  C10M2207/282 ,  C10M2207/2825 ,  C10M2207/2855 ,  C10M2207/34 ,  C10N2240/402 ,  C10N2240/403 ,  C10N2240/404 ,  C10N2240/405 ,  C10N2240/406 ,  C10N2240/407 ,  C10N2240/408 ,  C10N2240/409 ,  Y10T428/273 ,  Y10T428/31678 ,  Y10T428/31699 ,  Y10T428/31714

摘要： Metal sheet product, more particularly food or beverage can tab and end stock, is treated with a lubricant blend consisting essentially of about 25-90 wt % bis(2-ethylhexyl)sebacate or DOS; about 10-75 wt % petrolatum and a balance of incidental additives and impurities prior to coiling for transport and storage. With said composition applied hereon, in preferred average thicknesses between about 10-110 mg/ft.sup.2 for aluminum can tab stock and up to about 35 mg/ft.sup.2 for aluminum can end stock, the invention produces prelubricated can stock in a suitable condition for conversion into can tabs and/or can ends without further lubrication.

摘要翻译： 用基本上由约25-90重量％的癸二酸双（2-乙基己基）酯或DOS组成的润滑剂共混物处理金属片材产品，更特别是食品或饮料罐标签和端部料料; 约10-75重量％的凡士林，以及在卷取之前的附加添加剂和杂质的余量用于运输和储存。 使用本文所用的组合物，对于铝罐薄片坯料，优选的平均厚度在约10-110mg / ft 2之间，对于铝罐端料高达约35mg / ft 2，本发明生产适合条件的预润滑罐坯料转化为 可以在没有进一步润滑的情况下接头和/或罐端。

公开(公告)号：US5584361A

公开(公告)日：1996-12-17

申请号：US417403

申请日：1995-04-05

申请人： Lawrence W. Cisko ,  James R. Anglin ,  Aladar Fricke ,  Phillip J. Pallone ,  Frank E. Savor ,  Robert C. Wallace

发明人： Lawrence W. Cisko ,  James R. Anglin ,  Aladar Fricke ,  Phillip J. Pallone ,  Frank E. Savor ,  Robert C. Wallace

IPC分类号： B23Q11/10 ,  B21J3/00 ,  B23Q11/12 ,  F16N27/00

CPC分类号： B21J3/00

摘要： Apparatus for lubricating die and/or workpiece surfaces, the apparatus including a container adapted to capture a predetermined volume of lubricant. At least one nozzle is provided for spraying the volume of lubricant onto the die/workpiece surfaces when the volume is received from the container. A first valve is connected between the nozzle and container, and a reservoir of lubricant and a pump for circulating lubricant through the container and past the first valve at a relatively low pressure is provided, the circulation of lubricant occurring during a portion of a lubricating cycle when no lubricant is sprayed onto the die/workpiece surfaces. A second valve is located between the pump and container for interrupting the flow of lubricant past the first valve, and a blocking valve is located between the container and the reservoir for interrupting the flow of lubricant from the container. A piston is located within the container and an actuator is connected to the piston for moving the same within the container to direct the captured volume of lubricant from the container to the first valve at a pressure sufficient to open the first valve.

摘要翻译： 用于润滑模具和/或工件表面的装置，该装置包括适于捕获预定体积的润滑剂的容器。 提供至少一个喷嘴，用于当容器从容器接收时，将体积的润滑剂喷射到模具/工件表面上。 第一阀连接在喷嘴和容器之间，并且提供润滑剂储存器和泵，用于使润滑剂循环通过容器并以相对低的压力经过第一阀，润滑循环在润滑循环的一部分中发生 当没有润滑剂喷涂到模具/工件表面上时。 第二阀位于泵和容器之间，用于中断润滑剂流过​​第一阀的流动，并且阻塞阀位于容器和储存器之间，用于中断润滑剂从容器的流动。 活塞位于容器内，并且致动器连接到活塞，以将其移动到容器内以将捕获的润滑剂从容器引导到第一阀，压力足以打开第一阀。

公开(公告)号：US4343746A

公开(公告)日：1982-08-10

申请号：US214972

申请日：1980-12-10

申请人： James R. Anglin ,  Yumi P. Ryu ,  Gary M. Singerman

发明人： James R. Anglin ,  Yumi P. Ryu ,  Gary M. Singerman

IPC分类号： C07F11/00 ,  C10M159/18

CPC分类号： C07F11/005 ,  C10M159/18 ,  C10M2215/02 ,  C10M2215/04 ,  C10M2215/26 ,  C10N2210/06

摘要： Novel quaternary ammonium thiomolybdates are prepared by contacting an aqueous solution of a thiomolybdate salt with a solution of a water-insoluble quaternary ammonium salt in a water-immiscible organic solvent. For example, mixing a solution of dicocodimethylammonium chloride in toluene with an aqueous solution of potassium thiomolybdate results in a toluene solution containing dicocodimethylammonium thiomolybdate. These quaternary ammonium thiomolybdates find use as additives in motor oils and greases to enhance their antifriction characteristics.

摘要翻译： 通过使硫钼酸盐的水溶液与水不溶性季铵盐的溶液与水不混溶的有机溶剂接触来制备新的硫代钼酸铵。 例如，将二甲基二甲基氯化铵在甲苯中的溶液与硫钼酸钾的水溶液混合，得到含有二十二烷基硫代钼酸铵的甲苯溶液。 这些季铵硫钼酸盐可用作机油和油脂中的添加剂，以增强其抗摩擦特性。