公开(公告)号：US09126917B2

公开(公告)日：2015-09-08

申请号：US14364316

申请日：2012-12-13

Applicant: RHODIA OPERATIONS

Inventor： Martine Vibert ,  Corine Cochennec ,  Alain Etchebarne

IPC: C07C45/80

CPC classification number: C07C45/80 ,  C07C47/565 ,  C07C47/58

Abstract: A method is described for purifying vanillin, and derivatives thereof, from an initial solution of vanillin or of a vanillin derivative in a solvent S1 containing impurities, comprising the following steps: a) a step of evaporating the solvent S1 in the presence of water from such initial solution to obtain an aqueous solution of vanillin or of a vanillin derivative; b) a step of liquid/liquid extraction by bringing the aqueous solution obtained at the end of step a) into contact with a solvent S2, at a pH of greater than 8 and less than 10, to obtain an organic phase and an aqueous phase containing vanillin or a vanillin derivative and residual solvent S2; c) a step of precipitating, at a pH between 4 and 7.5, the vanillin contained in the aqueous phase obtained at the end of step b); and d) a step of isolating the vanillin or derivative thereof.

Abstract translation: 描述了从含有杂质的溶剂S1中的香草醛或香草醛衍生物的初始溶液中纯化香草醛及其衍生物的方法，包括以下步骤：a）在水存在下蒸发溶剂S1的步骤 获得香草醛或香草醛衍生物的水溶液的初始溶液; b）通过使步骤a）中得到的水溶液在大于8且小于10的pH下与溶剂S2接触来进行液/液萃取的步骤，得到有机相和水相 含有香草醛或香草醛衍生物和残留溶剂S2; c）在步骤b）结束时获得的水相中含有的香草醛在pH4至7.5之间沉淀的步骤; 和d）分离香草醛或其衍生物的步骤。

公开(公告)号：US20150044348A1

公开(公告)日：2015-02-12

申请号：US14390580

申请日：2013-03-28

Applicant: RHODIA OPERATIONS

Inventor： Dominique Giannotta ,  Corine Cochennec ,  Tristan Colas Des Francs ,  Sandrine Bodin ,  Bernard Barlet

IPC: A23L1/226 ,  A23K1/16 ,  A23G3/36 ,  A21D13/08 ,  A23G1/32

CPC classification number: A23G3/36 ,  A21D2/14 ,  A21D13/50 ,  A21D13/80 ,  A23G1/32 ,  A23G3/346 ,  A23K20/111 ,  A23L27/204 ,  A23L27/88 ,  A23V2002/00 ,  A23G2200/00

Abstract: The present invention concerns a new use for a compound of vanillin and ethyl vanillin, in a food product and more particularly in a food product with a reduced fat and/or sugar content. The present invention also concerns food compositions comprising said compound of vanillin and ethyl vanillin.

Abstract translation: 本发明涉及在食品中更具体地在具有降低的脂肪和/或糖含量的食品中的香草醛和乙基香兰素化合物的新用途。 本发明还涉及包含所述香草醛和乙基香兰素化合物的食品组合物。

公开(公告)号：US20140323769A1

公开(公告)日：2014-10-30

申请号：US14349842

申请日：2012-10-05

Applicant: RHODIA OPERATIONS

Inventor： Laurent Garel ,  Martine Vibert ,  Corine Cochennec ,  François Metz

IPC: C07C45/64

CPC classification number: C07C45/64 ,  C07C47/575

Abstract: A method for preparing a compound of formula (I) which is a vanillin derivative, of dimer type, called 3-(4-hydroxy-3-methoxybenzyl)-4-hydroxy-5-methoxybenzaldehyde, such method comprising a reaction of vanillin and vanillyl alcohol in the presence of a base.

Abstract translation: 制备称为3-（4-羟基-3-甲氧基苄基）-4-羟基-5-甲氧基苯甲醛的二聚体型香草醛衍生物的式（I）化合物的方法，该方法包括香草醛和 香草醇在碱的存在下。

公开(公告)号：US08933274B2

公开(公告)日：2015-01-13

申请号：US14349842

申请日：2012-10-05

Applicant: Rhodia Operations

Inventor： Laurent Garel ,  Martine Vibert ,  Corine Cochennec ,  François Metz

IPC: C07C45/71 ,  C07C45/64

CPC classification number: C07C45/64 ,  C07C47/575

Abstract: A method for preparing a compound of formula (I) which is a vanillin derivative, of dimer type, called 3-(4-hydroxy-3-methoxybenzyl)-4-hydroxy-5-methoxybenzaldehyde, such method comprising a reaction of vanillin and vanillyl alcohol in the presence of a base.

Abstract translation: 制备称为3-（4-羟基-3-甲氧基苄基）-4-羟基-5-甲氧基苯甲醛的二聚体型香草醛衍生物的式（I）化合物的方法，该方法包括香草醛和 香草醇在碱的存在下。

公开(公告)号：US20140316165A1

公开(公告)日：2014-10-23

申请号：US14364316

申请日：2012-12-13

Applicant: RHODIA OPERATIONS

Inventor： Martine Vibert ,  Corine Cochennec ,  Alain Etchebarne

IPC: C07C45/80

CPC classification number: C07C45/80 ,  C07C47/565 ,  C07C47/58

Abstract: A method is described for purifying vanillin, and derivatives thereof, from an initial solution of vanillin or of a vanillin derivative in a solvent S1 containing impurities, comprising the following steps: a) a step of evaporating the solvent S1 in the presence of water from such initial solution to obtain an aqueous solution of vanillin or of a vanillin derivative; b) a step of liquid/liquid extraction by bringing the aqueous solution obtained at the end of step a) into contact with a solvent S2, at a pH of greater than 8 and less than 10, to obtain an organic phase and an aqueous phase containing vanillin or a vanillin derivative and residual solvent S2; c) a step of precipitating, at a pH between 4 and 7.5, the vanillin contained in the aqueous phase obtained at the end of step b); and d) a step of isolating the vanillin or derivative thereof.

Abstract translation: 描述了从含有杂质的溶剂S1中的香草醛或香草醛衍生物的初始溶液中纯化香草醛及其衍生物的方法，包括以下步骤：a）在水存在下蒸发溶剂S1的步骤 获得香草醛或香草醛衍生物的水溶液的初始溶液; b）通过使步骤a）中得到的水溶液在大于8且小于10的pH下与溶剂S2接触来进行液/液萃取的步骤，得到有机相和水相 含有香草醛或香草醛衍生物和残留溶剂S2; c）在步骤b）结束时获得的水相中含有的香草醛在pH4至7.5之间沉淀的步骤; 和d）分离香草醛或其衍生物的步骤。