公开(公告)号：US08772624B2

公开(公告)日：2014-07-08

申请号：US11495249

申请日：2006-07-28

申请人： Richard Allen Hayes ,  Geraldine M. Lenges ,  Steven C. Pesek ,  Sam Louis Samuels ,  Charles Anthony Smith

发明人： Richard Allen Hayes ,  Geraldine M. Lenges ,  Steven C. Pesek ,  Sam Louis Samuels ,  Charles Anthony Smith

IPC分类号： H01L31/0203

CPC分类号： B32B17/10788 ,  B32B17/10018 ,  B32B17/10036 ,  B32B17/10743 ,  B32B2327/12 ,  H01L31/0488 ,  Y02E10/50

摘要： The present invention provides a solar cell module comprising at least one encapsulant layer which has 1) a total thickness of from about 0.1 to about 20 mils and 2) at least one surface layer made of ionomers containing a finite amount of polymerized residues of α-olefins and from about 18 to about 25 wt % of polymerized residues of α,β-ethylenically unsaturated carboxylic acids. The present invention also provides a process of manufacturing the solar cell module.

摘要翻译： 本发明提供了一种太阳能电池模块，其包括至少一个密封层，其具有1）总厚度为约0.1至约20密耳，以及2）至少一个由离聚物制成的表面层，该表面层含有有限量的α- 烯烃和约18至约25重量％的α，β-烯键式不饱和羧酸的聚合残余物。 本发明还提供一种制造太阳能电池模块的方法。

公开(公告)号：US20080023063A1

公开(公告)日：2008-01-31

申请号：US11495249

申请日：2006-07-28

申请人： Richard Allen Hayes ,  Geraldine M. Lenges ,  Steven C. Pesek ,  Sam Louis Samuels ,  Charles Anthony Smith

发明人： Richard Allen Hayes ,  Geraldine M. Lenges ,  Steven C. Pesek ,  Sam Louis Samuels ,  Charles Anthony Smith

IPC分类号： H02N6/00

CPC分类号： B32B17/10788 ,  B32B17/10018 ,  B32B17/10036 ,  B32B17/10743 ,  B32B2327/12 ,  H01L31/0488 ,  Y02E10/50

摘要： The present invention provides a solar cell module comprising at least one encapsulant layer which has 1) a total thickness of from about 0.1 to about 20 mils and 2) at least one surface layer made of ionomers containing a finite amount of polymerized residues of α-olefins and from about 18 to about 25 wt % of polymerized residues of α,β-ethylenically unsaturated carboxylic acids. The present invention also provides a process of manufacturing the solar cell module.

摘要翻译： 本发明提供了一种太阳能电池组件，其包括至少一个密封层，其具有1）总厚度为约0.1至约20密耳，以及2）至少一个由离聚物制成的表面层，该表面层含有有限量的α - 烯烃和约18至约25重量％的α，β-烯属不饱和羧酸的聚合残余物。 本发明还提供一种制造太阳能电池模块的方法。

公开(公告)号：US20120085482A1

公开(公告)日：2012-04-12

申请号：US13329021

申请日：2011-12-16

申请人： Robert J. Cadwallander ,  Richard Allen Hayes ,  Steven C. Pesek ,  Sam Louis Samuels ,  Charles Anthony Smith

发明人： Robert J. Cadwallander ,  Richard Allen Hayes ,  Steven C. Pesek ,  Sam Louis Samuels ,  Charles Anthony Smith

IPC分类号： B32B37/10

CPC分类号： B32B17/10018 ,  B32B17/10036 ,  B32B17/10743 ,  B32B17/10853 ,  B32B17/10862 ,  B32B17/10972 ,  B32B2367/00

摘要： A non-autoclave process of manufacturing a glass laminate comprising: (a) providing an assembly comprising (i) a first rigid sheet layer, and (ii) an interlayer sheet comprising a copolymer comprising units from an alpha olefin and about 17 weight to about 25 weight % of units from an alpha, beta-ethylenically unsaturated carboxylic acid, groups wherein about 1 to about 100 mole % of the carboxylic acid groups are neutralized with metal ions; and (b) forming the glass laminate from the assembly without use of an autoclave comprising in sequence (i) applying vacuum to the assembly; and (ii) applying heat to the assembly while still under vacuum.

摘要翻译： 一种制造玻璃层压体的非高压釜方法，包括：（a）提供一种组件，其包括（i）第一刚性片层，和（ii）包含共聚物的中间层片，所述共聚物包含来自α-烯烃的单元和约17重量％至约 25重量％的α，β-烯属不饱和羧酸的单元，其中约1至约100摩尔％的羧酸基团被金属离子中和; 和（b）从组件形成玻璃层压体而不使用高压釜，其包括按顺序（i）向组件施加真空; 和（ii）在仍然在真空下向组件施加热量。

公开(公告)号：US07445683B2

公开(公告)日：2008-11-04

申请号：US11605118

申请日：2006-11-28

申请人： Steven C. Pesek ,  Sam Louis Samuels ,  Charles Anthony Smith ,  Robert J. Cadwallader ,  Richard Allen Hayes

发明人： Steven C. Pesek ,  Sam Louis Samuels ,  Charles Anthony Smith ,  Robert J. Cadwallader ,  Richard Allen Hayes

IPC分类号： B32B17/10

CPC分类号： B32B17/10743 ,  B32B17/10018 ,  B32B17/10036 ,  B32B17/10825 ,  C09J123/0876 ,  Y10T428/31645 ,  Y10T428/31649 ,  Y10T428/31935

摘要： The present invention is a polymeric resin composition having improved toughness, suitable for use in transparent glazing, comprising an at least partially neutralized ethylene acid copolymer metal carboxylate resin, wherein the metal carboxylate consists essentially of zinc metal counter-ions.

摘要翻译： 本发明是一种具有改进韧性的聚合物树脂组合物，其适用于透明玻璃，其包含至少部分中和的乙烯酸共聚物金属羧酸盐树脂，其中金属羧酸盐基本上由锌金属抗衡离子组成。

公开(公告)号：US07960017B2

公开(公告)日：2011-06-14

申请号：US11584988

申请日：2006-10-23

申请人： Steven C. Pesek ,  Sam Louis Samuels ,  Charles Anthony Smith ,  Stephen J. Bennison ,  Richard Allen Hayes

发明人： Steven C. Pesek ,  Sam Louis Samuels ,  Charles Anthony Smith ,  Stephen J. Bennison ,  Richard Allen Hayes

IPC分类号： B32B27/32 ,  B32B27/36 ,  B32B27/30 ,  B32B17/06

CPC分类号： B32B17/10036 ,  B32B17/10743 ,  B32B27/08 ,  B32B27/302 ,  B32B27/308 ,  B32B27/32 ,  B32B27/365 ,  C08J5/18 ,  C08J2323/08 ,  C08L23/0876 ,  C08L33/02 ,  C08L2205/02 ,  Y10T428/31507 ,  Y10T428/31855 ,  Y10T428/31935 ,  Y10T428/31938 ,  C08L2666/04 ,  C08L2666/06

摘要： The invention describes a polymeric sheet that has at least one layer that comprises an ionomer or ionomer blend that incorporates a partially neutralized alpha, beta-ethylenically unsaturated carboxylic acid component and is useful in glass laminate applications. The ionomer or ionomer blend contains one or more monovalent metal ions in an amount ranging from about 1 to about 60%, preferably about 10 to about 55%, and more preferably about 15 to about 50%, and one or more polyvalent metal ions in an amount ranging from about 40 to about 99%, preferably about 45 to about 90%, and more preferably about 50 to about 85%. This ratio range of monovalent and polyvalent metal neutralization ions provides synergistically greater adhesion to glass than found for either the monovalent or the polyvalent metal neutralization ions alone.

摘要翻译： 本发明描述了一种聚合物片材，其具有至少一层包含离聚物或离聚物共混物的层，该混合物掺入部分中和的α，β-烯键式不饱和羧酸组分，并且可用于玻璃层压应用。 离聚物或离聚物共混物含有一种或多种一价金属离子，其量为约1至约60％，优选约10至约55％，更优选约15至约50％，以及一种或多种多价金属离子 约40至约99％，优选约45至约90％，更优选约50至约85％的量。 单价和多价金属中和离子的这种比例范围提供了与单独或多价金属中和离子单独发现的对玻璃的协同增加的粘合力。

公开(公告)号：US20090126859A1

公开(公告)日：2009-05-21

申请号：US11985705

申请日：2007-11-16

申请人： Robert J. Cadwallader ,  Richard Allen Hayes ,  Steven C. Pesek ,  Sam Louis Samuels ,  Charles Anthony Smith

发明人： Robert J. Cadwallader ,  Richard Allen Hayes ,  Steven C. Pesek ,  Sam Louis Samuels ,  Charles Anthony Smith

IPC分类号： B32B17/00

CPC分类号： B32B17/10018 ,  B32B17/10036 ,  B32B17/10743 ,  B32B17/10853 ,  B32B17/10862 ,  B32B17/10972 ,  B32B2367/00

摘要： A non-autoclave process of manufacturing a glass laminate comprising: (a) providing an assembly comprising (i) a first rigid sheet layer, and (ii) an interlayer sheet comprising a copolymer comprising units from an alpha olefin and about 17 weight % to about 25 weight % of units from an alpha, beta-ethylenically unsaturated carboxylic acid, groups wherein about 1 to about 100 mole % of the carboxylic acid groups are neutralized with metal ions; and (b) forming the glass laminate from the assembly without use of an autoclave comprising in sequence (i) applying vacuum to the assembly; and (ii) applying heat to the assembly while still under vacuum.

摘要翻译： 一种制造玻璃层压体的非高压釜方法，包括：（a）提供一种组件，其包括（i）第一刚性片层，和（ii）包含共聚物的中间层片材，所述共聚物包含来自α-烯烃的单元和约17重量％ 约25重量％的来自α，β-烯属不饱和羧酸的单元，其中约1至约100摩尔％的羧酸基团被金属离子中和; 和（b）从组件形成玻璃层压体而不使用高压釜，其包括按顺序（i）向组件施加真空; 和（ii）在仍然在真空下向组件施加热量。

公开(公告)号：US07851694B2

公开(公告)日：2010-12-14

申请号：US11491341

申请日：2006-07-21

申请人： Jerrel C. Anderson ,  Richard Allen Hayes ,  Geraldine M. Lenges ,  Charles Anthony Smith

发明人： Jerrel C. Anderson ,  Richard Allen Hayes ,  Geraldine M. Lenges ,  Charles Anthony Smith

IPC分类号： H01L31/00

CPC分类号： B32B17/10587 ,  B32B17/10743 ,  B32B17/10853 ,  B32B17/10862 ,  B32B27/32 ,  H01L31/048 ,  H01L31/0481 ,  Y02E10/50

摘要： A thermoplastic film or sheet having a thickness of about 1 mil (0.026 mm) to about 20 mils (0.51 mm) containing a surface embossed layer comprising a copolymer of alpha olefin(s) with alpha, beta ethylenically unsaturated carboxylic acid comonomer(s), ionomers derived therefrom and combinations thereof useful for making solar cell laminates, wherein the surface is embossed with a pattern which provides channels for de-airing, the channels having depth of about 20 microns or less, a width of about 30 microns to about 300 microns and spaced about 0.1 mm to about 1 mm apart, and use thereof in photovoltaic cells and the manufacture thereof.

摘要翻译： 具有约1密耳（0.026mm）至约20密耳（0.51mm）的厚度的热塑性膜或片材，其包含含有α烯烃与α，β-烯属不饱和羧酸共聚单体的共聚物的表面压花层， ，衍生自其的离聚物及其组合可用于制造太阳能电池层压板，其中该表面用提供用于脱气的通道的图案压花，具有约20微米或更小的深度的通道，约30微米至约300的宽度 微米并间隔约0.1mm至约1mm，并在光伏电池中的应用及其制造。

公开(公告)号：US20080017241A1

公开(公告)日：2008-01-24

申请号：US11491341

申请日：2006-07-21

申请人： Jerrel C. Anderson ,  Richard Allen Hayes ,  Geraldine M. Lenges ,  Charles Anthony Smith

发明人： Jerrel C. Anderson ,  Richard Allen Hayes ,  Geraldine M. Lenges ,  Charles Anthony Smith

IPC分类号： H02N6/00

CPC分类号： B32B17/10587 ,  B32B17/10743 ,  B32B17/10853 ,  B32B17/10862 ,  B32B27/32 ,  H01L31/048 ,  H01L31/0481 ,  Y02E10/50

摘要： A thermoplastic film or sheet having a thickness of about 1 mil (0.026 mm) to about 20 mils (0.51 mm) containing a surface embossed layer comprising a copolymer of alpha olefin(s) with alpha, beta ethylenically unsaturated carboxylic acid comonomer(s), ionomers derived therefrom and combinations thereof useful for making solar cell laminates, wherein the surface is embossed with a pattern which provides channels for de-airing, the channels having depth of about 20 microns or less, a width of about 30 microns to about 300 microns and spaced about 0.1 mm to about 1 mm apart, and use thereof in photovoltaic cells and the manufacture thereof.

摘要翻译： 具有约1密耳（0.026mm）至约20密耳（0.51mm）的厚度的热塑性膜或片材，其包含含有α烯烃与α，β-烯属不饱和羧酸共聚单体的共聚物的表面压花层， ，衍生自其的离聚物及其组合可用于制造太阳能电池层压板，其中该表面用提供用于脱气的通道的图案压花，具有约20微米或更小的深度的通道，约30微米至约300的宽度 微米并间隔约0.1mm至约1mm，并在光伏电池中的应用及其制造。

公开(公告)号：US20120237706A1

公开(公告)日：2012-09-20

申请号：US13486511

申请日：2012-06-01

申请人： Karlheinz Hausmann ,  Richard Allen Hayes ,  Steven C. Pesek ,  W. Alexander Shaffer ,  Charles Anthony Smith

发明人： Karlheinz Hausmann ,  Richard Allen Hayes ,  Steven C. Pesek ,  W. Alexander Shaffer ,  Charles Anthony Smith

IPC分类号： C08L33/02 ,  B32B1/02

CPC分类号： C08L33/02 ,  B32B17/10045 ,  B32B17/10743 ,  B32B17/10761 ,  B32B17/10853 ,  B32B17/10981 ,  B32B2367/00 ,  C08L23/0876 ,  C08L2205/02 ,  C08L2205/025 ,  C09J123/0876 ,  F41H5/0407 ,  Y10T428/1352 ,  Y10T428/269 ,  Y10T428/31645 ,  Y10T428/31855 ,  C08L2666/04

摘要： An ionomer blend composition comprises a blend of a first ionomer and a second ionomer that is different from the first ionomer. The first ionomer is derived from a first precursor acid copolymer that has a melt flow rate of about 10 to about 4000 g/10 min and that comprises copolymerized units of an α-olefin and about 20 to about 30 wt % of copolymerized units of an α,β-ethylenically unsaturated carboxylic acid. Moreover, the first precursor acid can be neutralized to a level of about 40% to about 90% to form a sodium ionomer that has a MFR of about 0.7 to about 25 g/10 min and a freeze enthalpy that is less than about 3.0 j/g or that is not detectable, when determined by differential scanning calorimetry (DSC). A variety of articles may comprise or be produced from the ionomer blend composition, for example by injection molding.

摘要翻译： 离聚物共混物组合物包含与第一离聚物不同的第一离聚物和第二离聚物的共混物。 第一离聚物衍生自具有约10至约4000g / 10min的熔体流动速率的第一前体酸共聚物，其包含α-烯烃的共聚单元和约20至约30wt％的共聚单元 α，β-烯属不饱和羧酸。 此外，第一前体酸可被中和至约40％至约90％的水平以形成具有约0.7至约25g / 10min的MFR和小于约3.0j的冷冻焓的钠离聚物 / g，或通过差示扫描量热法（DSC）测定时不可检测。 各种制品可以包括或由离聚物共混组合物制备，例如通过注塑成型。

公开(公告)号：US20100167061A1

公开(公告)日：2010-07-01

申请号：US12610701

申请日：2009-11-02

申请人： Stephen J. Bennison ,  Richard Allen Hayes ,  Steven C. Pesek ,  W. Alexander Shaffer ,  Charles Anthony Smith

发明人： Stephen J. Bennison ,  Richard Allen Hayes ,  Steven C. Pesek ,  W. Alexander Shaffer ,  Charles Anthony Smith

IPC分类号： B32B27/32 ,  B32B27/36 ,  B32B27/08 ,  B32B27/00 ,  B32B27/40 ,  B32B17/10

CPC分类号： B32B17/10743 ,  B32B17/10018 ,  B32B2367/00 ,  Y10T428/31507 ,  Y10T428/31573 ,  Y10T428/31645 ,  Y10T428/3175 ,  Y10T428/31797 ,  Y10T428/31913 ,  Y10T428/31938

摘要： A laminate comprises an ionomeric interlayer sheet which, in turn, comprises or is prepared from a sodium/zinc mixed ionomer that comprises carboxylate groups and a combination of counterions that consists essentially of sodium cations and zinc cations. The sodium/zinc mixed ionomer is the neutralization product of a precursor acid copolymer. The precursor acid copolymer comprises copolymerized units of an α-olefin and an α,β-ethylenically unsaturated carboxylic acid, and it has a melt flow rate of about 70 to about 1000 g/10 min. In addition, the precursor acid copolymer, when neutralized to a level of about 40% to about 90%, and when comprising counterions that consist essentially of sodium ions, produces a sodium ionomer that has a freeze enthalpy that is not detectable or that is less than about 3.0 j/g, when determined by differential scanning calorimetry.

摘要翻译： 层压材料包括离聚物中间层片材，其又包含钠盐/锌混合离子交换聚合物或由钠/锌混合离聚​​物制备，所述钠/锌混合离聚​​物包含羧酸根基团和基本上由钠阳离子和锌阳离子组成的抗衡离子的组合。 钠/锌混合离聚​​物是前体酸共聚物的中和产物。 前体酸共聚物包括α-烯烃和α，β-烯键式不饱和羧酸的共聚单元，其熔体流动速率为约70至约1000g / 10min。 此外，当将前体酸共聚物中和至约40％至约90％的水平时，并且当包含基本上由钠离子组成的抗衡离子时，产生具有不可检测或较少的冷冻焓的钠离聚物 当用差示扫描量热法测定时，约为3.0J / g。