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公开(公告)号：US06908730B2
公开(公告)日：2005-06-21
申请号：US10347014
申请日：2003-01-17
摘要： This invention relates to a silver halide photographic material comprising at least one silver halide emulsion comprising silver halide grains having associated therewith: (a) a first dye (Dye 1) that is a cyanine dye capable of spectrally sensitizing a silver halide emulsion and that has at least one anionic substituent; and (b) a second dye (Dye 2) that is not a cyanine dye and that has at least one cationic substituent. Dye 2 has a log P, excluding any counterion, of less than 4.00 and greater than 1.00 or Dye 2 is represented by a dye of formula II as described herein.
摘要翻译： 本发明涉及一种卤化银照相材料，其包含至少一种卤化银乳剂，其包含与其相关联的卤化银颗粒：（a）第一染料（染料1），其为能够对卤化银乳剂进行光谱增感的花青染料， 至少一个阴离子取代基; 和（b）不是花青染料并且具有至少一个阳离子取代基的第二染料（染料2）。 染料2具有小于4.00且大于1.00的对数P，不包括任何抗衡离子，或染料2由本文所述的式II染料表示。
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2.发明授权公开(公告)号：US06312883B1
公开(公告)日：2001-11-06
申请号：US09599468
申请日：2000-06-22
IPC分类号： G03C108
摘要： A silver halide photographic material comprises at least one silver halide emulsion comprising silver halide grains having associated therewith at least two dyes: (a) a first dye that has at least one anionic substituent and that is capable of spectrally sensitizing a silver halide emulsion; and (b) a second dye of formula II wherein: R1 is a substituted or unsubstituted alkyl or aryl group; E3 represents the atoms necessary to complete a substituted or unsubstituted 5- or 6-membered heterocyclic nucleus; Ar1 represents an electron-withdrawing substituted aryl, or a substituted or unsubstituted electron-withdrawing heteroaryl group; L11 through L14 are substituted or unsubstituted methine groups; s is 0 or 1; G1 is an electron-withdrawing group; G2 is O or dicyanovinyl (C(CN)2); W1 is a counterion if necessary.
摘要翻译： 卤化银照相材料包含至少一种包含卤化银颗粒的卤化银乳剂，所述卤化银颗粒具有至少两种染料：（a）具有至少一个阴离子取代基且能够使卤化银乳剂光谱增感的第一种染料; 和（b）式II的第二种染料，其中：R1是取代或未取代的烷基或芳基; E3表示完成取代或未取代的五元或六元杂环核所必需的原子; Ar 1表示吸电子取代的 芳基或取代或未取代的吸电子杂芳基; L11至L14为取代或未取代的次甲基; s为0或1; G 1为吸电子基团; G 2为O或二氰基乙烯基（C（CN）2）; 如果需要，W1是抗衡离子。
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公开(公告)号：US5952147A
公开(公告)日：1999-09-14
申请号：US69528
申请日：1998-04-29
摘要： Portal radiographic elements and a process of confirming the targeting of a beam of X-radiation of from 4 to 25 MVp using the portal radiographic elements are disclosed. The X-radiation is directed at a shield containing a port to create a beam. The beam is directed at a selected anatomical feature of a patient over a period of at least 30 seconds. The portion of the beam that passes through the patient impinges on a metal screen, causing it to emit electrons, and the electrons impinge upon a fluorescent screen, causing it to emit light that exposes a portal verification radiographic element to create a latent image in light-sensitized silver halide grains. A processor is employed to convert the latent image to a viewable silver image from which intended targeting of the X-radiation beam can be verified. The processor relies on attenuation of an infrared beam of a wavelength from 850 to 1100 nm by the radiographic element for activation, and at least one of the hydrophilic colloid layers of the radiographic element contains desensitized silver halide grains to increase the specular density of the radiographic element in the wavelength range of infrared sensors that control the processor.
摘要翻译： 公开了门静脉造影元件和使用门静脉造影元件确定4至25MVp的X射线束的靶向的过程。 X射线被引导到包含端口的屏蔽件以产生光束。 该束在至少30秒的时间内被引导到患者的选定解剖特征。 穿过患者的束的部分撞击在金属屏幕上，使其发射电子，并且电子撞击在荧光屏上，使其发射暴露入口验证放射线照相元件的光以在光中产生潜像 敏化卤化银颗粒。 使用处理器将潜像转换成可视的银图像，从而可以验证X射线束的预期瞄准。 处理器依赖于用于激活的射线照相元件从850nm到1100nm的波长的红外光束的衰减，并且放射线照相元件的至少一个亲水胶体层含有脱敏的卤化银颗粒以增加放射照相的镜面密度 元件在控制处理器的红外传感器的波长范围内。
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4.发明授权Infrared sensor detectable radiographic elements containing very thin tabular grain emulsions 失效红外传感器可检测的含有非常薄的片状颗粒乳剂的放射照相元件
公开(公告)号：US5876909A
公开(公告)日：1999-03-02
申请号：US934177
申请日：1997-09-19
IPC分类号： G03C5/26 , G03C1/00 , G03C1/005 , G03C1/035 , G03C1/74 , G03C1/825 , G03C5/16 , G03C5/38 , G03C1/76
CPC分类号： G03C5/164 , G03C1/8255 , G03C1/0051 , G03C5/16 , Y10S430/145 , Y10S430/164 , Y10S430/167
摘要： The problem of sensing the presence of radiographic elements using infrared sensors that occurs when a radiographic element contains one or more very thin tabular grain emulsions a total silver coating coverage of less than 30 mg/dm.sup.2 is addressed by placing particles in one or more non-emulsion hydrophilic colloid layers. The particles are removable during rapid access processing, have a mean equivalent circular diameter of from 0.3 to 1.1 .mu.m, and have an index of refraction at the wavelength of the infrared radiation that differs from the index of refraction of the hydrophilic colloid by at least 0.2.
摘要翻译： 当放射线照相元件含有一个或多个非常薄的片状颗粒乳剂时，使用红外传感器感测放射线照相元件的存在的问题，总涂层覆盖率小于30mg / dm 2，通过将颗粒放置在一个或多个非织造布 乳液亲水胶体层。 颗粒在快速进入处理过程中是可去除的，具有0.3至1.1μm的平均当量圆直径，并且在红外辐射的波长处的折射率与亲水胶体的折射率至少不同 0.2。
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公开(公告)号：US07189502B1
公开(公告)日：2007-03-13
申请号：US11242340
申请日：2005-10-03
CPC分类号： G03C1/346 , G03C1/16 , G03C1/29 , G03C1/7614 , G03C1/85 , G03C5/16 , G03C5/17 , G03C7/30511 , G03C2001/0055 , G03C2001/03511 , G03C2001/7425 , G03C2001/7635 , G03C2007/3025 , G03C2200/27 , Y10S430/156
摘要： A radiographic material containing tabular silver halide grains also includes an amido compound as an antifoggant precursor that can slowly release an antifoggant over time. These compounds are present in reactive association with the silver halide in tabular silver halide emulsion layers, and are present in an amount of at least 0.5 mmol/mol of silver. The radiographic materials are protected from fog during storage particularly in high temperature environments.
摘要翻译： 包含片状卤化银颗粒的射线照相材料还包括作为防灰雾剂前体的酰氨基化合物，其随时间缓慢释放防灰雾剂。 这些化合物与片状卤化银乳剂层中的卤化银反应性地存在，并且以至少0.5mmol / mol的银的量存在。 放射照相材料在储存期间特别是在高温环境中得到防雾。
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公开(公告)号：US06727055B1
公开(公告)日：2004-04-27
申请号：US10299475
申请日：2002-11-19
申请人： Anthony Adin , Richard E. Beal , Anthony D. Gingello , Stephen A. Hershey , John D. Mee , Myra T. Olm
发明人： Anthony Adin , Richard E. Beal , Anthony D. Gingello , Stephen A. Hershey , John D. Mee , Myra T. Olm
IPC分类号： G03C1005
CPC分类号： G03C1/08 , G03C1/035 , G03C2001/03511 , G03C2001/03535 , G03C2001/03541 , G03C2001/03594
摘要： A radiation-sensitive emulsion is disclosed comprised of cubic silver iodochlorobromide grains comprising 0.25 to about 1.5 mol % iodide, 1 to about 25 mol % chloride, and from about 73.5 to 98.75 mol % bromide, each based on total silver in the emulsion, wherein the grains have an average equivalent circular diameter of greater than 0.6 micrometers and contain from 10−7 to 10−3 mole per silver mole of a metal ion coordination complex dopant of Formula (I) in an internal region of the grains formed after 10 percent and before 95 percent of the total grain silver has been precipitated: [ML6]n (I) wherein n is zero, −1, −2, −3 or −4, M is a filled frontier orbital polyvalent metal ion, other than iridium, and L6 represents bridging ligands which can be independently selected, provided that at least four of the ligands are anionic ligands, and at least one of the ligands is a cyano ligand or a ligand more electronegative than a cyano ligand. Doping of relatively large grain silver iodochlorobromide cubic grain emulsions in accordance with the invention provides optimized speed, contrast and low intensity efficiency.
摘要翻译： 公开了一种辐射敏感性乳剂，其包含基于乳液中总银的0.25-约1.5mol％碘化物，1至约25mol％氯化物和约73.5-98.75mol％溴化物的立方氯碘氯溴化物颗粒，其中 晶粒的平均当量圆直径大于0.6微米，并且在每个银摩尔的式（I）的金属离子配位络合物掺杂剂的晶粒的内部区域中含有10 -7至10 -3摩尔 在10％之后形成，并且总颗粒银的95％已经沉淀出来：其中n为0，-1，-2，-3或-4，M为除铱之外的填充的边界轨道多价金属离子，L6 表示可以独立选择的桥连配体，条件是至少四个配体是阴离子配体，并且至少一个配体是氰基配体或比氰基配体更具有负电性的配体。 相对较大的根据本发明的碘代氯溴化钾立方晶粒状乳剂的掺杂提供优化的速度，对比度和低强度效率。
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7.发明授权Blue spectrally sensitized film for radiography, imaging assembly and method 失效蓝光谱增感胶片用于放射成像，成像组装和方法公开(公告)号：US06686116B1
公开(公告)日：2004-02-03
申请号：US10397435
申请日：2003-03-26
IPC分类号： G03C517
CPC分类号： G03C5/16 , G03C1/047 , G03C1/16 , G03C1/29 , G03C1/46 , G03C5/17 , G03C5/26 , G03C2001/0055 , G03C2001/03511 , G03C2001/03535 , G03C2007/3025 , G03C2200/27 , G03C2200/52 , Y10S430/167 , Y10S430/168
摘要： A blue-sensitive radiographic silver halide film comprises a silver halide emulsion layer comprising predominantly tabular silver halide grains that have an aspect ratio of at least 15, a grain thickness of at least 0.1 &mgr;m, and comprise at least 90 mol % bromide and up to 4 mol % iodide, based on total silver halide. Substantially all of the iodide is present in an internal localized portion of the tabular silver halide grains that excludes the surface of the grains. The tabular silver halide grains are dispersed in a hydrophilic polymeric vehicle mixture comprising at least 0.5% of oxidized gelatin, based on the total dry weight of the polymeric vehicle mixture in the emulsion layer. The tabular silver halide grains are spectrally sensitized using a combination of spectral sensitizing dyes to provide increased speed and reduced dye stain. The dyes have maximum J-aggregate absorptions on the tabular silver halide grains of from about 380 to about 500 nm, wherein the maximum J-aggregate absorption of one spectral sensitizing dye is from about 20 to about 50 nm lower in wavelength than the maximum J-aggregate absorption of the second spectral sensitizing dye.
摘要翻译： 蓝色感光放射线卤化银膜包括卤化银乳剂层，其主要包含片状卤化银颗粒，其长宽比至少为15，晶粒厚度为至少0.1μm，并且包含至少90mol％的溴化物，直到 4mol％碘化物，基于总卤化银。 基本上所有的碘化物都存在于不排除颗粒表面的片状卤化银颗粒的局部部分内。 片状卤化银颗粒分散在包含至少0.5％氧化明胶的亲水性聚合物载体混合物中，基于乳液层中聚合物载体混合物的总干重。 片状卤化银颗粒使用光谱增感染料的组合进行光谱增感，以提高速度和减少染色剂染色。 这些染料在约380至约500nm的片状卤化银颗粒上具有最大的J-聚集体吸收，其中一种光谱增感染料的最大J-聚集体吸收值比最大J值低约20至约50nm 聚集的第二光谱增感染料的吸收。
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公开(公告)号：US5637447A
公开(公告)日：1997-06-10
申请号：US574508
申请日：1995-12-19
申请人： Robert E. Dickerson , Richard E. Beal , Franklin C. Brayer , Stephen A. Hershey , Patrick M. Jeffries
发明人： Robert E. Dickerson , Richard E. Beal , Franklin C. Brayer , Stephen A. Hershey , Patrick M. Jeffries
CPC分类号： G03C5/164 , G03C1/295 , G03C1/832 , G03C5/16 , G03C1/035 , G03C2200/58 , Y10S430/145 , Y10S430/167
摘要： A radiation-sensitive film for reproducing digitally stored medical diagnostic images through a series of laterally offset exposures by a controlled radiation source followed byprocessing in 90 seconds or less including development, fixing and drying is disclosed. The film exhibits an average contrast in the range of from 1.5 to 2.0, measured over a density above fog of from 0.25 to 2.0. An emulsion is provided in which silver bromochloride grains provided (a) containing at least 10 mole percent bromide, based on silver, (b) having a mean equivalent circular diameter of less than 0.40 .mu.m, (c) exhibiting an average aspect ratio of less than 1.3, and (d) coated at a silver coverage of less than 40 mg/dm.sup.2. Adsorbed to the surfaces of the silver bromochloride grains is at least one spectral sensitizing dye having an absorption half peak bandwidth in the spectral region of exposure by the controlled exposure source. The film also contains an infrared opacifying dye capable of reducing specular transmission through the film before, during and after processing to less than 50 percent, measured at a wavelength within the spectral region of from 850 to 1100 nm.
摘要翻译： 公开了一种用于通过受控辐射源的一系列横向偏移曝光再现数字存储的医疗诊断图像的辐射敏感膜，随后在90秒或更短时间内处理，包括显影，定影和干燥。 该薄膜的平均对比度在1.5至2.0的范围内，在雾度以上的密度测量为0.25至2.0。 提供了一种乳液，其中溴溴化银颗粒提供（a）含有至少10摩尔百分比的溴，基于银，（b）平均当量圆直径小于0.40微米，（c）具有平均长宽比 小于1.3，（d）以小于40mg / dm2的银覆盖率涂覆。 吸附到溴氯化银颗粒的表面上的是至少一种光谱增感染料，其在受控曝光源的曝光的光谱区域中具有吸收半峰带宽。 该薄膜还含有一种红外遮光染料，其能够在850至1100nm的光谱区域内的波长下测量，在加工前，加工期间和之后通过薄膜的镜面透射小于50％。
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公开(公告)号：US5292627A
公开(公告)日：1994-03-08
申请号：US892850
申请日：1992-06-03
摘要： Monocyclic and polycyclic azoles having the following formula modify the tone of a silver image formed from a fine grain radiation sensitive silver bromide or silver bromoiodide emulsion layer in which the silver bromide or silver bromoiodide grains have a mean equivalent circular diameter of less than 0.3 .mu.m. The azoles have the formula: ##STR1## wherein Z is --N.dbd. or --C(R.sup.5).dbd. where R.sup.5 is hydrogen, --NH.sub.2, aliphatic of 1 to 8 carbon atoms or aromatic of 1 to 8 carbon atoms;R.sup.4 is hydrogen, aliphatic of 1 to 8 carbon atoms or aromatic of 1 to 8 carbon atoms;R.sup.4 and R.sup.5 together complete a 5 or 6 membered heterocyclic nucleus containing 1 to 3 ring nitrogen atoms;L is a divalent aliphatic linking group containing 1 to 8 carbon atoms;T is an aliphatic terminal group containing 1 to 10 carbon atoms;m is 0 or 1;n is an integer of 1 to 4; andp is an integer of 2 to 4.
摘要翻译： 具有下式的单环和多环唑改变由细晶粒辐射敏感的溴化银或溴碘化银乳剂层形成的银图像的色调，其中溴化银或溴碘化银颗粒的平均当量圆直径小于0.3（我的 ）m。 唑类具有下列通式：（*化学结构*）（I）其中Z为-N =或-C（R5）=其中R5为氢，-NH2为1至8个碳原子的脂族或1至8个碳的芳族 原子 R4是氢，1至8个碳原子的脂族或1至8个碳原子的芳族; R4和R5一起完成含有1至3个环氮原子的5或6元杂环核; L是含有1至8个碳原子的二价脂族连接基团; T是含有1至10个碳原子的脂肪族端基; m为0或1; n为1〜4的整数， p为2〜4的整数。
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公开(公告)号：US06174657B1
公开(公告)日：2001-01-16
申请号：US09103596
申请日：1998-06-24
IPC分类号： G03C1498
CPC分类号： G03C1/49872 , G03C1/76 , G03C1/825 , G03C1/83 , G03C1/831 , G03C1/832 , G03C1/833 , G03C2200/22 , G03C2200/42
摘要： A photothermographic element comprises: (a) a support bearing on one surface thereof (b) a photosensitive emulsion layer (i) a binder; (ii) a light-insensitive organic silver salt, (iii) a reducing agent, and (iv) a photosensitive silver halide emulsion; (c) an antihalation dye incorporated in the emulsion layer, in a polymer layer under the photosensitive layer, in the support, or in a backside polymer layer; and (d) one or more tinting dyes such that the final color space of the film lies within the range defined by 220°
摘要翻译： 光热敏成像元件包括：（a）在其一个表面上的支撑轴承（b）感光乳剂层（i）粘合剂; （ii）不光敏有机银盐，（iii）还原剂，和（iv）光敏卤化银乳剂; （c）掺入乳剂层中的防光晕染料，在感光层下的聚合物层，载体中或背面聚合物层中; 和（d）一种或多种着色染料，使得膜的最终色彩空间在由220°
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