Photographic elements with tetra-nuclear merocyanine sensitizers
    1.
    发明授权
    Photographic elements with tetra-nuclear merocyanine sensitizers 失效
    摄影元素与四核花菁敏化剂

    公开(公告)号:US5563021A

    公开(公告)日:1996-10-08

    申请号:US479581

    申请日:1995-06-07

    CPC分类号: G03C1/26 A01M31/002 G03C1/061

    摘要: A photographic element comprising a light sensitive silver halide emulsion sensitized with a dye of formula (I) and a nucleating agent or amine booster associated with the silver halide emulsion: ##STR1## wherein: R.sub.3 is an alkyl group, alkenyl group, or aryl groupR.sub.4 and R.sub.5 are each hydrogen, an alkyl group, alkenyl or aryl group;R.sub.6, R.sub.7 and R.sub.8 are, independently, an alkyl group, alkenyl group, aryl group, or H;the dye has at least three acid or acid salt substituents; andeach L independently represents a methine group;p is 0 or 1;Z.sub.1 represents the atoms necessary to complete a 5- or 6-membered heterocyclic ring group;(X).sub.n represents counterions as needed to balance the charge on the molecule.The present invention also provides a process for forming a high contrast photographic image on a photographic element having a light sensitive silver halide emulsion sensitized with a dye of formula (I). The process comprises developing such a photographic element in the presence of a hydrazine compound and an amine booster.

    摘要翻译: 包含用式(I)的染料敏化的感光卤化银乳剂和与卤化银乳剂相关的成核剂或胺促进剂的照相元件:其中:R 3是烷基,烯基, 或芳基R 4和R 5各自为氢,烷基,烯基或芳基; R6,R7和R8独立地为烷基,烯基,芳基或H; 该染料具有至少三个酸或酸盐取代基; 并且每个L独立地表示次甲基; p为0或1; Z1表示完成5-或6-元杂环基团所必需的原子; (X)n表示在分子上平衡电荷所需的抗衡离子。 本发明还提供了在具有用式(I)的染料敏化的感光卤化银乳剂的照相材料上形成高对比度摄影图像的方法。 该方法包括在肼化合物和胺助剂的存在下开发这种照相元件。

    Photographic element
    6.
    发明授权
    Photographic element 失效
    摄影元素

    公开(公告)号:US06312884B1

    公开(公告)日:2001-11-06

    申请号:US09533573

    申请日:2000-03-23

    IPC分类号: G03C114

    CPC分类号: G03C1/14

    摘要: This invention comprises a photographic element comprising a light sensitive silver halide emulsion layer which contains a sensitizing dye of the formula: wherein: n is 0 or 1; X, Y, and Z are independently O, N, S, Se, or C; X′ is O, NR13, S, or Se; R1 and R2 are acid substituted alkyl; R4 is H or alkyl, with the proviso that if X′ is N, R4 is H; each of R6, R7, R8 and R9 is independently H or a substituent or R7 and R8 or R8 and R9 together with the carbon atoms to which they are attached form a 5-membered or 6-membered ring; when X or Y or Z is O, N, S or Se then a, b or c, respectively, is 0 and when X or Y or Z is C, a, b or c, respectively is 1 and the corresponding R10, R11, or R12 substituent is independently H or a non-aromatic substituent; and R13 is alkyl or substituted alkyl.

    摘要翻译: 本发明包括一种含有感光卤化银乳剂层的照相元件,其含有下式的增感染料:其中:n为0或1; X,Y和Z独立地为O,N,S,Se或C; X'是O,NR 13,S或Se; R 1和R 2是酸取代的烷基; R 4是H或烷基,条件是如果X'是N,则R4是H; R6,R7,R8和R9各自是 独立地是H或取代基,或者R 7和R 8或R 8和R 9与它们所连接的碳原子一起形成5元或6元环;当X或Y或Z为O,N,S或Se时, ,b或c分别为0,当X或Y或Z为C时,a,b或c分别为1,相应的R10,R11或R12取代基独立为H或非芳香族取代基; 和R 13是烷基或取代的烷基。

    Nondiffusive compounds comprised of a sensitizing dye moiety and an
image dye moiety joined by a radiation cleavable linkage
    7.
    发明授权
    Nondiffusive compounds comprised of a sensitizing dye moiety and an image dye moiety joined by a radiation cleavable linkage 失效
    由致敏染料部分和通过可辐射切割键连接的图像染料部分组成的非扩散化合物

    公开(公告)号:UST998006I4

    公开(公告)日:1980-09-02

    申请号:US64693

    申请日:1979-08-08

    申请人: John D. Mee

    发明人: John D. Mee

    IPC分类号: G03C1/73

    CPC分类号: G03C1/73

    摘要: Radiation-cleavable nondiffusible compounds for providing a transfer dye image are comprised of a spectral sensitizing dye moiety and a diffusible image dye moiety joined by a linkage in the spectral sensitizing dye moiety which is cleaved upon absorption of radiation by the spectral sensitizing dye moiety, thereby releasing a diffusible image dye. Such compounds are useful in radiation-sensitive elements and processes to provide dye images. Preferred compounds have the formula ##STR1## where: Q represents the atoms to complete a pyridine or quinoline ring;SENS is attached to the 2 or 4 position of the pyridine or quinoline ring and represents the atoms which, in conjunction with N, complete a spectral sensitizing dye;ALK represents an alkylene moiety of 1 to 8 carbon atoms;DYE represents a diffusible photographic dye or dye precursor moiety; andX.sup..crclbar. represents an anion, if necessary to provide charge neutrality.

    Photographic elements containing particular sensitizing dyes
    9.
    发明授权
    Photographic elements containing particular sensitizing dyes 失效
    含有特定敏化染料的摄影元素

    公开(公告)号:US5464736A

    公开(公告)日:1995-11-07

    申请号:US234744

    申请日:1994-04-28

    IPC分类号: G03C1/22 G03C1/12

    CPC分类号: G03C1/22

    摘要: A photographic element having a silver halide emulsion sensitized by dye of the formula I: ##STR1## wherein: R.sup.1 represents a substituted or unsubstituted aromatic or heteroaromatic group, a substituted or unsubstituted alkyl or H;R.sup.2 represents a substituted or unsubstituted alkyl, alkenyl, aryl, aralkyl, or H;E.sup.1 represents an electron withdrawing group;Z represents the non-metallic atoms required to complete a substituted or unsubstituted ring system containing at least one 5- or 6-membered heterocyclic nucleus;L.sup.1, L.sup.2, L.sup.5 and L.sup.6 independently represent a substituted or unsubstituted methine;m may be 0, 1, 2 or 3;n may be 0 or 1.

    摘要翻译: 具有由式I的染料敏化的卤化银乳剂的照相元件:其中:R 1表示取代或未取代的芳族或杂芳族基团,取代或未取代的烷基或H; R 2表示取代或未取代的烷基,烯基,芳基,芳烷基或H; E1表示吸电子基团; Z表示完成含有至少一个5-或6-元杂环核的取代或未取代的环体系所需的非金属原子; L1,L2,L5和L6独立地表示取代或未取代的次甲基; m可以是0,1,2或3; n可以是0或1。