摘要:
A photographic element comprising a light sensitive silver halide emulsion sensitized with a dye of formula (I) and a nucleating agent or amine booster associated with the silver halide emulsion: ##STR1## wherein: R.sub.3 is an alkyl group, alkenyl group, or aryl groupR.sub.4 and R.sub.5 are each hydrogen, an alkyl group, alkenyl or aryl group;R.sub.6, R.sub.7 and R.sub.8 are, independently, an alkyl group, alkenyl group, aryl group, or H;the dye has at least three acid or acid salt substituents; andeach L independently represents a methine group;p is 0 or 1;Z.sub.1 represents the atoms necessary to complete a 5- or 6-membered heterocyclic ring group;(X).sub.n represents counterions as needed to balance the charge on the molecule.The present invention also provides a process for forming a high contrast photographic image on a photographic element having a light sensitive silver halide emulsion sensitized with a dye of formula (I). The process comprises developing such a photographic element in the presence of a hydrazine compound and an amine booster.
摘要:
Dyes according to formulas (I), (II), (III), (IV), and (V) below are described. The dyes are useful as low-staining sensitizing dyes for photographic materials. ##STR1## Z.sub.1, Z.sub.2, Z.sub.3, R.sub.1, R.sub.2, L, D, G, X, n, P, and q are defined herein.
摘要:
A photosensitive photographic material is described comprising a support bearing a silver halide emulsion layer sensitized with a dye of the general formula: ##STR1## wherein Y is S or Se,L.sup.1, L.sup.2, L.sup.3, L.sup.4 and L.sup.5 are each independently substituted or unsubstituted methine groups,A is N--R.sup.3 or O,B is N--R.sup.4 when A is O, or N--R.sup.4, S, or O when A is N--R.sup.3,R.sup.1 and R.sup.2 are each a substituted or unsubstituted alkyl group,R.sup.3 and R.sup.4 are each a substituted or unsubstituted alkyl or a substituted or unsubstituted aryl group,R.sup.5 is an alkyl group of 1-4 carbon atoms,n is 0, 1 or 2, andX is counterion,and wherein at least two of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are substituted with an acid or acid salt substituent.
摘要:
Compounds of the formulaa: ##STR1## where Z.sub.1, Z.sub.2, L.sub.1 -L.sub.5, R.sub.1, R.sub.2, R.sub.3, m, and n are as defined herein are disclosed. A method of making the componds is also disclosed. the compounds are useful as sensitizing dyes in photographic elements.
摘要:
ENERGY-SENSITIVE COMPOUNDS CONTAINING A HETERCYCLIC NITROGEN ATOMS SUBSTITUTED WITH AN -OR GROUP ARE PHOTOCHEMICAL INITIATORS FOR THE POLYMERIZATION OF VINYL MONOMERS.
摘要:
This invention comprises a photographic element comprising a light sensitive silver halide emulsion layer which contains a sensitizing dye of the formula: wherein: n is 0 or 1; X, Y, and Z are independently O, N, S, Se, or C; X′ is O, NR13, S, or Se; R1 and R2 are acid substituted alkyl; R4 is H or alkyl, with the proviso that if X′ is N, R4 is H; each of R6, R7, R8 and R9 is independently H or a substituent or R7 and R8 or R8 and R9 together with the carbon atoms to which they are attached form a 5-membered or 6-membered ring; when X or Y or Z is O, N, S or Se then a, b or c, respectively, is 0 and when X or Y or Z is C, a, b or c, respectively is 1 and the corresponding R10, R11, or R12 substituent is independently H or a non-aromatic substituent; and R13 is alkyl or substituted alkyl.
摘要翻译:本发明包括一种含有感光卤化银乳剂层的照相元件,其含有下式的增感染料:其中:n为0或1; X,Y和Z独立地为O,N,S,Se或C; X'是O,NR 13,S或Se; R 1和R 2是酸取代的烷基; R 4是H或烷基,条件是如果X'是N,则R4是H; R6,R7,R8和R9各自是 独立地是H或取代基,或者R 7和R 8或R 8和R 9与它们所连接的碳原子一起形成5元或6元环;当X或Y或Z为O,N,S或Se时, ,b或c分别为0,当X或Y或Z为C时,a,b或c分别为1,相应的R10,R11或R12取代基独立为H或非芳香族取代基; 和R 13是烷基或取代的烷基。
摘要:
Radiation-cleavable nondiffusible compounds for providing a transfer dye image are comprised of a spectral sensitizing dye moiety and a diffusible image dye moiety joined by a linkage in the spectral sensitizing dye moiety which is cleaved upon absorption of radiation by the spectral sensitizing dye moiety, thereby releasing a diffusible image dye. Such compounds are useful in radiation-sensitive elements and processes to provide dye images. Preferred compounds have the formula ##STR1## where: Q represents the atoms to complete a pyridine or quinoline ring;SENS is attached to the 2 or 4 position of the pyridine or quinoline ring and represents the atoms which, in conjunction with N, complete a spectral sensitizing dye;ALK represents an alkylene moiety of 1 to 8 carbon atoms;DYE represents a diffusible photographic dye or dye precursor moiety; andX.sup..crclbar. represents an anion, if necessary to provide charge neutrality.
摘要:
Novel photographic materials comprising a light-sensitive layer and a light-absorbing material are described. The light-absorbing materials comprise colored components which are decolorized by various forms of energy, such as, for example heat. The novel light-absorbing materials are useful in antihalation layers particularly adapted for photographic elements designed for development with heat.
摘要:
A photographic element having a silver halide emulsion sensitized by dye of the formula I: ##STR1## wherein: R.sup.1 represents a substituted or unsubstituted aromatic or heteroaromatic group, a substituted or unsubstituted alkyl or H;R.sup.2 represents a substituted or unsubstituted alkyl, alkenyl, aryl, aralkyl, or H;E.sup.1 represents an electron withdrawing group;Z represents the non-metallic atoms required to complete a substituted or unsubstituted ring system containing at least one 5- or 6-membered heterocyclic nucleus;L.sup.1, L.sup.2, L.sup.5 and L.sup.6 independently represent a substituted or unsubstituted methine;m may be 0, 1, 2 or 3;n may be 0 or 1.
摘要翻译:具有由式I的染料敏化的卤化银乳剂的照相元件:其中:R 1表示取代或未取代的芳族或杂芳族基团,取代或未取代的烷基或H; R 2表示取代或未取代的烷基,烯基,芳基,芳烷基或H; E1表示吸电子基团; Z表示完成含有至少一个5-或6-元杂环核的取代或未取代的环体系所需的非金属原子; L1,L2,L5和L6独立地表示取代或未取代的次甲基; m可以是0,1,2或3; n可以是0或1。
摘要:
Polymethine dyes are disclosed containing a tellurazolium nucleus which is substituted at its 2-position with methine chain which is in turn substituted at its .beta. position with a dye property modifier. These dyes can be used in photographic elements to facilitate image formation.