Mercaptofunctional silane and process for its preparation

    公开(公告)号:US20080083350A1

    公开(公告)日:2008-04-10

    申请号:US11544132

    申请日:2006-10-06

    IPC分类号: C07F7/08 C09C1/28

    摘要: A mercaptofunctional silane is provided of general Formula (1): [HSG1SiZθZβ]m[HSG2SiZβ3]n[HSG3SiZβ2X]o[[HSG4SiZβX2]p   (1) wherein: each occurrence of G1, G2, G3, and G4 is independently a hydrocarbylene group containing from 1 to 30 carbon derived by substitution of a hydrogen on alkyl, alkenyl, aryl, or aralkyl or a divalent heterocarbon group containing 2 to 30 carbon atoms and one or more etheric oxygen (—O—) and/or sulfur (—S—) atoms; each occurrence of X is independently selected from the group consisting of —Cl, —Br, RO—, RC(—O)O—, R2C═NO—, R2NO—, —R, (HO)d-1G5O—, wherein each R is independently selected from the group consisting of hydrogen, straight, cyclic or branched alkyl that can or can not contain unsaturation, alkenyl groups, aryl groups, and aralkyl groups, wherein each R, other than hydrogen, contains from 1 to 18 carbon atoms, G5 is independently a substituted hydrocarbon group from 2 to 15 carbon atoms or a substituted heterocarbon group from about 4 to 15 carbon atoms and contains one or more etheric oxygen atoms; each occurrence of Zβ, which forms a bridging structure between two silicon atoms, is [—OG5(OH)d-2O—]0.5, wherein each occurrence of G5 is independently selected form the group consisting of a hydrocarbylene group of from 2 to 15 carbon atoms or a divalent heterocarbon group of from 4 to 15 carbon atoms containing one or more etheric oxygen atoms; each occurrence of Zθ, which forms a cyclic structure with a silicon atom, is independently given by —OG5(OH)d-2O—, wherein G5 is independently selected form the group consisting of a hydrocarbylene group of from 2 to 15 carbon atoms or a divalent heterocarbon group of from 4 to 15 carbon atoms containing one or more etheric oxygen atoms; and, each occurrence of subscripts d, m, n, o and p independently is an integer wherein d is from 2 to 6 in a first embodiment, 2 or 3 in a second embodiment and 2 in a third embodiment; m is 0 to 20; n is 0 to 18; o is 0 to 20; and, p is 0 to 20; with the proviso that m+n+o+p is equal to or greater than 2.

    DIOL-DERIVED ORGANOFUNCTIONAL SILANE AND COMPOSITIONS CONTAINING SAME
    4.
    发明申请
    DIOL-DERIVED ORGANOFUNCTIONAL SILANE AND COMPOSITIONS CONTAINING SAME 有权
    二元衍生的有机硅烷及其组合物

    公开(公告)号:US20120157616A1

    公开(公告)日:2012-06-21

    申请号:US13406825

    申请日:2012-02-28

    IPC分类号: C08L9/00 C07F7/18

    摘要: Described are diol-derived organofunctional silanes in which the silanes contain cyclic and bridged alkoxy groups derived from hydrocarbon-based diols and methods for the preparation of the silanes. Also described are rubber compositions containing the diol-derived organofunctional silanes, methods for the preparation of the rubber compositions and articles of manufacture containing the rubber compositions, in particular, automotive tires and components thereof.

    摘要翻译: 描述了二醇衍生的有机官能硅烷,其中硅烷含有源自烃基二醇的环状和桥连烷氧基以及制备硅烷的方法。 还描述了含有二醇衍生的有机官能硅烷的橡胶组合物,制备橡胶组合物的方法和含有橡胶组合物,特别是汽车轮胎及其组分的制品。