摘要:
A blocked mercaptosilane of the structure: G-C(═O)—S—CH2CH2CH2SiX3 is disclosed wherein each X is an independently selected RO— group or R— group wherein each R is independently selected from the group consisting of hydrogen, alkyl that may or may not contain unsaturation, alkenyl groups, aryl groups, and aralkyl groups, such moieties other than hydrogen having from 1 to 18 carbon atoms, at least one X is RO—, and G is a monovalent alkyl group.
摘要翻译:具有以下结构的封端巯基硅烷:GC(-O)-S-CH 2 CH 2 CH 2 SiX 3 SUB >,其中每个X是独立选择的RO-基团或R-基团,其中每个R独立地选自氢,可以含有或可以不含有不饱和键的烷基,烯基,芳基和芳烷基,例如 具有1至18个碳原子的氢以外的部分,至少一个X为RO-,G为一价烷基。
摘要:
A filled elastomer composition comprises: a) at least one rubber component; b) at least one particulate filler; and, c) at least one mercaptofunctional silane of a particular structure.
摘要:
A mercaptofunctional silane is provided of general Formula (1): [HSG1SiZθZβ]m[HSG2SiZβ3]n[HSG3SiZβ2X]o[[HSG4SiZβX2]p (1) wherein: each occurrence of G1, G2, G3, and G4 is independently a hydrocarbylene group containing from 1 to 30 carbon derived by substitution of a hydrogen on alkyl, alkenyl, aryl, or aralkyl or a divalent heterocarbon group containing 2 to 30 carbon atoms and one or more etheric oxygen (—O—) and/or sulfur (—S—) atoms; each occurrence of X is independently selected from the group consisting of —Cl, —Br, RO—, RC(—O)O—, R2C═NO—, R2NO—, —R, (HO)d-1G5O—, wherein each R is independently selected from the group consisting of hydrogen, straight, cyclic or branched alkyl that can or can not contain unsaturation, alkenyl groups, aryl groups, and aralkyl groups, wherein each R, other than hydrogen, contains from 1 to 18 carbon atoms, G5 is independently a substituted hydrocarbon group from 2 to 15 carbon atoms or a substituted heterocarbon group from about 4 to 15 carbon atoms and contains one or more etheric oxygen atoms; each occurrence of Zβ, which forms a bridging structure between two silicon atoms, is [—OG5(OH)d-2O—]0.5, wherein each occurrence of G5 is independently selected form the group consisting of a hydrocarbylene group of from 2 to 15 carbon atoms or a divalent heterocarbon group of from 4 to 15 carbon atoms containing one or more etheric oxygen atoms; each occurrence of Zθ, which forms a cyclic structure with a silicon atom, is independently given by —OG5(OH)d-2O—, wherein G5 is independently selected form the group consisting of a hydrocarbylene group of from 2 to 15 carbon atoms or a divalent heterocarbon group of from 4 to 15 carbon atoms containing one or more etheric oxygen atoms; and, each occurrence of subscripts d, m, n, o and p independently is an integer wherein d is from 2 to 6 in a first embodiment, 2 or 3 in a second embodiment and 2 in a third embodiment; m is 0 to 20; n is 0 to 18; o is 0 to 20; and, p is 0 to 20; with the proviso that m+n+o+p is equal to or greater than 2.
摘要:
Described are diol-derived organofunctional silanes in which the silanes contain cyclic and bridged alkoxy groups derived from hydrocarbon-based diols and methods for the preparation of the silanes. Also described are rubber compositions containing the diol-derived organofunctional silanes, methods for the preparation of the rubber compositions and articles of manufacture containing the rubber compositions, in particular, automotive tires and components thereof.
摘要:
Diol derived blocked mercaptofunctional silane compositions in which the silanes comprise cyclic and bridged alkoxy groups derived from hydrocarbon-based diols and processes for their preparation are provided. Also provided are rubber compositions comprising the cyclic diol-derived blocked mercaptofunctional silanes, processes for their preparation and articles of manufacture comprising the rubber compositions, in particular, automotive tires and components thereof.
摘要:
Sulfur-containing silane coupling agents, and organic polymers containing carbon-carbon double bonds. These silanes can be carried on organic and inorganic fillers. The invention also relates to tire compositions and articles of manufacture, particularly tires, made from the elastomer compositions described herein.
摘要:
Sulfur-containing silane coupling agents, and organic polymers containing carbon-carbon double bonds. These silanes can be carried on organic and inorganic fillers. The invention also relates to tire compositions and articles of manufacture, particularly tires, made from elastomer compositions.
摘要:
Free-flowing filler compositions containing sulfur-containing silane coupling agents, and a tire composition containing the filler composition, for use in the manufacture of tires.
摘要:
Diol derived blocked mercaptofunctional silane compositions in which the silanes comprise cyclic and bridged alkoxy groups derived from hydrocarbon-based diols and processes for their preparation are provided. Also provided are rubber compositions comprising the cyclic diol-derived blocked mercaptofunctional silanes, processes for their preparation and articles of manufacture comprising the rubber compositions, in particular, automotive tires and components thereof.
摘要:
Diol derived blocked mercaptofunctional silane compositions in which the silanes comprise cyclic and bridged alkoxy groups derived from hydrocarbon-based diols and processes for their preparation are provided. Also provided are rubber compositions comprising the cyclic diol-derived blocked mercaptofunctional silanes, processes for their preparation and articles of manufacture comprising the rubber compositions, in particular, automotive tires and components thereof.