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公开(公告)号：US4497923A
公开(公告)日：1985-02-05
申请号：US547904
申请日：1983-11-02
IPC分类号： B01J13/00 , B05D5/08 , C08J3/00 , C08J3/09 , C09K3/00 , C10L7/02 , C08J3/08 , C08J3/10 , C08K5/01 , C08K5/04
CPC分类号： B05D5/08 , B01J13/0082 , C08J3/005 , C08J3/091 , C09K3/00 , C10L7/02 , Y10S524/924
摘要： The present invention relates to a process for the viscosification of an organic liquid which comprises the steps of forming a first solution of an anionic polymer dissolved in the organic liquid; forming a second solution of a cationic polymer dissolved in the organic liquid; and mixing the first and the second solutions together to form an interpolymer complex of the anionic and cationic polymer in the organic liquid, wherein the organic liquid containing the interpolymer complex has improved viscosification properties. This solution possesses higher viscosity than the mean of the separate viscosities of the starting solutions at relatively low solids content. Moreover, these interpolymer complexes, in hydrocarbon solutions, can be formulated to exhibit shear thickening at increased shear rates. This property is useful in such technological applications as antimisting of the solvent.
摘要翻译： 本发明涉及有机液体的增粘方法，其包括以下步骤：形成溶解在有机液体中的阴离子聚合物的第一溶液; 形成溶解在有机液体中的阳离子聚合物的第二溶液; 并将第一和第二溶液混合在一起形成有机液体中阴离子和阳离子聚合物的互聚物络合物，其中含有互聚物络合物的有机液体具有改进的增粘性能。 该溶液具有比起始溶液在相对较低固体含量下分开的粘度的平均值更高的粘度。 此外，在烃溶液中的这些互聚物配合物可以配制成在增加的剪切速率下显示剪切增稠。 该特性在溶剂的抗溶剂等技术应用中是有用的。
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公开(公告)号：US5389271A
公开(公告)日：1995-02-14
申请号：US77577
申请日：1993-06-15
IPC分类号： C08F8/36 , C08F8/44 , C08F10/00 , C10M151/00
CPC分类号： C08F8/36 , C10M151/04 , C10M2205/022
摘要： The present invention provides novel sulfonated ethylene/alpha olefin copolymer compositions obtained by sulfonating ethylene/alpha olefin copolymer having number average molecular weights in the range of about 800 to about 50,000, and which have a high degree of terminal unsaturation. Preferably, at least 30% of the terminal unsaturation is vinylidene terminal unsaturation. Also, the alpha olefin preferably has 3 to about 12 carbon atoms.
摘要翻译： 本发明提供了通过磺化乙烯/α-烯烃共聚物获得的新型磺化乙烯/α-烯烃共聚物组合物，其数均分子量在约800至约50,000的范围内并且具有高度的末端不饱和度。 优选地，末端不饱和度的至少30％是亚乙烯基末端不饱和度。 此外，α-烯烃优选具有3至约12个碳原子。
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公开(公告)号：US4529527A
公开(公告)日：1985-07-16
申请号：US610128
申请日：1984-05-14
IPC分类号： C10M169/04 , C08F8/44 , C10M135/10 , C10M151/02 , C10N20/00 , C10N20/02 , C10N30/02 , C10N70/00 , C10M1/40 , C10M3/34
CPC分类号： C10M151/02 , C08F8/44 , C10M2209/084 , C10M2221/02
摘要： The instant invention relates to an improved process for controlling the viscosity of organic liquids at low temperatures by incorporating in said liquid a minor amount of an ionic polymer and a cosolvent for the ionic groups of said polymer. The ionic polymer comprises a backbone which is substantially soluble in said organic liquid and pendant ionic groups which are substantially insoluble in said organic liquid, wherein such ionic polymer or terpolymer is formed from at least one acrylate or methacrylate monomer having at least eight carbon atoms and a minor portion of a sulfonate-containing monomer. A cosolvent is selected which will solubilize the pendant ionomeric groups and provide a reasonably homogeneous mixture of solvent, cosolvent and ionomeric polymer. The preferred compositions prepared by the method of the instant invention comprise an organic liquid having a solubility parameter of from 6 to 10.5 in combination with a sulfonated co- or terpolymer containing from 0.2 up to 10.0 mole percent ionic groups which has been neutralized by a basic material selected from Group IA, IIA, IB and IIB of the Periodic Table of the Elements (also lead, tin and antimony) and a nonvolatile alcohol or amine cosolvent. In a most preferred embodiment, the solvent is a high boiling paraffinic-type oil, the polymer is a metal sulfonate containing acrylate or methacrylate copolymer, comprising from 0.3 to 3.0 weight percent sodium or potassium sulfonate groups, and a C.sub.6 to C.sub.12 alcohol, or C.sub.2 -C.sub.12 glycol, or C.sub.3 -C.sub.12 triol is used as the cosolvent.
摘要翻译： 本发明涉及通过在所述液体中掺入少量离子聚合物和所述聚合物的离子基团的助溶剂来控制低温下有机液体的粘度的改进方法。 离子聚合物包含基本上可溶于所述有机液体的骨架和基本上不溶于所述有机液体的侧基离子基团，其中这种离子聚合物或三元共聚物由至少一种具有至少8个碳原子的丙烯酸酯或甲基丙烯酸酯单体形成， 少量的含磺酸酯的单体。 选择共溶剂，其将溶解侧基离聚物基团并提供溶剂，共溶剂和离聚物聚合物的合理均匀的混合物。 通过本发明的方法制备的优选组合物包含溶解度参数为6至10.5的有机液体与含有0.2至10.0摩尔％离子基团的磺化共聚物或三元共聚物组合，其已被碱性 选自元素周期表的IA，IIA，IB和IIB族的材料（也包括铅，锡和锑）和不挥发性醇或胺助溶剂。 在最优选的实施方案中，溶剂是高沸点链烷烃型油，该聚合物是含有丙烯酸酯或甲基丙烯酸酯共聚物的金属磺酸盐，其包含0.3至3.0重量％的磺酸钠或磺酸钾基团和C 6至C 12醇，或 使用C 2 -C 12二醇或C 3 -C 12三醇作为助溶剂。
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公开(公告)号：US4330447A
公开(公告)日：1982-05-18
申请号：US222484
申请日：1981-01-05
CPC分类号： C08L23/32
摘要： This invention relates to a blend composition of a metal neutralized sulfonated polymer, a preferential plasticizer and polydialkylsiloxane, wherein the blend composition has improved melt flow and a lower coefficient of friction while substantially maintaining physical properties as compared to the blend of either the metal neutralized sulfonated polymer and preferential plasticizer or the metal neutralized sulfonated polymer itself.
摘要翻译： 本发明涉及金属中和磺化聚合物，优选增塑剂和聚二烷基硅氧烷的共混组合物，其中共混物组合物具有改善的熔体流动性和较低的摩擦系数，同时与金属中和磺化的共混物相比基本保持物理性能 聚合物和优选增塑剂或金属中和的磺化聚合物本身。
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公开(公告)号：US3974241A
公开(公告)日：1976-08-10
申请号：US524512
申请日：1974-11-18
CPC分类号： C08L23/32
摘要： This invention relates to blends of sulfonated elastomers with crystalline polyolefins. The sulfonated elastomer comprises from about 0.2 to about 20 mole percent sulfonate groups, at least 95% of which are combined with metal counter ions selected from the group consisting of Groups I and II of the Periodic Table of the Elements, aluminum, and lead; organic amines; and mixtures thereof. The crystalline polyolefin is preferably selected from the group consisting of polyethylene, including high and low density polyethylenes, and polypropylene. The crystalline polyolefin comprises a minor portion of said blends.
摘要翻译： 本发明涉及磺化弹性体与结晶聚烯烃的共混物。 磺化弹性体包含约0.2至约20摩尔％的磺酸盐基团，其中至少95％与选自元素周期表第I和II族的金属抗衡离子，铝和铅组合; 有机胺; 及其混合物。 结晶聚烯烃优选选自包括高密度和低密度聚乙烯的聚乙烯和聚丙烯。 结晶聚烯烃包含少部分所述共混物。
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6.发明授权
公开(公告)号：US4904722A
公开(公告)日：1990-02-27
申请号：US788963
申请日：1985-10-18
摘要： A method for controlling the viscosity of organic liquids, said organic liquid having a solubility parameter of less than 9.5, a viscosity, as measured at 25.degree. C., of less than 200 centipoises and said organic liquid is selected from the group consisting of mineral oils, synthetic oils, naphthanes, alkanes, cycloalkanes and aromatics and mixtures thereof, which comprises incorporating in said organic liquid about 0.01 to 20 grams of polymer complex per 100 ml. of said organic liquid, said polymer complex being formed "in situ" in said organic liquid or dissolved in said organic liquid, said complex being comprised of polymer A, containing about 4 meq. to 500 meq. of neutralized sulfonate groups, and polymer B, containing basic nitrogen groups, both functional groups being present at a level of from about 4 to 500 meq. per 100 g. of polymer, wherein polymer B has the formula: ##STR1## wherein x is about 50.0 to 99.8 weight percent and y is about 0.2 to about 50.0 weight percent, wherein said sulfonate groups of said polymer A being neutralized with basic compounds selected from the group consisting of transition elements, said polymer A having a polymeric backbone substantially soluble in said organic liquid and said polymer having a molecular weight of about 1,000 to 10,000,000.
摘要翻译： 一种用于控制有机液体的粘度的方法，所述有机液体的溶解度参数小于9.5，在25℃下测得的小于200厘泊的粘度和所述有机液体选自矿物质 油，合成油，萘烷，烷烃，环烷烃和芳族化合物及其混合物，其包括在每一100ml中在所述有机液体中加入约0.01至20克聚合物复合物。 的所述有机液体，所述聚合物复合物在所述有机液体中“原位”形成或溶解在所述有机液体中，所述复合物由聚合物A组成，含有约4meq。 至500毫克 的中和磺酸盐基团和含有碱性氮基团的聚合物B，两个官能团的存在量为约4至500meq。 每100克 的聚合物，其中聚合物B具有下式：其中x为约50.0至99.8重量％，y为约0.2至约50.0重量％，其中所述聚合物A的所述磺酸盐基团用碱性化合物中和，所述碱性化合物选自 由过渡元素组成，所述聚合物A具有基本上可溶于所述有机液体的聚合物骨架，所述聚合物的分子量为约1,000至10,000,000。
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7.发明授权Novel polymer compositions based on sulfonated ionomers and amine containing polymers 失效基于磺化离聚物和含胺聚合物的新型聚合物组合物
公开(公告)号：US4617337A
公开(公告)日：1986-10-14
申请号：US673005
申请日：1984-11-19
摘要： A composition comprising interacting a blend of a neutralized sulfonated polymer containing from about 4 meq. of metal sulfonate per 100 g. of polymer up to 200 meq. per 100 g. of polymer, said sulfonate polymer being at least 95% neutralized, complexed with a second polymer containing basic nitrogen atoms incorporated, pyridine copolymerized or grafted thereon, said polymer containing basic nitrogen from about 4 meq. up to 500 meq. per 100 g. of polymer, wherein the molar ratio of metal sulfonate groups to that of basic nitrogen atoms varies from about 0.03 to about 30; wherein said polymer containing basic nitrogen groups have the formula: ##STR1## wherein R.sub.1 is an alkyl group having about 1 to about 8 carbon atoms, R.sub.2 is an alkyl group having about 1 to about 18 carbon atoms, x is about 50 to about 99.8 wt. %, and y is about 0.2 to about 50 wt. %.
摘要翻译： 一种组合物，其包含使含有约4meq的中和磺化聚合物的共混物相互作用。 的金属磺酸盐/ 100g。 的聚合物高达200meq。 每100克 的聚合物，所述磺酸盐聚合物至少95％中和，与含有碱性氮原子的第二聚合物络合，其中共聚或接枝的吡啶，所述聚合物含有约4meq的碱性氮。 高达500毫克 每100克 的聚合物，其中金属磺酸盐基团与碱式氮原子的摩尔比为约0.03至约30; 其中所述含有碱性氮基团的聚合物具有下式：其中R 1为具有约1至约8个碳原子的烷基，R 2为具有约1至约18个碳原子的烷基，x为约50至约99.8 重量 ％，y为约0.2至约50wt。 ％。
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公开(公告)号：US4483957A
公开(公告)日：1984-11-20
申请号：US551106
申请日：1983-11-14
IPC分类号： B05D5/08 , C08L23/32 , C08L57/00 , C08L101/00 , C08K5/05
CPC分类号： B05D5/08 , C08L101/00 , C08L23/32 , C08L57/00
摘要： The instant invention relates to a process for increasing the viscosity of organic liquids by incorporating in said liquid a minor amount of polymer complex, and 1 to 1000 parts per million by volume of a cosolvent for the ionic groups of said polymer. The polymer complex comprises the reaction product of a metal neutralized sulfonated polymer and a styrene-ring pyridene copolymer, wherein the polymer complex is substantially soluble in said organic liquid, and pendant sulfonate groups which are substantially insoluble in said organic liquid. The cosolvent is selected because it will solubilize the pendant sulfonate groups and provide a reasonably homogeneous mixture of solvent, cosolvent and ionomeric polymer. The preferred compositions prepared by the method of the instant invention comprise an organic liquid having a solubility parameter of from 6 to 10.5 in combination with a polymer complex containing from 0.2 up to 10.0 mole % sulfonate groups which has been neutralized by a basic material selected from Groups IA and IIA, IB and IIB of the Periodic Table of Elements (and also lead, tin and antimony) and 1 to 1000 parts per million by volume of a nonvolatile alcohol or amine cosolvent.
摘要翻译： 本发明涉及一种通过在所述液体中加入少量聚合物络合物来提高有机液体的粘度的方法，以及用于所述聚合物的离子基团的共溶剂的1至1000份（体积）。 聚合物络合物包括金属中和的磺化聚合物和苯乙烯 - 环的亚
甲基共聚物的反应产物，其中聚合物络合物基本上可溶于所说的有机液体中，以及基本上不溶于所说有机液体的磺酸根基侧基。 选择共溶剂是因为它将溶解磺酸根基团并提供合适的溶剂，共溶剂和离聚物聚合物的均匀混合物。 通过本发明的方法制备的优选组合物包含溶解度参数为6至10.5的有机液体与含有0.2至10.0摩尔％磺酸盐基团的聚合物复合物组合，该组合物已经被选自以下的碱性物质中和： 元素周期表IA和IIA，IB和IIB族元素（以及铅，锡和锑）和1至1000份/百万体积的不挥发性醇或胺助溶剂。-
公开(公告)号：US4157992A
公开(公告)日：1979-06-12
申请号：US855773
申请日：1977-11-29
CPC分类号： C08L23/32
摘要： The present invention relates to improved elastomeric blend compositions for injection molding and extrusion application having improved compression set, weathering stability and physical properties, wherein the improved elastomeric compositions include minimally a metal neutralized sulfonated EPDM terpolymer, a non-polar process oil, an inorganic filler, and a carbon black at critically selected concentration levels. These blend compositions can be readily processed due to their superior rheological properties on conventional plastic fabrication equipment, especially on low pressure injection molding equipment into elastomeric articles having excellent physical properties and desirable rubbery characteristics.
摘要翻译： 本发明涉及用于注射成型和挤出应用的改进的弹性体共混组合物，其具有改进的压缩永久变形，耐候性稳定性和物理性能，其中改进的弹性体组合物包括金属中和的磺化EPDM三元共聚物，非极性加工油，无机填料 ，和一个选定浓度水平的炭黑。 这些共混组合物由于其在常规塑料制造设备，特别是低压注塑设备上具有优异的物理性能和所需橡胶特性的弹性体制品中的优异的流变性能而可以容易地加工。
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公开(公告)号：US4127546A
公开(公告)日：1978-11-28
申请号：US855755
申请日：1977-11-29
IPC分类号： C08L23/00 , C08L7/00 , C08L21/00 , C08L23/26 , C08L23/32 , C08L33/00 , C08L33/02 , C08L101/00 , C08L93/00
CPC分类号： C08L23/32 , Y10S260/31
摘要： This invention relates to an improved elastomeric composition of metal neutralized sulfonated polymers which are plasticized with a preferential plasticizer at a concentration level of at least 1 part by weight based on 100 parts by weight of the metal neutralized EPDM terpolymer, wherein the preferential plasticizer is a metal rosin salt. The resultant compositions have improved physical properties and can be processed on conventional plastic fabrication equipment.
摘要翻译： 本发明涉及金属中和的磺化聚合物的改进的弹性体组合物，其基于100重量份的金属中和的三元共聚物三元共聚物，以优选的增塑剂增塑至少1重量份，其中， 优选的增塑剂是金属松香盐。 所得组合物具有改善的物理性能并且可以在常规塑料制造设备上加工。
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