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公开(公告)号：US5461106A
公开(公告)日：1995-10-24
申请号：US353850
申请日：1994-12-12
IPC分类号： C08F220/06 , C08F222/02
CPC分类号： C08F220/06
摘要： A solid polymeric latent initiator which is a dehydrated aqueous emulsion polymer of a monomer having an ethylenically unsaturated group and an organic salt group, the salt group being a product of an acid and a base, wherein either the acid or the base or the acid and the base are initiators capable of opening a strained heterocyclic ring system, provides rapid cure-on-demand one-part adhesives with improved shelf stability.
摘要翻译： 一种固体聚合物潜在引发剂，其是具有烯键式不饱和基团和有机盐基团的单体的脱水水性乳液聚合物，该盐基团是酸和碱的产物，其中酸或碱或酸和/ 碱是能够打开应变杂环系统的引发剂，提供快速的按需单组分粘合剂，具有改进的储存稳定性。
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2.发明授权Addition polymerizable adduct of a polymeric monoahl and an unsaturated isocyanate 失效聚合单烯烃和不饱和异氰酸酯的加成聚合加合物
公开(公告)号：US4394491A
公开(公告)日：1983-07-19
申请号：US195155
申请日：1980-10-08
申请人： Dwight K. Hoffman
发明人： Dwight K. Hoffman
CPC分类号： C08F283/06 , C08G18/283 , C08G18/635 , C08G18/8108 , Y10S525/92
摘要： An adduct of a monoahl, e.g., a monohydroxyl polyalkylene oxide, and an active ethylenically unsaturated isocyanate, e.g., 2-isocyanatoethyl methacrylate, is usefully employed in the preparation of stable copolymer dispersions of the type used in the production of polyurethane foams and polyurethane elastomers.The copolymer dispersion is prepared by addition copolymerization of (1) the adduct with (2) ethylenically unsaturated monomer(s), e.g., styrene or mixture thereof with acrylonitrile, while (1) and (2) are dispersed or dissolved in an excess of an active hydrogen polyfunctional compound.
摘要翻译： 单醛，例如单羟基聚环氧烷和活性烯键式不饱和异氰酸酯，例如甲基丙烯酸2-异氰酸酯基乙酯的加合物可用于制备用于生产聚氨酯泡沫和聚氨酯弹性体的类型的稳定的共聚物分散体 。 通过（1）加合物与（2）烯属不饱和单体（例如苯乙烯或其混合物）与丙烯腈的加成共聚合制备共聚物分散体，而（1）和（2）分散或溶解在过量的 一种活性氢多官能化合物。
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公开(公告)号：US5055532A
公开(公告)日：1991-10-08
申请号：US69997
申请日：1987-07-06
IPC分类号： C08F299/02
CPC分类号： C08F299/026
摘要： Vinylized epoxy resins, such as vinyl ester resins, comprise polymerizable ethylenic unsaturation and an in situ polymerized polymer, such as a polyalkyl acrylate. The vinylized epoxy resins can form stable dispersions and are useful in thermoset applications.
摘要翻译： 乙烯基酯树脂等乙烯基化环氧树脂包括可聚合的烯属不饱和基团和原位聚合的聚合物，如聚丙烯酸烷基酯。 乙烯基化环氧树脂可以形成稳定的分散体，并且可用于热固性应用。
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公开(公告)号：US4789712A
公开(公告)日：1988-12-06
申请号：US83135
申请日：1987-08-10
IPC分类号： C08F283/10 , C08F299/02 , C08L63/10
CPC分类号： C08F299/026 , C08F283/10 , Y10S525/922
摘要： Dispersions of polymers and optional dispersion stabilizers in a polyepoxide resin continuous phase is characterized in that the dispersion remains stable above 60.degree. C. The compositions are curable and are useful as coatings, in preparing laminates and reinforced plastics, and as adhesives. The compositions exhibit properties which are superior to compositions containing reactive liquid polymers.
摘要翻译： 聚合物和任选的分散体稳定剂在聚环氧化物树脂连续相中的分散体的特征在于，分散体在60℃以上保持稳定。组合物是可固化的，并且可用作制备层压板和增强塑料以及作为粘合剂的涂料。 该组合物显示出优于含有反应性液体聚合物的组合物的性能。
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公开(公告)号：US4431754A
公开(公告)日：1984-02-14
申请号：US353709
申请日：1982-03-01
申请人： Dwight K. Hoffman
发明人： Dwight K. Hoffman
IPC分类号： C08F283/00 , C08G18/63 , C08G18/14
CPC分类号： C08G18/635 , C08F283/00 , C08G18/63 , C08G2105/02
摘要： A low viscosity copolymer polyahl dispersion is prepared by polymerizing polymer particles in a polyahl medium, to a first solids concentration and thereafter diluting the dispersion to a second lower solids concentration. The resulting diluted dispersion has a lower viscosity than if the dispersion were prepared directly at the lower solids level. The invention has particular advantage when used with "all acrylonitrile" dispersions. The copolymer polyahl dispersions are useful in the manufacture of urethane and isocyanurate foams.
摘要翻译： 通过将多聚烯烃介质中的聚合物颗粒聚合至第一固体浓度，然后将分散体稀释至第二较低固体浓度来制备低粘度共聚物聚烯烃分散体。 所得到的稀释分散体的粘度低于直接在较低固体含量下制备分散体的粘度。 当与“所有丙烯腈”分散体一起使用时，本发明具有特别的优点。 共聚物聚乙烯分散体可用于制备聚氨酯和异氰脲酸酯泡沫。
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6.发明授权Cure on demand adhesives and window module with cure on demand adhesive thereon 有权固化按需粘合剂和窗口模块，在其上固化需要的粘合剂公开(公告)号：US06613816B2
公开(公告)日：2003-09-02
申请号：US09875986
申请日：2001-06-07
IPC分类号： C08G7708
CPC分类号： C09J175/08 , C08G18/10 , C08G18/12 , C08G18/24 , C08G18/246 , C08G18/4808 , C08G18/4825 , C08G18/718 , C08G65/2642 , C08G65/2651 , C08G65/336 , C08G2190/00 , C09J171/02 , Y10T428/31601 , Y10T428/31612 , Y10T428/31645 , C08G18/307 , C08G18/3893
摘要： In one embodiment the invention is An adhesive composition comprising a) a polymer having a flexible backbone and a reactive moiety capable of cross-linking, b) a particle comprising an active agent encapsulated in an encapsulating agent wherein the active agent comprises a catalyst for cross-linking of the reactive moiety, a curing agent for the reactive moiety, an accelerator for the curing reaction or a mixture thereof; and the encapsulating agent comprises a side chain crystallizable polymer wherein the active agent is not substantially extractable from the particle at ambient conditions in a first extraction after particle formation.
摘要翻译： 在一个实施方案中，本发明是一种粘合剂组合物，其包含a）具有柔性主链和能够交联的反应性部分的聚合物，b）包含包封在包封剂中的活性剂的颗粒，其中活性剂包含用于交联的催化剂， 反应性部分的连接，反应性部分的固化剂，用于固化反应的促进剂或其混合物;并且所述包封剂包含侧链可结晶聚合物，其中活性剂在环境条件下基本上不可从颗粒中提取 颗粒形成后的第一次提取。
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公开(公告)号：US6133398A
公开(公告)日：2000-10-17
申请号：US291146
申请日：1999-04-13
IPC分类号： C08G18/10 , C08G18/12 , C08G18/48 , C09J175/04
CPC分类号： C09J175/04 , C08G18/10 , C08G18/12 , C08G18/4812
摘要： The present invention is a one-part adhesive composition comprising:A) an isocyanate functional polyurethane prepolymer;B) a catalyst capable of catalyzing the reaction of isocyanate moieties with an isocyanate reactive compound;C) particles comprising a curing agent for an isocyanate functional. polyurethane prepolymer encapsulated within a coating material;wherein the prepolymer has a free isocyanate content of from about 0.8 to about 2.2 percent. In another embodiment the invention is a process for bonding two substrates together which comprises rupturing the encapsulated curing agent particles so as to contact the curing agent with the prepolymer in the adhesive composition, contacting the adhesive composition of the invention with at least one of the substrates and contacting the substrates together along the portion of the substrate(s) to which the adhesive has been applied before the adhesive applied cures and allowing the adhesive to cure and bond the substrates together.
摘要翻译： 本发明是一种单组分粘合剂组合物，其包含：A）异氰酸酯官能聚氨酯预聚物; B）能够催化异氰酸酯部分与异氰酸酯反应性化合物的反应的催化剂; C）包含异氰酸酯官能团的固化剂的颗粒。 包封在涂料中的聚氨酯预聚物; 其中所述预聚物的游离异氰酸酯含量为约0.8至约2.2％。 在另一个实施方案中，本发明是用于将两个基底结合在一起的方法，其包括使包封的固化剂颗粒破裂，以使固化剂与粘合剂组合物中的预聚物接触，使本发明的粘合剂组合物与至少一个底物接触 并且在粘合剂施加之前沿着已经施加有粘合剂的基底的部分将基底接触在一起，并且使粘合剂固化并将基底粘合在一起。
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公开(公告)号：US4707529A
公开(公告)日：1987-11-17
申请号：US749249
申请日：1985-06-27
IPC分类号： C08F299/02 , C08F299/08 , C08G81/00 , C08L63/00 , C08F283/10
CPC分类号： C08G81/00 , C08F299/026 , C08F299/08 , C08L63/00
摘要： Dispersions of siloxane polymers and optional dispersion stabilizers in a polyepoxide resin continuous phase are characterized in that the siloxane polymer is grafted to the polyepoxide resin, and the dispersions remain stable. The compositions are curable and are useful as coatings, in preparing laminates and reinforced plastics, and as adhesives.
摘要翻译： 硅氧烷聚合物和任选的分散稳定剂在聚环氧化物树脂连续相中的分散体的特征在于硅氧烷聚合物接枝到聚环氧树脂上，分散体保持稳定。 组合物是可固化的，并且可用作涂层，在制备层压材料和增强塑料中以及作为粘合剂。
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公开(公告)号：US4690988A
公开(公告)日：1987-09-01
申请号：US693411
申请日：1985-01-22
IPC分类号： C08F299/02 , C08G8/30 , C08L63/10
CPC分类号： C08F299/026
摘要： Vinylized epoxy resins, such as vinyl ester resins, comprise polymerizable ethylenic unsaturation and an in situ polymerized polymer, such as a polyalkyl acrylate. The vinylized epoxy resins can form stable dispersions and are useful in thermoset applications.
摘要翻译： 乙烯基酯树脂等乙烯基化环氧树脂包括可聚合的烯属不饱和基团和原位聚合的聚合物，如聚丙烯酸烷基酯。 乙烯基化环氧树脂可以形成稳定的分散体，并且可用于热固性应用。
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公开(公告)号：US06224793B1
公开(公告)日：2001-05-01
申请号：US09300339
申请日：1999-04-27
IPC分类号： B01J1302
CPC分类号： B01J13/04 , B01J13/20 , Y10T428/2984 , Y10T428/2985 , Y10T428/2987 , Y10T428/2989
摘要： The invention is an encapsulated active agent comprising an active agent encapsulated in a crystallizable or thermoplastic polymer wherein the particle size of the encapsulated active agent is 3,000 microns or less wherein the active agent is not significantly extractable from the particles under ambient conditions. In another embodiment the invention is a process for preparing an encapsulated agent which comprises a) contacting an active agent with a crystallizable or thermoplastic polymer wherein the polymer is molten and the active agent in not volatile under the contacting conditions; b) forming particles of about 3000 microns or less; and c) exposing the particles to conditions such that the portion of the particle at and near the surface undergoes rapid solidification. The encapsulated active agents of the invention do not require washing in order for them to be stable in curable compositions. These encapsulated active agents can be designed to release the active agent at a desired temperature. The encapsulated agents of the invention demonstrate excellent stability at ambient temperatures and exhibit relatively rapid reactivity upon release of the active agent. Furthermore, the presence of the encapsulating agent does not result in deterioration of adhesive or elastomer properties of a cured composition after preparation.
摘要翻译： 本发明是一种包封的活性剂，其包含包封在可结晶或热塑性聚合物中的活性剂，其中包封的活性剂的粒径为3,000微米或更小，其中活性剂在环境条件下不能从颗粒中显着提取。 在另一个实施方案中，本发明是一种制备包封剂的方法，其包括：a）使活性剂与可结晶或热塑性聚合物接触，其中聚合物熔融，活性剂在接触条件下不挥发; b）形成约3000微米或更小的颗粒; 和c）将颗粒暴露于使表面处和附近的颗粒部分快速凝固的条件。 本发明的包封的活性剂不需要洗涤，以使它们在可固化组合物中稳定。 这些包封的活性剂可以设计成在所需温度下释放活性剂。 本发明的包封的试剂在环境温度下表现出优异的稳定性，并且在释放活性剂时表现出相对快速的反应性。 此外，包封剂的存在不会导致制备后的固化组合物的粘合剂或弹性体性能的劣化。
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