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公开(公告)号：US4069170A
公开(公告)日：1978-01-17
申请号：US750027
申请日：1976-12-13
申请人： Robert J. Blake , Guy W. Roy
发明人： Robert J. Blake , Guy W. Roy
摘要： Catalyst compositions comprising mixtures of salts of copper, potassium, didymium, lanthanum and magnesium are useful in the fluidized bed oxychlorination of aliphatic hydrocarbons. The catalyst composition loading is disposed on a suitable support media, preferably an alumina and does not cake or cause defluidization of the bed under start-up, operating, or shut-down conditions.
摘要翻译： 包含铜，钾，钕，镧和镁的盐的混合物的催化剂组合物可用于脂族烃的流化床氧氯化。 将催化剂组合物负载设置在合适的载体介质上，优选氧化铝，并且不会在启动，运行或停机条件下使床脱粘或引起床层流化。
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公开(公告)号：US4284833A
公开(公告)日：1981-08-18
申请号：US862242
申请日：1977-12-19
申请人： Robert J. Blake , Guy W. Roy
发明人： Robert J. Blake , Guy W. Roy
IPC分类号： B01J23/94 , C07C17/154 , C07C17/152
CPC分类号： B01J23/94 , C07C17/154 , Y02P20/584 , Y10S502/517
摘要： The active life of an oxychlorination copper-containing catalyst is extended by the removal of sulfur-containing compounds from the gases fed to the catalyst reaction zone. A copper-containing oxychlorination catalyst which has been deactivated by the deposition of sulfur compounds thereon is reactivated in situ by operating the catalyst bed in an oxygen-free atmosphere for a sufficient period of time. The reactivation of the catalyst is completed when the conversions of hydrocarbon and chlorinating agent to chlorinated products indicate a high level of catalyst activity, as determined by an analysis of the gaseous effluent leaving the catalyst bed.
摘要翻译： 通过从供给到催化剂反应区的气体中除去含硫化合物来延长含氧氯化铜催化剂的活性。 通过在其上沉积硫化合物而使其失活的含铜氧氯化催化剂在现场通过在无氧气氛中操作催化剂床足够长的时间来再活化。 当烃和氯化剂转化为氯化产物时，催化剂的再活化可以完成，如通过离开催化剂床的气态流出物的分析所确定的高水平的催化剂活性。
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公开(公告)号：US4594076A
公开(公告)日：1986-06-10
申请号：US554818
申请日：1983-11-23
CPC分类号： C09K3/185
摘要： This invention is directed to the reduction of the strength of ice in association with solid particulate materials, such as, for example, coal, by applying to the solid particulate material, prior to exposure to water freezing conditions, a composition comprising a mixture of a glycol derived from ethylene oxide and containing from 1 to 4 oxyethylene units and an alkyl and/or an aryl ether of a glycol derived from ethylene oxide and/or propylene oxide and containing from 1 to 9 oxyalkylene units.
摘要翻译： 本发明涉及通过在暴露于水冻结条件之前施加至固体颗粒材料，与固体颗粒材料（例如煤）相结合来降低冰的强度，所述组合物包含 衍生自环氧乙烷并含有1至4个氧化乙烯单元的二元醇和衍生自环氧乙烷和/或环氧丙烷并含有1至9个氧化烯单元的二醇的烷基和/或芳基醚。
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4.发明授权Method of reducing the strength of adhesion of solid particulate materials to metal surfaces 失效降低固体颗粒材料粘附到金属表面的强度的方法
公开(公告)号：US4339338A
公开(公告)日：1982-07-13
申请号：US189630
申请日：1980-09-22
CPC分类号： B05D5/08 , B05D7/14 , Y10T428/31678
摘要： This invention is directed to a method for reducing the strength of adhesion of solid particulate materials to metal surfaces as occurs under water freezing conditions by coating the metal surface with a mixture comprising a hydrocarbon liquid which has a solidification or pour point not greater than 0.degree. F. and a saturated or unsaturated fatty acid having from about 10 to about 18 carbon atoms.
摘要翻译： 本发明涉及一种降低固体颗粒材料在水冷条件下发生粘附强度的方法，方法是用含有固化或倾点不大于0℃的烃液体的混合物涂覆金属表面 以及具有约10至约18个碳原子的饱和或不饱和脂肪酸。
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