Fluidized bed apparatus for the mixing of fluids and solids
    5.
    发明授权
    Fluidized bed apparatus for the mixing of fluids and solids 失效
    用于混合流体和固体的流化床装置

    公开(公告)号:US4861562A

    公开(公告)日:1989-08-29

    申请号:US600594

    申请日:1984-04-16

    申请人: Frederick Rowe

    发明人: Frederick Rowe

    摘要: Process and apparatus for fluidized bed mixing of fluids and gases in which the fluid is injected with a high angular velocity through a relatively narrow, preferably single, orifice (3). The angular velocity may be imparted by injecting the fluid at high velocity tangentially at the periphery of the squate chamber (4) so that angular momentum is gained as it spirals inwards towards orifice (3). Optionally, an open-topped hopper (5) for solids is suspended above orifice (3). The lower end of the hopper (5) terminates in a second orifice (7) located vertically above orifice (3). The solid particles are thereby swept radially outwards towards the wall of the chamber (1) in co-current admixture with the fluid.

    摘要翻译: 流体和流体混合流体和气体的方法和装置,其中流体以较高的角速度通过较窄的,优选单个的孔口(3)注入。 角速度可以通过以高速切向地在空心室(4)的周边喷射流体来实现,使得当其朝向孔口(3)向内螺旋时获得角动量。 可选地,用于固体的开顶料斗(5)悬挂在孔口(3)上方。 料斗(5)的下端终止于位于孔口(3)上方的垂直上方的第二孔口(7)。 因此,固体颗粒以与流体同时混合的方式向腔室(1)的壁径向向外扫掠。

    Recovery of ethylene, chlorine and HCl from vented waste gas from direct
chlorination reactor
    6.
    发明授权
    Recovery of ethylene, chlorine and HCl from vented waste gas from direct chlorination reactor 失效
    从直接氯化反应器排出的废气中回收乙烯,氯和HCl

    公开(公告)号:US4760207A

    公开(公告)日:1988-07-26

    申请号:US908744

    申请日:1986-09-18

    申请人: Joseph A. Cowfer

    发明人: Joseph A. Cowfer

    摘要: In a process for producing 1,2-dichloroethane or ethylene dichloride ("EDC") in a high temperature direct chlorination ("HTDC") reactor in which ethylene is reacted with wet chlorine having a water content more than 100 ppm but no more than 1% by wt of the chlorine, the water leaves the reactor with the EDC product draw-off, either in the vapor overhead (if the HTDC is a boiling reactor), or, as a liquid sidestream (if the HTDC is a non-boiling reactor). In a subsequent step, the EDC draw-off is distilled in a product distillation column in which the water leaves in the overhead which is condensed to remove condensables in a first stage, and vent a non-condensable vent streams. The vent stream is corrosive due to the presence of minor amounts of chlorine, HCl and water, along with oxygen which is injected into the HTDC to improve selectivity of the reaction. The vent gases from the first stage are further cooled to a temperature in the range from about -30.degree. C. to about 0.degree. C. to condense condensables and freeze water without plugging the liquid lines. Plugging is avoided provided the vent stream contains less than 1.5% by wt of water, based on the weight of the vent stream. The essentially moisture-free non-condensables remaining are relatively non-corrosive and may be recycled to an oxychlorination reactor, also for the production of EDC, without unduly sacrificing the vent compressor and other carbon steel equipment in the recycle line.

    摘要翻译: 在高温直接氯化(“HTDC”)反应器中制备1,2-二氯乙烷或二氯乙烷(“EDC”)的方法中,其中乙烯与水含量大于100ppm但不超过 1%(重量)的氯,水在蒸汽塔顶(如果HTDC是沸腾反应器)中离开反应器,EDC产物排出,或作为液体侧流(如果HTDC是非离子表面活性剂) 沸腾反应器)。 在随后的步骤中,在产物蒸馏塔中蒸馏EDC馏出物,其中水在塔顶馏出,其被冷凝以在第一阶段除去可冷凝物,并排出不可冷凝的排放物流。 由于存在少量的氯,HCl和水以及注入HTDC中的氧气以提高反应的选择性,排气流是腐蚀性的。 来自第一阶段的排出气体进一步冷却至约-30℃至约0℃的温度,以冷凝可冷凝物和冷冻水而不堵塞液体管线。 避免堵塞,只要排气流含有小于1.5重量%的水,基于排气流的重量。 剩余的基本上不含湿气的不可冷凝物是相对非腐蚀性的,并且可以再循环到氧氯化反应器中,也用于生产EDC,而不会过度地牺牲再循环管线中的排气压缩机和其它碳钢设备。

    Process for making methyl iodide from methane
    7.
    发明授权
    Process for making methyl iodide from methane 失效
    从甲烷制备甲基碘的方法

    公开(公告)号:US4731494A

    公开(公告)日:1988-03-15

    申请号:US31804

    申请日:1987-03-30

    IPC分类号: C07C17/154 C07C17/10

    CPC分类号: C07C17/154

    摘要: A process for making methyl iodide is disclosed. In this process methane, and a source of oxygen are introduced into a molten salt, maintained at a temperature of at least about 500.degree. C., said molten salt comprising an iodide of a metal selected from the group consisting of alkali metals, alkaline earth metals and mixtures thereof and a catalyst comprising at least one metal selected from the group consisting of a metal of Group IB and Group VIII of the Periodic Table of the Elements with the proviso that said methane and said source of oxygen do not contact each other.

    摘要翻译: 公开了制备甲基碘的方法。 在该方法中,将甲烷和氧源引入熔融盐中,保持在至少约500℃的温度,所述熔融盐包含选自碱金属,碱土金属 金属及其混合物,以及包含至少一种选自元素周期表第IB族和第VIII族金属的金属的催化剂,条件是所述甲烷和所述氧源不相互接触。

    Production of chlorinated hydrocarbons
    9.
    发明授权
    Production of chlorinated hydrocarbons 失效
    生产氯化碳氢化合物

    公开(公告)号:US3949010A

    公开(公告)日:1976-04-06

    申请号:US458654

    申请日:1974-04-08

    申请人: Morgan C. Sze

    发明人: Morgan C. Sze

    CPC分类号: B01J10/005 C07C17/15

    摘要: Oxidized molten chloride salts are employed for chlorinating and/or oxychlorinating a feed in a first reactor and then passed by gravity to a second reactor situated below the first reactor and operated at a pressure higher than the first reactor wherein the molten salt is oxidized. The oxidized salt is returned to the first reactor. Vinyl chloride or chloromethanes can be produced by the process.

    摘要翻译: 氧化的氯化氯盐用于在第一反应器中对进料进行氯化和/或氧氯化,然后通过重力通过位于第一反应器下方的第二反应器,并在高于熔融盐被氧化的第一反应器的压力下操作。 将氧化的盐返回到第一反应器。 可以通过该过程生产氯乙烯或氯甲烷。