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公开(公告)号：US06506297B1
公开(公告)日：2003-01-14
申请号：US09547809
申请日：2000-04-11
IPC分类号： C10G7100
CPC分类号： C10G45/58 , C10G67/04 , C10G2400/10 , C10G2400/12 , C10G2400/14 , C10M107/02 , C10M2205/173 , C10N2220/028 , C10N2270/00
摘要： Discloses novel biodegradable high performance hydrocarbon base oils useful as lubricants in engine oil and industrial compositions, and process for their manufacture. A waxy, or paraffinic feed, particularly a Fischer-Tropsch wax, is reacted over a dual function catalyst to produce hydroisomerization and hydrocracking reactions, at 700° F.+ conversion levels ranging from about 20 to 50 wt. %, preferably about 25-40 wt. %, sufficient to produce a crude fraction, e.g., a C5-1050° F.+ crude fraction, containing 700° F.+ isoparaffins having from about 6.0 to about 7.5 methyl branches per 100 carbon atoms in the molecule. The methyl paraffins containing crude fraction is topped via atmospheric distillation to produce a bottoms fraction having an initial boiling point between about 650° F. and 750° F. which is then solvent dewaxed, and the dewaxed oil is then fractionated under high vacuum to produce biodegradable high performance hydrocarbon base oils.
摘要翻译： 公开了可用作发动机油和工业组合物中的润滑剂的新型可生物降解的高性能烃基油及其制造方法。 蜡状或石蜡原料，特别是费 - 托蜡在双功能催化剂上反应，产生加氢异构化和加氢裂化反应，在700°F +转化率范围为约20至50wt。 ％，优选约25-40wt。 ％，足以产生含有分子中每100个碳原子具有约6.0至约7.5个甲基支链的含有700°F +的异构烷烃的粗馏分，例如C5-1050°F +粗馏分。 含有粗制部分的甲基链烷烃通过常压蒸馏来顶部，产生沸点在约650°F至750°F之间的塔底馏分，然后进行溶剂脱蜡，然后将脱蜡油在高真空下分馏， 可生物降解的高性能烃基油。
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公开(公告)号：US6096940A
公开(公告)日：2000-08-01
申请号：US121320
申请日：1998-07-22
IPC分类号： B01J23/88 , B01J23/89 , C10G2/00 , C10G45/58 , C10G45/60 , C10G45/62 , C10G47/02 , C10G47/12 , C10G47/14 , C10G65/04 , C10G65/12 , C10G67/04 , C10G67/14 , C10G73/06 , C10M101/02 , C10M107/02 , C10N40/25 , C10G57/00 , C10G47/00 , C10G47/20
CPC分类号： C10G45/58 , C10G67/04 , C10M107/02 , C10G2400/10 , C10G2400/12 , C10G2400/14 , C10M2205/173 , C10N2220/028 , C10N2270/00
摘要： Discloses novel biodegradable high performance hydrocarbon base oils useful as lubricants in engine oil and industrial compositions, and process for their manufacture. A waxy, or paraffinic feed, particularly a Fischer-Tropsch wax, is reacted over a dual function catalyst to produce hydroisomerization and hydrocracking reactions, at 700.degree. F.+ conversion levels ranging from about 20 to 50 wt. %, preferably about 25-40 wt. %, sufficient to produce a crude fraction, e.g., a C.sub.5 -1050.degree. F.+ crude fraction, containing 700.degree. F.+ isoparaffins having from about 6.0 to about 7.5 methyl branches per 100 carbon atoms in the molecule. The methyl paraffins containing crude fraction is topped via atmospheric distillation to produce a bottoms fraction having an initial boiling point between about 650.degree. F. and 750.degree. F. which is then solvent dewaxed, and the dewaxed oil is then fractionated under high vacuum to produce biodegradable high performance hydrocarbon base oils.
摘要翻译： 公开了可用作发动机油和工业组合物中的润滑剂的新型可生物降解的高性能烃基油及其制造方法。 蜡状或石蜡原料，特别是费 - 托蜡在双重功能催化剂上反应，在700°F下进行加氢异构化和加氢裂化反应。转化率范围为约20至50wt。 ％，优选约25-40wt。 ％，足以产生粗分馏，例如含有分子中每100个碳原子的约6.0至约7.5个甲基支链的含有700°F +异链烷烃的C5-1050°F +粗级分。 含有粗馏分的甲基链烷烃通过常压蒸馏来顶部，产生沸点在约650°F至750°F之间的塔底馏分，然后进行溶剂脱蜡，然后将脱蜡油在高真空下分馏， 可生物降解的高性能烃基油。
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公开(公告)号：US5807413A
公开(公告)日：1998-09-15
申请号：US691769
申请日：1996-08-02
CPC分类号： C10L1/08
摘要： A diesel engine fuel is produced from Fischer-Tropsch wax by separating a light density fraction, e.g., C.sub.5 -C.sub.15, preferably C.sub.7 -C.sub.14 cut having at least 80+ wt % n-paraffins, no more than 5000 ppm alcohols as oxygen, less than 10 wt % olefins, twice aromatics and very low sulfur and nitrogen.
摘要翻译： 通过分离光密度分数，例如C5-C15，优选具有至少80重量％正链烷烃的C7-C14切割，不超过5000ppm的醇作为氧，柴油发动机燃料减少 超过10重量％的烯烃，两次芳烃和非常低的硫和氮。
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公开(公告)号：US06607568B2
公开(公告)日：2003-08-19
申请号：US09771408
申请日：2001-01-26
IPC分类号： C10L108
摘要： Diesel fuels or blending stocks having excellent lubricity, oxidative stability and high cetane number are produced from non-shifting Fischer-Tropsch processes by separating the Fischer-Tropsch product into a lighter and heavier fractions, e.g., at about 700° F., subjecting the 700° F.+ fraction to hydro-treating, and combining the 700° F.− portion of the hydrotreated product with the lighter fraction that has not been hydrotreated.
摘要翻译： 通过将费 - 托产物分离成更轻和更重的馏分（例如在约700°F），将非挥发性费 - 托方法从具有优异的润滑性，氧化稳定性和高十六烷值的柴油燃料或混合原料生产， 加热处理的700°F +级分，并将加氢处理产物的700°F部分与尚未加氢处理的较轻级分组合。
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公开(公告)号：US06296757B1
公开(公告)日：2001-10-02
申请号：US08544343
申请日：1995-10-17
IPC分类号： C10G1400
摘要： Diesel fuels or blending stocks having excellent lubricity, oxidative stability and high cetane number are produced from non-shifting Fischer-Tropsch processes by separating the Fischer-Tropsch product into a lighter and heavier fractions, e.g., at about 700° F., subjecting the 700° F.+fraction to hydro-treating, and combining the 700° F.− portion of the hydrotreated product with the lighter fraction that has not been hydrotreated.
摘要翻译： 通过将费 - 托产物分离成更轻和更重的馏分（例如在约700°F），将非挥发性费 - 托方法从具有优异的润滑性，氧化稳定性和高十六烷值的柴油燃料或混合原料生产， 加热处理的700°F +级分，并将加氢处理产物的700°F部分与尚未加氢处理的较轻级分组合。
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公开(公告)号：US06274029B1
公开(公告)日：2001-08-14
申请号：US09464179
申请日：1999-12-16
IPC分类号： C10L104
摘要： Diesel fuels or blending stocks having excellent lubricity, oxidative stability and high cetane number are produced from non-shifting Fischer-Tropsch processes by separating the Fischer-Tropsch product into a lighter and heavier fractions, e.g., at about 700° F., subjecting the 700° F.+fraction to hydro-treating, and combining the 700° F.+portion of the hydrotreated product with the lighter fraction that has not been hydrotreated.
摘要翻译： 通过将费 - 托产物分离成更轻和更重的馏分（例如在约700°F），将非挥发性费 - 托方法从具有优异的润滑性，氧化稳定性和高十六烷值的柴油燃料或混合原料生产， 加热处理的700°F +级分，并将加氢处理的产物的700°F +部分与未加氢处理的较轻级分组合。
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公开(公告)号：US07096931B2
公开(公告)日：2006-08-29
申请号：US09877610
申请日：2001-06-08
申请人： Min Chang , Richard Frank Bauman
发明人： Min Chang , Richard Frank Bauman
CPC分类号： C10G2/344 , B01J8/1836 , B01J8/22 , B01J2208/00132 , F28F1/16 , F28F1/26 , F28F1/36
摘要： Ribbed heat exchange tubes in which the aspect ratio of the ribs is less than 5, provide greater indirect heat exchange than conventional heat exchange tubes with or without fins, when used in a slurry comprising a liquid phase, in which is dispersed flowing gas bubbles or particulate solids and flowing gas bubbles. The ribs, and typically also the longitudinal axis of the heat exchange tubes, are aligned in a direction parallel to, or spirally along the gas bubble flow direction. This is useful to increase either (i) the productivity of a slurry Fischer-Tropsch hydrocarbon synthesis reactor without an increase in the temperature in the reactor or (ii) increasing the production of higher molecular weight hydrocarbons by reducing the reaction temperature at a given feed conversion.
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