摘要:
A gas containing oxygen, H.sub.2 S and sulfur oxides is desulfurized by contacting same with cerium oxide at a temperature of from about 350.degree.-600.degree. C. This invention is particularly useful for desulfurizing tail gas from a Claus plant. In a preferred embodiment the cerium oxide is supported on alumina and oxygen is present in the gas in an amount more than that stoichiometrically required to convert the H.sub.2 S and SO.sub.2 to cerium oxysulfate.
摘要:
Methods, systems, apparatus and processes for determining the lithology as well as the mineralogy of subterranean formations surrounding a borehole are described. According to the methods and processes, well log data measurements from neutron spectroscopy applications and associated tool response parameters are solved using an artificial intelligence system, such as an expert system, which in turn generates an appropriate discriminator and/or compositional model that estimates both general and specific lithology as well as the mineralogy constraints of the subterranean formation being analyzed. The methods exhibit good elemental correlation between conventional methods of lithology and mineralogy determination, and can provide numerous output data, including grain density and porosity data within zones of the formation.
摘要:
A process for the preparation of high surface area mixed metal oxides by decomposition of solid solutions of carbonates possessing the calcite structure. Oxide compounds comprising mixtures of Ca, Mn, Fe, Co, Ni, Zn, Cd and Mg can be prepared by this method. For example, CaMnO.sub.3 with a surface area of 11 m.sup.2 /g useful as a battery cathode, has been prepared by the instant method, that is, by decomposition of a CaMn(CO.sub.3).sub.2 precursor.The mixed metal carbonate solid solutions which are used as precursors for the preparation of the mixed metal oxides are themselves prepared by the precipitation from solution of the appropriate metal ions by the addition of an excess of a carbonate ion source (such as (NH.sub.4).sub.2 CO.sub.3). The metal-ion ratio in this solution is adjusted so that the resulting precipitate has the same stoichiometry as the desired oxide. The intimate mixing achieved by using the carbonate precipitation technique allows calcination to metal oxide to be run at lower temperatures for shorter periods of time, thereby achieving higher surface areas.
摘要:
A novel battery is disclosed in which the cathode active material is an oxide having a perovskite or perovskite related structure and the general formula ABO.sub.3, wherein A is an element selected from Group IIA of the Periodic Table of the Elements and B is a non-noble transition metal selected from Group VIIB and VIII of the periodic Table of the Elements. The anode is a metal selected from cadmium, zinc, lead, lithium, sodium and potassium.
摘要:
A method for estimating a lithotype of an earth formation, the method includes: obtaining at least two different energy spectra of radiation received from the earth formation using the logging tool, each energy spectrum having at least one of a natural gamma-ray spectrum, a fast neutron-induced inelastic spectrum, and a thermal neutron induced capture spectrum; establishing at least one geochemically-based constraint related to elemental spectral yields to be determined; determining the elemental spectral yields from the at least two different energy spectra by decomposing the at least two different energy spectra over weighted sum of monoelemental standards wherein at least one weight is constrained by the at least one geochemically-based constraint and each weight represents a proportion of one monoelemental standard; converting the elemental spectral yields to elemental concentrations; and using a classifier to receive the elemental concentrations as input and to provide a lithotype as output.
摘要:
Methods, systems, apparatus and processes for determining the lithology as well as the mineralogy of subterranean formations surrounding a borehole are described. According to the methods and processes, well log data measurements from neutron spectroscopy applications and associated tool response parameters are solved using an artificial intelligence system, such as an expert system, which in turn generates an appropriate discriminator and/or compositional model that estimates both general and specific lithology as well as the mineralogy constraints of the subterranean formation being analyzed. The methods exhibit good elemental correlation between conventional methods of lithology and mineralogy determination, and can provide numerous output data, including grain density and porosity data within zones of the formation.
摘要:
A low value of Th/U ratio as determined from natural gamma radiation is indicative of deepwater sedimentation. This, together with estimates of total organic carbon from pulsed neutron measurements, is used to characterize source rocks. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understand that it will not be used to interpret or limit the scope or meaning of the claims.
摘要:
A method for electrocatalytically reacting various oxidizable organic compounds by introducing current by means of an anode into an electrolyte of a cell containing the oxidizable organic compound. The anode comprises an electrocatalyst material which has at least one compound of the formula:A.sub.2 [B.sub.2-x B'.sub.x ]O.sub.7-ywherein A is selected from any of the pyrochlore structure metal cations in a group consisting of: Pb, Bi, and Tl, wherein B' is selected from any of the pyrochlore structure metal cations in a group consisting of Pb, Bi, Tl, and Sn; wherein B is a pyrochlore structure metal cation at least a major portion of which is selected from a group consisting of at least one of: Ru, Rh, Ir, and Os, wherein y is equal to or greater than zero and equal to or less than one; and wherein x is equal to or less than one and equal to or greater than zero.
摘要:
Nonstoichiometric carbon-sulfur compounds have been found to be effective adsorbents for separating organic vapors from a gaseous mixture. Separation of aromatic compounds from gaseous mixtures is particularly effective using such compounds. The spent adsorbent may then be regenerated.
摘要:
A liquid solution method of preparing electrically conductive pyrochlore compounds having the formula:A.sub.2 [B.sub.2-x A.sub.x ]O.sub.7-yis disclosed wherein A is selected from lead, bismuth and mixtures thereof, B is selected from ruthenium, iridium and mixtures thereof, 0.ltoreq..times..ltoreq.1.0 and 0.ltoreq.y.ltoreq.1. The method involves reacting A and B cations to yield a pyrochlore oxide by precipitation of A and B cations in a liquid medium having a pH which is equal to or greater than 4.5, but less than 13.5, in the presence of an oxygen source at a temperature below about 200.degree. C. for a time sufficient for reaction to occur. In those instances in which amorphous reaction products are obtained, these amorphous reaction products are subsequently heat treated at a temperature of about 200.degree. C. to about 600.degree. C. for a time sufficient to convert amorphous reaction products to crystalline pyrochlore(s).
摘要翻译:公开了一种制备具有下式的导电烧绿石化合物的液体溶液方法:其中A选自铅,铋及其混合物,B选自钌,铱及其混合物, /=x=1.0和0 = y = 1。 该方法包括使A和B阳离子反应,通过在pH为等于或大于4.5但小于13.5的液体介质中,在氧源的存在下,在A 温度低于约200℃,持续足以产生反应的时间。 在获得无定形反应产物的情况下,随后将这些无定形反应产物在约200℃至约600℃的温度下热处理足以将无定形反应产物转化为结晶烧绿石的时间。