摘要:
A process and catalyst for the hydro-oxidation of an olefin having three or more carbon atoms, such as propylene, to form an olefin oxide, such as propylene oxide. The process involves contacting the olefin with oxygen in the presence of hydrogen and a hydro-oxidation catalyst under reaction conditions; the catalyst comprising gold nanoparticles deposited on a nanoporous titanium-containing support, prepared by depositing a gold-ligand cluster complex onto the support to form a catalyst precursor, and then heating and/or chemically treating the catalyst precursor to form the hydro-oxidation catalyst composition. The hydro-oxidation catalyst exhibits stabilized catalyst activity, enhanced lifetime, and improved hydrogen efficiency.
摘要:
A process and catalyst for the hydro-oxidation of an olefin having three or more carbon atoms, such as propylene, to form an olefin oxide, such as propylene oxide. The process involves contacting the olefin with oxygen in the presence of hydrogen and a hydro-oxidation catalyst under reaction conditions; the catalyst comprising gold nanoparticles deposited on a nanoporous titanium-containing support, prepared by depositing a gold-ligand cluster complex onto the support to form a catalyst precursor, and then heating and/or chemically treating the catalyst precursor to form the hydro-oxidation catalyst composition. The hydro-oxidation catalyst exhibits stabilized catalyst activity, enhanced lifetime, and improved hydrogen efficiency.
摘要:
A method of reclaiming a titanosilicate from a deactivated or spent oxidation catalyst containing a titanosilicate having deposited thereon one or more catalytic metals, such as gold, and optionally, one or more promoter metals, the method involving treating the deactivated catalyst with an oxidant; contacting the oxidant-treated catalyst with acid, preferably aqua regia; washing the titanosilicate to remove residual acid; and optionally drying and/or calcining. A method of reconstituting an active oxidation catalyst from a spent or deactivated oxidation catalyst, the method involving reclaiming the titanosilicate as noted above, and then depositing one or more catalytic metals and, optionally, one or more promoter metals onto the reclaimed titanosilicate.
摘要:
A method of increasing the lifetime of a hydro-oxidation catalyst comprising, preferably, gold, silver, or mixtures thereof, and optionally one or more promoters, on a titanium-containing support, such as a titanosilicate or titanium dispersed on silica. The method of the invention involves contacting the catalyst support with a hydroxy-functionalized organosilicon compound, a carboxy-functionalized organosilicon compound, or a mixture of hydroxy- and carboxy-functionalized organosilicon compounds, such as, sodium methyl siliconate or (2-carboxypropyl)tetramethyldisiloxane. The contacting is preferably conducted during deposition of the catalytic metal(s) and optional promoters(s) onto the support. A catalyst composition and hydro-oxidation process utilizing the silicon-treated catalyst support are also claimed.
摘要:
A vaporizer filler includes a fill port. The fill port defines an open interior. The open interior is configured to receive the nozzle of an anesthetic bottle. An agent reservoir is configured to receive and store anesthetic agent. A valve is disposed between the open interior and the agent reservoir. At least one vent extends through the fill port. A method of filling a vaporizer includes inserting the nozzle of a bottle filled with anesthetic agent into a vaporizer filler. At least one vent is occluded from fluid communication. Fluid communication between and open interior and an agent reservoir is opened. Anesthetic agent is poured into an agent reservoir of a vaporizer. Fluid communication is closed between the open interior and the agent reservoir. At least one vent is opened to fluid communication with the open interior. Pressure within the open interior is released through the at least one vent.
摘要:
Catalyst compositions for producing mixed alcohols from a synthesis gas feed. The catalyst composition comprises a catalytic metal combination on a catalyst support, a first optional promoter and a second optional promoter, where the catalytic metal combination consists essentially of iridium, vanadium, and molybdenum.
摘要:
Use a transition metal-containing, Keggin-type heteropoly compound as a catalyst to convert synthesis gas to an alcohol, especially a C1-C6 alcohol.
摘要:
Catalyst compositions for producing mixed alcohols from a synthesis gas feed. The catalyst composition comprises a catalytic metal combination on a catalyst support, a first optional promoter and a second optional promoter, where the catalytic metal combination consists essentially of iridium, vanadium, and molybdenum.
摘要:
A heterogeneous catalyst that is a combination of rhodium, zinc, iron, a fourth metal and at least one metal selected from alkali metals and alkaline earth metals on a catalyst support (e.g. at least one of silica, alumina, titania, magnesia, zinc aluminate (ZnAl2O4), magnesium aluminate (MgAl2O4), magnesia-modified alumina, zinc oxide-modified alumina, zirconium oxide-modified alumina, and zinc oxide) and use of the catalyst in converting an alkylene to an oxygenate that has one more carbon atom than the alkylene.
摘要翻译:催化剂载体上的铑,锌,铁,第四金属和至少一种选自碱金属和碱土金属的金属的组合的多相催化剂(例如二氧化硅,氧化铝,二氧化钛,氧化镁,铝酸锌中的至少一种 (ZnAl 2 O 4),铝酸镁(MgAl 2 O 4),氧化镁改性氧化铝,氧化锌改性氧化铝,氧化锆改性氧化铝和氧化锌),并使用该催化剂将亚烷基转化成具有比碳原子多一个碳原子的氧化物 亚烷基。
摘要:
A vaporizer filler includes a fill port. The fill port defines an open interior. The open interior is configured to receive the nozzle of an anesthetic bottle. An agent reservoir is configured to receive and store anesthetic agent. A valve is disposed between the open interior and the agent reservoir. At least one vent extends through the fill port. A method of filling a vaporizer includes inserting the nozzle of a bottle filled with anesthetic agent into a vaporizer filler. At least one vent is occluded from fluid communication. Fluid communication between and open interior and an agent reservoir is opened. Anesthetic agent is poured into an agent reservoir of a vaporizer. Fluid communication is closed between the open interior and the agent reservoir. At least one vent is opened to fluid communication with the open interior. Pressure within the open interior is released through the at least one vent.