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1.发明授权Synthesis of perylene-porphyrin building blocks and polymers thereof for the production of light-harvesting arrays 失效用于生产光收集阵列的苝 - 卟啉结构单元及其聚合物的合成公开(公告)号：US06916982B2
公开(公告)日：2005-07-12
申请号：US10164474
申请日：2002-06-06
IPC分类号： C08G61/12 , C07D487/22 , H01G9/20 , H01L31/04 , H01L51/00 , H01L51/30 , H01L51/42 , H01M14/00 , H01L31/0256 , C07D221/18 , C07D311/00
CPC分类号： H01L51/0077 , B82Y10/00 , C07D487/22 , C09B5/62 , C09B47/00 , C09B69/102 , C09B69/108 , C09B69/109 , H01G9/2059 , H01G9/209 , H01L51/0035 , H01L51/0053 , H01L51/009 , H01L51/0095 , H01L51/0595 , H01L51/42 , H01L51/447 , Y02E10/542 , Y02E10/549 , Y02P70/521
摘要： The present invention provides methods, compounds, and compositions for the synthesis of light harvesting arrays, such arrays comprising: (a) a first substrate comprising a first electrode; and (b) a layer of light harvesting rods electrically coupled to said first electrode, each of said light harvesting rods comprising a polymer of Formula I: X1Xm+1)m (I) wherein m is at least 1; X1 is a charge separation group, and X2 through Xm+1 are chromophores. At least one of X2 through Xm+1 has at least one perylene group coupled thereto.
摘要翻译： 本发明提供了用于合成光收集阵列的方法，化合物和组合物，这种阵列包括：（a）包含第一电极的第一基底; 每个所述光收集杆包括式I的聚合物：<？在线公式描述=“在线公式”结束=“引线” （I）<？in-line-formula description =“在线公式” end =“tail”？>其中m至少为1; X 1是电荷分离组，X 2至X m + 1是发色团。 X 2至X 1至X 1 +中的至少一个具有与其偶联的至少一个苝基团。
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2.发明申请SYNTHESIS OF PHOSPHONO-SUBSTITUTED PORPHYRIN COMPOUNDS FOR ATTACHMENT TO METAL OXIDE SURFACES 失效用于连接到金属氧化物表面的磷取代的哌啶化合物的合成公开(公告)号：US20090234136A1
公开(公告)日：2009-09-17
申请号：US12473438
申请日：2009-05-28
CPC分类号： H01L51/0077 , C07F9/6524 , H01G9/2031 , H01L51/4226 , Y02E10/542 , Y02P70/521
摘要： A method of making a phosphono-substituted dipyrromethane comprises reacting an aldehyde or acetal having at least one phosphono group substituted thereon with pyrrole to produce a phosphono-substituted dipyrromethane; and wherein the phosphono is selected from the group consisting of dialkyl phosphono, diaryl phosphono, and dialkylaryl phosphono. Additional methods, intermediates and products are also described.
摘要翻译： 制备膦酰取代的二吡咯甲烷的方法包括使具有至少一个被取代的膦酰基的醛或缩醛与吡咯反应以产生膦酰取代的二吡咯烷; 并且其中膦酰基选自二烷基膦酰基，二芳基膦酰基和二烷基芳基膦酰基。 还描述了其它方法，中间体和产物。
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3.发明申请Synthesis of Phosphono-Substituted Porphyrin Compounds for Attachment to Metal Oxide Surfaces 失效用于附着到金属氧化物表面的膦酰取代的卟啉化合物的合成公开(公告)号：US20120322999A1
公开(公告)日：2012-12-20
申请号：US13597815
申请日：2012-08-29
IPC分类号： C07F9/572 , C07D487/22
CPC分类号： H01L51/0077 , C07F9/6524 , H01G9/2031 , H01L51/4226 , Y02E10/542 , Y02P70/521
摘要： A method of making a phosphono-substituted dipyrromethane comprises reacting an aldehyde or acetal having at least one phosphono group substituted thereon with pyrrole to produce a phosphono-substituted dipyrromethane; and wherein the phosphono is selected from the group consisting of dialkyl phosphono, diaryl phosphono, and dialkylaryl phosphono. Additional methods, intermediates and products are also described.
摘要翻译： 制备膦酰取代的二吡咯甲烷的方法包括使具有至少一个被取代的膦酰基的醛或缩醛与吡咯反应以产生膦酰取代的二吡咯烷; 并且其中膦酰基选自二烷基膦酰基，二芳基膦酰基和二烷基芳基膦酰基。 还描述了其它方法，中间体和产物。
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4.发明授权Synthesis of phosphono-substituted porphyrin compounds for attachment to metal oxide surfaces 失效合成膦酰取代的卟啉化合物用于附着到金属氧化物表面公开(公告)号：US08278439B2
公开(公告)日：2012-10-02
申请号：US13299894
申请日：2011-11-18
IPC分类号： C07D207/00 , C07F9/02
CPC分类号： H01L51/0077 , C07F9/6524 , H01G9/2031 , H01L51/4226 , Y02E10/542 , Y02P70/521
摘要： A method of making a phosphono-substituted dipyrromethane comprises reacting an aldehyde or acetal having at least one phosphono group substituted thereon with pyrrole to produce a phosphono-substituted dipyrromethane; and wherein the phosphono is selected from the group consisting of dialkyl phosphono, diaryl phosphono, and dialkylaryl phosphono. Additional methods, intermediates and products are also described.
摘要翻译： 制备膦酰取代的二吡咯甲烷的方法包括使具有至少一个被取代的膦酰基的醛或缩醛与吡咯反应以产生膦酰取代的二吡咯烷; 并且其中膦酰基选自二烷基膦酰基，二芳基膦酰基和二烷基芳基膦酰基。 还描述了其它方法，中间体和产物。
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公开(公告)号：US06603070B2
公开(公告)日：2003-08-05
申请号：US09939010
申请日：2001-08-24
IPC分类号： H01L310248
CPC分类号： C09K11/06 , B82Y10/00 , C07D487/22 , C09B47/00 , C09B69/109 , C09K2211/1029 , C09K2211/1074 , C09K2211/186 , C09K2211/188 , H01G9/2059 , H01G9/209 , H01L51/0034 , H01L51/0035 , H01L51/0077 , H01L51/0078 , H01L51/009 , H01L51/0093 , H01L51/0595 , H01L51/4206 , Y02E10/542 , Y02E10/549 , Y02P70/521 , Y02T10/7022
摘要： The present invention provides a convergent method for the synthesis of light harvesting rods. The rods are oligomers of the formula A1(Ab+1)b, wherein b is at least 1, A1 through Ab+1 are covalently coupled rod segments, and each rod segment A1 through A1+b comprises a compound of the formula X1(Xm+1)m wherein m is at least 1 and X1 through Xm+1 are covalently coupled porphyrinic macrocycles. Light harvesting arrays and solar cells containing such light harvesting rods are also described, along with intermediates useful in such methods and rods produced by such methods.
摘要翻译： 本发明提供了一种用于合成光收集杆的收敛方法。 棒是式A1（Ab + 1）b的低聚物，其中b至少为1，Al至Ab + 1为共价键，每个棒段A1至A1 + b包含式X1化合物 Xm + 1）m，其中m为至少1，X1至Xm + 1为共价偶联的卟啉大环。 还描述了含有这种光收获杆的光收集阵列和太阳能电池，以及可用于通过这种方法制备的这种方法和棒中的中间体。
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公开(公告)号：US08529996B2
公开(公告)日：2013-09-10
申请号：US11688194
申请日：2007-03-19
申请人： David F. Bocian , Jonathan S. Lindsey , Zhiming Liu , Amir A. Yasseri , Veena Misra , Qian Zhao , Qiliang Li , Shyam Surthi , Robert S. Loewe
发明人： David F. Bocian , Jonathan S. Lindsey , Zhiming Liu , Amir A. Yasseri , Veena Misra , Qian Zhao , Qiliang Li , Shyam Surthi , Robert S. Loewe
IPC分类号： C23C16/00
CPC分类号： H01L51/0002 , B82Y10/00 , G11B9/14 , G11B9/149 , G11C13/0014 , G11C13/0016 , H01L51/0008 , H01L51/001 , H01L51/0026 , H01L51/0075 , H01L51/0077 , H01L51/0595 , H01L51/4213 , H01M4/60 , H01M14/005 , Y02E10/549
摘要： This invention provides a new procedure for attaching molecules to semiconductor surfaces, in particular silicon. The molecules, which include, but are not limited to porphyrins and ferrocenes, have been previously shown to be attractive candidates for molecular-based information storage. The new attachment procedure is simple, can be completed in short times, requires minimal amounts of material, is compatible with diverse molecular functional groups, and in some instances affords unprecedented attachment motifs. These features greatly enhance the integration of the molecular materials into the processing steps that are needed to create hybrid molecular/semiconductor information storage devices.
摘要翻译： 本发明提供了一种将分子连接到半导体表面，特别是硅的新方法。 以前已经显示出包括但不限于卟啉和二茂铁的分子是用于基于分子的信息存储的有吸引力的候选物。 新的附件程序简单，可以在短时间内完成，需要最少量的材料，与不同的分子官能团相容，并在某些情况下提供前所未有的附着图案。 这些特征大大增强了分子材料与创建混合分子/半导体信息存储设备所需的处理步骤的集成。
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7.发明授权公开(公告)号：US08445695B2
公开(公告)日：2013-05-21
申请号：US13597815
申请日：2012-08-29
IPC分类号： C07D207/00 , C07F9/02
CPC分类号： H01L51/0077 , C07F9/6524 , H01G9/2031 , H01L51/4226 , Y02E10/542 , Y02P70/521
摘要： A method of making a phosphono-substituted dipyrromethane comprises reacting an aldehyde or acetal having at least one phosphono group substituted thereon with pyrrole to produce a phosphono-substituted dipyrromethane; and wherein the phosphono is selected from the group consisting of dialkyl phosphono, diaryl phosphono, and dialkylaryl phosphono. Additional methods, intermediates and products are also described.
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8.发明申请Synthesis of Phosphono-Substituted Porphyrin Compounds for Attachment to Metal Oxide Surfaces 失效用于附着到金属氧化物表面的膦酰取代的卟啉化合物的合成公开(公告)号：US20080269501A1
公开(公告)日：2008-10-30
申请号：US11937808
申请日：2007-11-09
IPC分类号： C07F9/572
CPC分类号： H01L51/0077 , C07F9/6524 , H01G9/2031 , H01L51/4226 , Y02E10/542 , Y02P70/521
摘要： A method of making a phosphono-substituted dipyrromethane comprises reacting an aldehyde or acetal having at least one phosphono group substituted thereon with pyrrole to produce a phosphono-substituted dipyrromethane; and wherein the phosphono is selected from the group consisting of dialkyl phosphono, diaryl phosphono, and dialkylaryl phosphono. Additional methods, intermediates and products are also described.
摘要翻译： 制备膦酰取代的二吡咯甲烷的方法包括使具有至少一个被取代的膦酰基的醛或缩醛与吡咯反应以产生膦酰取代的二吡咯烷; 并且其中膦酰基选自二烷基膦酰基，二芳基膦酰基和二烷基芳基膦酰基。 还描述了其它方法，中间体和产物。
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9.发明申请SYNTHESIS OF PORPHYRINS DESIGNED FOR ATTACHMENT TO ELECTROACTIVE SURFACES VIA ONE OR MORE CARBON TETHERS 失效通过一个或多个碳化合物设计用于连接到电动表面的聚吡咯的合成公开(公告)号：US20080194839A1
公开(公告)日：2008-08-14
申请号：US12052084
申请日：2008-03-20
IPC分类号： C07D403/06
CPC分类号： C07D207/323 , C07D207/333
摘要： Porphyrin compounds having a surface attachment group coupled thereto at the 5 position are described. The surface attachment group has the formula: wherein R is —CHCH2 or —CCH and Ar is an aromatic group. Methods and intermediates useful for making such compounds are also described.
摘要翻译： 描述了在5位置具有与其连接的表面附着基团的卟啉化合物。 表面附着基团具有下式：其中R是-CHCH 2或-CCH，Ar是芳族基团。 还描述了可用于制备这些化合物的方法和中间体。
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10.发明申请SYNTHESIS OF PHOSPHONO-SUBSTITUTED PORPHYRIN COMPOUNDS FOR ATTACHMENT TO METAL OXIDE SURFACES 失效用于连接到金属氧化物表面的磷取代的哌啶化合物的合成公开(公告)号：US20120065391A1
公开(公告)日：2012-03-15
申请号：US13299894
申请日：2011-11-18
IPC分类号： C07F9/6561
CPC分类号： H01L51/0077 , C07F9/6524 , H01G9/2031 , H01L51/4226 , Y02E10/542 , Y02P70/521
摘要： A method of making a phosphono-substituted dipyrromethane comprises reacting an aldehyde or acetal having at least one phosphono group substituted thereon with pyrrole to produce a phosphono-substituted dipyrromethane; and wherein the phosphono is selected from the group consisting of dialkyl phosphono, diaryl phosphono, and dialkylaryl phosphono. Additional methods, intermediates and products are also described.
摘要翻译： 制备膦酰取代的二吡咯甲烷的方法包括使具有至少一个被取代的膦酰基的醛或缩醛与吡咯反应以产生膦酰取代的二吡咯烷; 并且其中膦酰基选自二烷基膦酰基，二芳基膦酰基和二烷基芳基膦酰基。 还描述了其它方法，中间体和产物。
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