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公开(公告)号：US09505874B2
公开(公告)日：2016-11-29
申请号：US14281944
申请日：2014-05-20
Applicant: Rohm and Haas Company , Dow Global Technologies LLC
Inventor： Gregoire Cardoen , Ian J. Drake , Ralph C. Even , Andrew Hughes , Tianlan Zhang , Thomas H. Kalantar
IPC: C08G18/83 , C08G18/75 , C08G18/76 , C08F283/00 , C08F290/06 , C09D175/02 , C08G18/32 , C08G18/38 , C08L75/02
CPC classification number: C08G18/831 , C08F283/006 , C08F290/067 , C08G18/3228 , C08G18/3819 , C08G18/751 , C08G18/755 , C08G18/7614 , C08G18/7671 , C08L75/02 , C08L75/16 , C09D133/06 , C09D175/02 , C09D133/12
Abstract: The present invention is a composition comprising a) a stable aqueous dispersion of polymer particles having one or more structural units of i) a polyurea macromer; and ii) an acrylate, a methacrylate, a vinyl ester, or a styrene monomer, or a combination thereof; and/or b) an 5 aqueous mixture of a i) polyurea macromer polymer particles; and b) acrylate, methacrylate, vinyl ester, or styrenic polymer particles, or a combination thereof, wherein the polyurea macromer is characterized by the following formula I: 10 where A1, A2, R1, R2, and R3 are as defined herein. In another aspect, the present invention is the compound of Formula I. Compositions prepared using the compound of the present invention can be used to form coatings with excellent balance of low temperature film formation, hardness, and flexibility.
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公开(公告)号：US20140350178A1
公开(公告)日：2014-11-27
申请号：US14281944
申请日：2014-05-20
Applicant: Rohm and Haas Company , Dow Global Technologies LLC
Inventor： Gregoire Cardoen , Ian J. Drake , Ralph C. Even , Andrew Hughes , Tianlan Zhang , Thomas H. Kalantar
CPC classification number: C08G18/831 , C08F283/006 , C08F290/067 , C08G18/3228 , C08G18/3819 , C08G18/751 , C08G18/755 , C08G18/7614 , C08G18/7671 , C08L75/02 , C08L75/16 , C09D133/06 , C09D175/02 , C09D133/12
Abstract: The present invention is a composition comprising a) a stable aqueous dispersion of polymer particles having one or more structural units of i) a polyurea macromer; and ii) an acrylate, a methacrylate, a vinyl ester, or a styrene monomer, or a combination thereof; and/or b) an aqueous mixture of a i) polyurea macromer polymer particles; and b) acrylate, methacrylate, vinyl ester, or styrenic polymer particles, or a combination thereof, wherein the polyurea macromer is characterized by the following formula I: where A1, A2, R1, R2, and R3 are as defined herein. In another aspect, the present invention is the compound of Formula I.Compositions prepared using the compound of the present invention can be used to form coatings with excellent balance of low temperature film formation, hardness, and flexibility.
Abstract translation: 本发明是一种组合物，其包含a）具有一种或多种结构单元的聚合物颗粒的稳定水分散体，其i）聚脲大分子单体; 和ii）丙烯酸酯，甲基丙烯酸酯，乙烯基酯或苯乙烯单体或其组合; 和/或b）i）聚脲大分子单体聚合物颗粒的水性混合物; 和b）丙烯酸酯，甲基丙烯酸酯，乙烯基酯或苯乙烯聚合物颗粒或其组合，其中聚脲大分子单体的特征在于以下式I：其中A1，A2，R1，R2和R3如本文所定义。 另一方面，本发明是式I的化合物。使用本发明化合物制备的组合物可用于形成具有低温成膜，硬度和柔韧性优异平衡的涂层。
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公开(公告)号：US09783669B2
公开(公告)日：2017-10-10
申请号：US14942202
申请日：2015-11-16
Applicant: Rohm and Haas Company , Dow Global Technologies LLC
Inventor： Gregoire Cardoen , Ian J. Drake , Ralph C. Even , Andrew Hughes , Tianlan Zhang , Thomas H. Kalantar
IPC: C08L33/24 , C08L33/06 , C08F283/00 , C08L33/08 , C08G18/75 , C08G18/76 , C08G18/32 , C08G18/63 , C08F290/06
CPC classification number: C08L33/08 , C08F290/067 , C08G18/3228 , C08G18/633 , C08G18/636 , C08G18/755 , C08G18/7671 , C08L33/24 , C08L2201/54 , C08F220/18
Abstract: The present invention is a composition comprising a) a stable aqueous dispersion of polymer particles having one or more structural units of i) a polyurea macromer; and ii) an acrylate, a methacrylate, a vinyl ester, or a styrene monomer, or a combination thereof; and/or b) an aqueous mixture of a i) polyurea macromer polymer particles; and b) acrylate, methacrylate, vinyl ester, or styrenic polymer particles, or a combination thereof, wherein the polyurea macromer is characterized by the following formula I: where A1, A2, R1, R2, and R3 are as defined herein. Compositions prepared using the compound of the present invention can be used to form coatings with excellent balance of low temperature film formation, hardness, and flexibility.
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公开(公告)号：US09217081B2
公开(公告)日：2015-12-22
申请号：US14281947
申请日：2014-05-20
Applicant: Rohm and Haas Company , Dow Global Technologies LLC
Inventor： Gregoire Cardoen , Ian J. Drake , Ralph C. Even , Andrew Hughes , Tianlan Zhang , Thomas H. Kalantar
IPC: C08L33/24 , C08F283/00 , C08G18/75 , C08G18/76 , C08G18/32 , C08G18/63 , C08F290/06
CPC classification number: C08L33/08 , C08F290/067 , C08G18/3228 , C08G18/633 , C08G18/636 , C08G18/755 , C08G18/7671 , C08L33/24 , C08L2201/54 , C08F220/18
Abstract: The present invention is a composition comprising a) a stable aqueous dispersion of polymer particles having one or more structural units of i) a polyurea macromer; and ii) an acrylate, a methacrylate, a vinyl ester, or a styrene monomer, or a combination thereof; and/or b) an aqueous mixture of a i) polyurea macromer polymer particles; and b) acrylate, methacrylate, vinyl ester, or styrenic polymer particles, or a combination thereof, wherein the polyurea macromer is characterized by the following formula I: where A1, A2, R1, R2, and R3 are as defined herein. Compositions prepared using the compound of the present invention can be used to form coatings with excellent balance of low temperature film formation, hardness, and flexibility.
Abstract translation: 本发明是一种组合物，其包含a）具有一种或多种结构单元的聚合物颗粒的稳定水分散体，其i）聚脲大分子单体; 和ii）丙烯酸酯，甲基丙烯酸酯，乙烯基酯或苯乙烯单体或其组合; 和/或b）i）聚脲大分子单体聚合物颗粒的水性混合物; 和b）丙烯酸酯，甲基丙烯酸酯，乙烯基酯或苯乙烯聚合物颗粒或其组合，其中聚脲大分子单体的特征在于以下式I：其中A1，A2，R1，R2和R3如本文所定义。 使用本发明化合物制备的组合物可用于形成具有低温成膜，硬度和柔韧性优异平衡的涂层。
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Patent Agency Ranking
公开(公告)号：US20160068673A1
公开(公告)日：2016-03-10
申请号：US14942202
申请日：2015-11-16
Applicant: ROHM AND HAAS COMPANY , DOW GLOBAL TECHNOLOGIES LLC
Inventor： Gregoire Cardoen , Ian J. Drake , Ralph C. Even , Andrew Hughes , Tianlan Zhang , Thomas H. Kalantar
IPC: C08L33/08
CPC classification number: C08L33/08 , C08F290/067 , C08G18/3228 , C08G18/633 , C08G18/636 , C08G18/755 , C08G18/7671 , C08L33/24 , C08L2201/54 , C08F220/18
Abstract: The present invention is a composition comprising a) a stable aqueous dispersion of polymer particles having one or more structural units of i) a polyurea macromer; and ii) an acrylate, a methacrylate, a vinyl ester, or a styrene monomer, or a combination thereof; and/or b) an aqueous mixture of a i) polyurea macromer polymer particles; and b) acrylate, methacrylate, vinyl ester, or styrenic polymer particles, or a combination thereof, wherein the polyurea macromer is characterized by the following formula I: where A1, A2, R1, R2, and R3 are as defined herein. Compositions prepared using the compound of the present invention can be used to form coatings with excellent balance of low temperature film formation, hardness, and flexibility.
Abstract translation: 本发明是一种组合物，其包含a）具有一种或多种结构单元的聚合物颗粒的稳定水分散体，其i）聚脲大分子单体; 和ii）丙烯酸酯，甲基丙烯酸酯，乙烯基酯或苯乙烯单体或其组合; 和/或b）i）聚脲大分子单体聚合物颗粒的水性混合物; 和b）丙烯酸酯，甲基丙烯酸酯，乙烯基酯或苯乙烯聚合物颗粒或其组合，其中聚脲大分子单体的特征在于以下式I：其中A1，A2，R1，R2和R3如本文所定义。 使用本发明化合物制备的组合物可用于形成具有低温成膜，硬度和柔韧性优异平衡的涂层。
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公开(公告)号：US20150231589A1
公开(公告)日：2015-08-20
申请号：US14624404
申请日：2015-02-17
Applicant: Rohm and Haas Company
Inventor： Selvanathan Arumugam , Andrew Hughes , Ralph C. Even
IPC: B01J13/20
CPC classification number: B01J13/20 , B01J13/16 , Y10T428/2985
Abstract: A process for adjusting the wettability property of a plurality of on-demand activation-type microcapsules of a core and shell structure including the steps of: (a) providing a plurality of microcapsules of a core and shell structure, wherein the shell includes a polymeric matrix containing a certain amount of unreacted functionalizable reactive electrophiles covalently bonded to the surface of the wall of the shell of the microcapsules; and (b) contacting the plurality of microcapsules of step (a) with a certain amount of nucleophiles; wherein the nucleophiles are adapted to react with the electrophiles; and wherein the nucleophiles are adapted to modify the wettability property of the microcapsules' shell structure to a predetermined degree of hydrophilicity or solvent compatibility.
Abstract translation: 一种用于调节核和壳结构的多种按需激活型微胶囊的润湿性的方法，包括以下步骤：（a）提供多个芯壳结构的微胶囊，其中所述壳包括聚合物 含有一定量的未反应的可官能化的活性亲电子基团，共价键合到微胶囊壳的表面上; 和（b）使步骤（a）的多个微胶囊与一定量的亲核试剂接触; 其中亲核试剂适于与亲电试剂反应; 并且其中所述亲核试剂适于将微胶囊壳结构的润湿性改性至预定的亲水性或溶剂相容性。
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公开(公告)号：US10947330B2
公开(公告)日：2021-03-16
申请号：US16638951
申请日：2018-08-20
Inventor： Damien Guironnet , Muhammad Rabnawaz , Ralph Even , Andrew Hughes , Joshua Katz
Abstract: A method for encapsulating a catalyst in a dispersed polymer particle comprising dissolving a Group 8 to Group 11 transition metal containing catalyst and a self-dispersing polymer in a solvent; adding water and optionally a base under particle forming conditions to form a dispersed polymer encapsulated catalyst comprising particles having a population number average diameter between 10 and 300 nanometers is provided.
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公开(公告)号：US20150231588A1
公开(公告)日：2015-08-20
申请号：US14624411
申请日：2015-02-17
Inventor： Jeffery S. Moore , Jun Li , Andrew Hughes
CPC classification number: B01J13/16 , B01J13/185 , C08G18/3228 , C08G18/6423 , C08G18/6523 , C08G18/7664 , C08G59/188 , C08G59/245 , C08G59/502 , C08J3/241 , C08J2363/00 , C08K3/346 , C08L63/00
Abstract: Microcapsules including a shell and core structure are disclosed herein. In one aspect, the core includes at least one poly(allylamine). A process for producing such microcapsules is also disclosed herein. In another aspect, a curable epoxy resin composition includes a mixture of (a) at least one epoxy monomer compound and (b) a plurality of the disclosed microcapsules. Processes for producing the curable epoxy resin composition and a cured epoxy resin composite are also disclosed.
Abstract translation: 本文公开了包括壳和芯结构的微胶囊。 在一个方面，核心包括至少一种聚（烯丙胺）。 本文还公开了生产这种微胶囊的方法。 另一方面，可固化环氧树脂组合物包括（a）至少一种环氧单体化合物和（b）多个所公开的微胶囊的混合物。 还公开了用于制备可固化环氧树脂组合物和固化的环氧树脂复合材料的方法。
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公开(公告)号：US20140350170A1
公开(公告)日：2014-11-27
申请号：US14281947
申请日：2014-05-20
Applicant: Rohm and Haas Company , Dow Global Technologies LLC
Inventor： Gregoire Cardoen , Ian J. Drake , Ralph C. Even , Andrew Hughes , Tianlan Zhang , Thomas H. Kalantar
IPC: C08L33/24
CPC classification number: C08L33/08 , C08F290/067 , C08G18/3228 , C08G18/633 , C08G18/636 , C08G18/755 , C08G18/7671 , C08L33/24 , C08L2201/54 , C08F220/18
Abstract: The present invention is a composition comprising a) a stable aqueous dispersion of polymer particles having one or more structural units of i) a polyurea macromer; and ii) an acrylate, a methacrylate, a vinyl ester, or a styrene monomer, or a combination thereof; and/or b) an aqueous mixture of a i) polyurea macromer polymer particles; and b) acrylate, methacrylate, vinyl ester, or styrenic polymer particles, or a combination thereof, wherein the polyurea macromer is characterized by the following formula I: where A1, A2, R1, R2, and R3 are as defined herein. Compositions prepared using the compound of the present invention can be used to form coatings with excellent balance of low temperature film formation, hardness, and flexibility.
Abstract translation: 本发明是一种组合物，其包含a）具有一种或多种结构单元的聚合物颗粒的稳定水分散体，其i）聚脲大分子单体; 和ii）丙烯酸酯，甲基丙烯酸酯，乙烯基酯或苯乙烯单体或其组合; 和/或b）i）聚脲大分子单体聚合物颗粒的水性混合物; 和b）丙烯酸酯，甲基丙烯酸酯，乙烯基酯或苯乙烯聚合物颗粒或其组合，其中聚脲大分子单体的特征在于以下式I：其中A1，A2，R1，R2和R3如本文所定义。 使用本发明化合物制备的组合物可用于形成具有低温成膜，硬度和柔韧性优异平衡的涂层。
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