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1.发明授权Method for producing paper, paperboard and cardboard using an uncrosslinked fixing agent during paper stock draining 有权纸张排水期间使用未交联固定剂生产纸，纸板和纸板的方法公开(公告)号：US06576086B1
公开(公告)日：2003-06-10
申请号：US09403769
申请日：1999-11-02
申请人： Roland Ettl , Hubert Meixner , Anton Esser , Rainer Scholz , Norbert Mahr , Ulrich Steuerle , Matthias Höne , Klaus Lorenz
发明人： Roland Ettl , Hubert Meixner , Anton Esser , Rainer Scholz , Norbert Mahr , Ulrich Steuerle , Matthias Höne , Klaus Lorenz
IPC分类号： D21C2110
CPC分类号： C08G73/0206 , C08F8/32 , C08F8/44 , C08G73/028 , D21H17/08 , D21H17/14 , D21H17/17 , D21H17/37 , D21H17/38 , D21H17/49 , D21H17/55 , D21H17/56 , D21H21/10 , D21H21/16
摘要： Paper, board and cardboard are produced by draining paper stock containing interfering substances in the presence of fixing agents by a process in which the fixing agents used are reaction products which are obtainable by reacting amino- and/or ammonium-containing polymers selected from the group consisting of the polymers containing vinylamine units polyalkylene polyamines polyamidoamines ethyleneimine-grafted polyamidoamines which may be crosslinked, polydiallyldimethylammonium chlorides polymers containing dialkylaminoalkylacrylamide units or dialkylaminoalkylmethacrylamide units and polyallylamines and dicyandiamide and formaldehyde condensates with reactive sizes for paper in a weight ratio of polymer to reactive size of from 15,000:1 to 1:1, and the reaction products thus obtainable are used as fixing agents for water-soluble and for water-insoluble interfering substances in the production of paper, board and cardboard from paper stocks containing interfering substances.
摘要翻译： 纸，纸板和纸板是通过在固定剂存在下排出含有干扰物质的纸原料而制备的，其中所用的固定剂是通过使选自下组的氨基和/或含铵聚合物反应获得的反应产物 由聚合物单体聚亚烷基多胺聚酰氨基亚胺亚甲基亚胺接枝的聚酰氨基胺，其可以是交联的，含二烷基氨基烷基丙烯酰胺单元或二烷基氨基烷基甲基丙烯酰胺单元的聚二烯丙基二甲基氯化铵聚合物和聚烯丙基胺和双氰胺和甲醛缩合物，聚合物与反应性大小的重量比为15,000:1至1:1 ，由此可得到的反应产物用作纸，纸板和纸板的水溶性固定剂和含有干扰物质的纸料的水不溶性干扰物质。
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2.发明授权Method for fractionation of water soluble or dispersible polymers containing amino groups with a broad molar mass distribution 有权分离含有宽摩尔质量分布的氨基的水溶性或分散性聚合物的方法公开(公告)号：US06706190B1
公开(公告)日：2004-03-16
申请号：US09926503
申请日：2001-11-13
申请人： Ulrich Steuerle , Hartwig Voss , Jürgen Bernbach , Jürgen Decker , Rainer Dyllick-Brenzinger , Klaus Lorenz , Hubert Meixner , Martin Rübenacker
发明人： Ulrich Steuerle , Hartwig Voss , Jürgen Bernbach , Jürgen Decker , Rainer Dyllick-Brenzinger , Klaus Lorenz , Hubert Meixner , Martin Rübenacker
IPC分类号： B01D6114
CPC分类号： B01D61/145 , B01D61/025 , B01D61/142 , B01D61/22 , B01D61/58 , C08G73/00 , C08G73/02 , C08G73/0213 , C08G73/028 , D21H21/10 , D21H21/16
摘要： A process for fractionating water-soluble or water-dispersible amino-containing synthetic polymers having a broad molar mass distribution by ultrafiltration, wherein the polymer solution or dispersion to be fractionated is fed continuously into an ultrafiltration circulation with at least one ultrafiltration unit, and retentate having a narrower molar mass distribution and permeate are discharged continuously, in such a way that the ultrafiltration circulation is essentially in a steady state, the polymers obtainable by this process and their use.
摘要翻译： 一种通过超滤分级具有宽摩尔质量分布的水溶性或水分散性含氨基合成聚合物的方法，其中待分级的聚合物溶液或分散体通过至少一个超滤单元连续进料到超滤循环中，并将渗余物 具有较窄的摩尔质量分布和渗透物被连续排出，使得超滤循环基本上处于稳定状态，可通过该方法获得的聚合物及其用途。
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公开(公告)号：US08512520B2
公开(公告)日：2013-08-20
申请号：US11720362
申请日：2005-11-29
摘要： A paper size which comprises a stable aqueous dispersion of a reactive size, from 5 to 100% by weight, based on the reactive size, of a substantially linear nitrogen-comprising polymer having at least 3 mmol/g of basic nitrogen atoms, and from 1 to 50% by weight of cationic starch having a degree of substitution of at least 0.05 is described. The paper size has a good sizing effect and a stable viscosity.
摘要翻译： 一种纸张尺寸，其包含基于反应性大小的反应性大小为5-100重量％的稳定的水性分散体，其具有至少3mmol / g碱性氮原子的基本上线性的含氮聚合物，以及 描述1至50重量％的取代度至少为0.05的阳离子淀粉。 纸张尺寸具有良好的施胶效果和粘度稳定性。
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4.发明授权Aqueous dispersions of reactive gluing agents, method for the production and the use thereof 有权反应性粘合剂的水性分散体，其制备方法及其用途公开(公告)号：US08633274B2
公开(公告)日：2014-01-21
申请号：US10589857
申请日：2005-02-26
申请人： Johann Bonn , Roland Ettl , Klaus Lorenz
发明人： Johann Bonn , Roland Ettl , Klaus Lorenz
IPC分类号： C08F8/30
摘要： Aqueous dispersions of reactive sizes comprise cationic polymers comprising vinylamine units as a protective colloid, the protective colloid comprising less than 0.0001% by weight, based on the protective colloid, of diketenes.
摘要翻译： 反应性大小的水性分散体包含含有乙烯胺单元作为保护胶体的阳离子聚合物，保护胶体基于保护胶体小于0.0001重量％的双烯酮。
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公开(公告)号：US20080041546A1
公开(公告)日：2008-02-21
申请号：US11720362
申请日：2005-11-29
摘要： A paper size which comprises a stable aqueous dispersion of a reactive size, from 5 to 100% by weight, based on the reactive size, of a substantially linear nitrogen-comprising polymer having at least 3 mmol/g of basic nitrogen atoms, and from 1 to 50% by weight of cationic starch having a degree of substitution of at least 0.05 is described. The paper size has a good sizing effect and a stable viscosity.
摘要翻译： 一种纸张尺寸，其包含基于反应性大小的反应性大小为5-100重量％的稳定的水性分散体，其具有至少3mmol / g碱性氮原子的基本上线性的含氮聚合物，以及 描述1至50重量％的取代度至少为0.05的阳离子淀粉。 纸张尺寸具有良好的施胶效果和粘度稳定性。
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6.发明申请Aqueous dispersions of reactive gluing agents, method for the production and the use thereof 有权反应性粘合剂的水性分散体，其制备方法及其用途公开(公告)号：US20070167558A1
公开(公告)日：2007-07-19
申请号：US10589857
申请日：2005-02-26
申请人： Johann Bonn , Roland Ettl , Klaus Lorenz
发明人： Johann Bonn , Roland Ettl , Klaus Lorenz
IPC分类号： C08F8/30
摘要： Aqueous dispersions of reactive sizes comprise cationic polymers comprising vinylamine units as a protective colloid, the protective colloid comprising less than 0.0001% by weight, based on the protective colloid, of diketenes.
摘要翻译： 反应性大小的水性分散体包含含有乙烯胺单元作为保护胶体的阳离子聚合物，保护胶体基于保护胶体小于0.0001重量％的双烯酮。
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7.发明授权公开(公告)号：US09193822B2
公开(公告)日：2015-11-24
申请号：US13318157
申请日：2010-05-04
申请人： Hartmut Nefzger , Erika Bauer , Jörg Hofmann , Klaus Lorenz , Bert Klesczewski
发明人： Hartmut Nefzger , Erika Bauer , Jörg Hofmann , Klaus Lorenz , Bert Klesczewski
IPC分类号： C07C69/675 , C08G63/91 , C08G18/42 , C08G63/87
CPC分类号： C08G63/914 , C08G18/4261 , C08G63/87
摘要： The invention relates to a process for producing polyester polyols with secondary hydroxyl end groups, including the step of the reaction of a polyester including carboxyl end groups with an epoxide of the general formula (1): wherein R1 stands for an alkyl residue or an aryl residue and the reaction is carried out in the presence of a catalyst that includes at least one nitrogen atom per molecule. The process is distinguished in that the polyester including carboxyl end groups exhibits an acid value from ≧25 mg KOH/g to ≦400 mg KOH/g and a hydroxyl value from ≦5 mg KOH/g and in that the polyester including carboxyl end groups is produced by ≧1.03 mol to ≦1.90 mol carboxyl groups or carboxyl-group equivalents of an acid component being employed per mol hydroxyl groups of an alcohol. The polyester polyols obtained, including secondary hydroxyl end groups, can be used for the purpose of producing polyurethane polymers.
摘要翻译： 本发明涉及一种生产具有仲羟基端基的聚酯多元醇的方法，包括包括羧基端基的聚酯与通式（1）的环氧化物反应的步骤：其中R1代表烷基或芳基 残基，反应在每分子包含至少一个氮原子的催化剂存在下进行。 该方法的区别在于包括羧基端基的聚酯显示出≥25mgKOH / g至≥1000的KOH值，400mg KOH / g的酸值和来自＆lt; NEE的5K KOH / g的羟值，并且包括羧基的聚酯 端基是由醇的每摩尔羟基使用的≥1.03摩尔至1升; 1.90摩尔羧基或酸组分的羧基当量。 得到的聚酯多元醇（包括仲羟基端基）可用于制备聚氨酯聚合物。
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公开(公告)号：US09045377B2
公开(公告)日：2015-06-02
申请号：US13392988
申请日：2010-08-12
申请人： Luc Nicoleau , Gerhard Albrecht , Klaus Lorenz , Eva Jetzlsperger , Daniel Fridrich , Thomas Wohlhaupter , Reinhard Dorfner , Hubert Leitner , Mario Vierle , Dirk Schmitt , Michael Braeu , Christoph Hesse , Sabrina Montero Pancera , Siegfried Zuern , Michael Kutschera
发明人： Luc Nicoleau , Gerhard Albrecht , Klaus Lorenz , Eva Jetzlsperger , Daniel Fridrich , Thomas Wohlhaupter , Reinhard Dorfner , Hubert Leitner , Mario Vierle , Dirk Schmitt , Michael Braeu , Christoph Hesse , Sabrina Montero Pancera , Siegfried Zuern , Michael Kutschera
CPC分类号： C04B40/0039 , C04B2103/14 , C04B12/04 , C04B22/085 , C04B24/122 , C04B24/246 , C04B24/383 , C04B2103/22
摘要： The invention concerns a process for the preparation of a hardening accelerator composition by reaction of a water-soluble calcium compound with a water-soluble silicate compound and by reaction of a calcium compound with a silicon dioxide containing component under alkaline conditions, in both cases the reaction being carried out in the presence of a polycondensate containing at least one structural unit consisting of an aromatic or heteroaromatic moiety bearing a polyether side chain and at least one structural unit consisting of an aromatic or heteroaromatic moiety bearing at least one phosphoric acid ester group and/or its salt. The invention concerns a composition of calcium silicate hydrate and the polycondensate, its use as hardening accelerator and for the reduction of the permeability of hardened compositions.
摘要翻译： 本发明涉及通过水溶性钙化合物与水溶性硅酸盐化合物的反应以及碱性条件下钙化合物与含二氧化硅的组分的反应来制备硬化促进剂组合物的方法，在这两种情况下 反应在含有至少一个结构单元的存在下进行，所述缩聚物包含至少一个由具有聚醚侧链的芳族或杂芳族部分组成的结构单元和至少一个由具有至少一个磷酸酯基团的芳族或杂芳族部分组成的结构单元，和 /或其盐。 本发明涉及硅酸钙水合物和缩聚物的组合物，其用作硬化促进剂和降低硬化组合物的渗透性。
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公开(公告)号：US20140142344A1
公开(公告)日：2014-05-22
申请号：US14125776
申请日：2012-06-26
申请人： Klaus Lorenz , Jörg Hofmann , Horst Zwick , Christian Steinlein , Edward Browne
发明人： Klaus Lorenz , Jörg Hofmann , Horst Zwick , Christian Steinlein , Edward Browne
IPC分类号： C08G65/26
CPC分类号： C08G65/2609 , C08G65/2663 , C08G65/2696
摘要： The invention relates to a process for the preparation of polyether polyols with equivalent molecular weights of from 8,000 to 20,000 g/mol from one or more H-functional starter compounds and one or more alkylene oxides in the presence of a double metal cyanide catalyst, characterized in that the alkylene oxides are metered into the reactor in the course of from 15 to 23 h.
摘要翻译： 本发明涉及在双金属氰化物催化剂存在下，从一种或多种H官能起始化合物和一种或多种烯化氧制备具有8,000至20,000g / mol的当量分子量的聚醚多元醇的方法，其特征在于 因为在15至23小时的过程中将环氧烷烃计量加入反应器中。
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公开(公告)号：US20130204047A1
公开(公告)日：2013-08-08
申请号：US13582786
申请日：2011-03-09
申请人： Klaus Lorenz
发明人： Klaus Lorenz
IPC分类号： C07C41/02
CPC分类号： C07C41/02 , C08G18/283 , C08G18/4883 , C08G65/2609 , C08G65/2696 , C08G2650/26
摘要： The present invention relates to is coupling process for the preparation of polyether polyols starting from highly functional starter compounds that are solid or highly viscous under reaction conditions and monofunctional starter compounds that are liquid under reaction conditions with Zerewitinoff-active hydrogen atoms.
摘要翻译： 本发明涉及用于制备聚醚多元醇的偶合方法，其起始于在反应条件下为固体或高粘度的高官能起始化合物，以及在具有齐来维诺 - 活性氢原子的反应条件下为液体的单官能起始化合物。
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