公开(公告)号：US09029495B2

公开(公告)日：2015-05-12

申请号：US13381130

申请日：2010-06-30

Applicant: Hartmut Nefzger ,  Erika Bauer ,  Jörg Hofmann ,  Klaus Lorenz ,  Norbert Hahn

Inventor： Hartmut Nefzger ,  Erika Bauer ,  Jörg Hofmann ,  Klaus Lorenz ,  Norbert Hahn

IPC: C08G18/42 ,  C08G18/48 ,  C08G65/26 ,  C08G65/28 ,  C07C67/08 ,  C07C69/708 ,  C07C69/734 ,  C08G65/332 ,  C07C69/757 ,  C07C69/76 ,  C07C69/80 ,  C07C69/82

CPC classification number: C08G18/4887 ,  C07C67/08 ,  C07C69/708 ,  C07C69/734 ,  C07C69/757 ,  C07C69/76 ,  C07C69/80 ,  C07C69/82 ,  C08G18/4866 ,  C08G65/2615 ,  C08G65/2663 ,  C08G65/2669 ,  C08G65/2672 ,  C08G65/3324 ,  C08G65/3326

Abstract: The present invention relates to a process for producing polyether polyols having primary hydroxyl end groups, comprising the steps of reacting a starter compound containing active hydrogen atoms with an epoxide under double metal cyanide catalysis, reacting the resulting product with a cyclic carboxylic anhydride and reacting this resulting product with ethylene oxide in the presence of a catalyst containing at least one nitrogen atom per molecule, excluding non-cyclic, identically substituted tertiary amines. The invention further relates to polyether polyols obtainable by this process, compositions containing said polyols and polyurethane polymers based on said polyols.

Abstract translation: 本发明涉及一种制备具有伯羟基端基的聚醚多元醇的方法，包括以下步骤：在双金属氰化物催化下使含有活性氢原子的起始化合物与环氧化物反应，使所得产物与环状羧酸酐反应， 在每分子含有至少一个氮原子的催化剂的存在下，得到的产物与环氧乙烷不同，不包括非环状，相同取代的叔胺。 本发明还涉及可通过该方法获得的聚醚多元醇，所述组合物含有所述多元醇和基于所述多元醇的聚氨酯聚合物。

公开(公告)号：US08592623B2

公开(公告)日：2013-11-26

申请号：US13127300

申请日：2009-11-03

Applicant: Rolf Roers ,  Hartmut Nefzger ,  Erika Bauer ,  Johannes Van De Braak ,  Torsten Heinemann ,  Jürgen Schloβmacher

Inventor： Rolf Roers ,  Hartmut Nefzger ,  Erika Bauer ,  Johannes Van De Braak ,  Torsten Heinemann ,  Jürgen Schloβmacher

IPC: C08G63/20 ,  C07C69/54

CPC classification number: C08G18/425 ,  C08G18/4018 ,  C08G18/7664 ,  C08G18/794 ,  C08G63/672 ,  C08G63/78 ,  C08G2101/0025 ,  C08G2101/005 ,  C08G2350/00 ,  Y10T428/24999

Abstract: Polyester polyols are produced from at least one carboxylic acid hydride and diethylene glycol by a process in which the formation of 1,4-dioxane is suppressed. These polyester polyols are useful for producing polyurethane (PUR) and polyisocyanurate (PIR) foams and metal composite elements containing these PUR or PIR foams.

Abstract translation: 通过抑制1,4-二恶烷的形成的方法由至少一种羧酸氢化物和二甘醇制备聚酯多元醇。 这些聚酯多元醇可用于制备含有这些PUR或PIR泡沫的聚氨酯（PUR）和聚异氰脲酸酯（PIR）泡沫和金属复合元素。

公开(公告)号：US07772321B2

公开(公告)日：2010-08-10

申请号：US10897683

申请日：2004-07-22

Applicant: Hartmut Nefzger ,  Erika Bauer ,  Erhard Michels

Inventor： Hartmut Nefzger ,  Erika Bauer ,  Erhard Michels

IPC: C08F283/02 ,  C08F2/32 ,  C08F257/02 ,  C08K5/10 ,  C08G18/42

CPC classification number: C08G18/631 ,  C08F2/06 ,  C08F283/00 ,  C08F283/02 ,  C08F283/06 ,  C08G18/10 ,  C08G18/4072 ,  C08G63/688 ,  C08G64/081 ,  C08G2101/0066 ,  C08G2410/00 ,  C08G18/40

Abstract: The present invention relates to polymer dispersions in polyester polyols, a process for producing them and their use for the production of polyurethanes, in particular microcellular polyurethanes. These polyester polyols have sulfur atoms and are free of olefinically unsaturated groups.

Abstract translation: 本发明涉及聚酯多元醇中的聚合物分散体，其制备方法及其用于生产聚氨酯，特别是微孔聚氨酯的用途。 这些聚酯多元醇具有硫原子并且不含烯属不饱和基团。

公开(公告)号：US20050137275A1

公开(公告)日：2005-06-23

申请号：US11002942

申请日：2004-12-02

Applicant: Hartmut Nefzger ,  Erika Bauer ,  Erhard Michels ,  Nils Perchenek

Inventor： Hartmut Nefzger ,  Erika Bauer ,  Erhard Michels ,  Nils Perchenek

IPC: C08F2/04 ,  C08F12/00 ,  C08F16/36 ,  C08F18/08 ,  C08F20/00 ,  C08F36/00 ,  C08F283/02 ,  C08G18/42 ,  C08G18/63 ,  C08L75/00

CPC classification number: C08G18/631 ,  C08F283/02 ,  C08G2101/0066 ,  C08G2410/00

Abstract: The present invention relates to polymer dispersions in polyester polyols, to a process for their preparation, and to the preparation of polyurethanes, especially microcellular polyurethanes, from these polymer dispersions.

Abstract translation: 本发明涉及聚酯多元醇中的聚合物分散体，其制备方法，以及由这些聚合物分散体制备聚氨酯，尤其是微孔聚氨酯。

公开(公告)号：US09328196B2

公开(公告)日：2016-05-03

申请号：US13988606

申请日：2011-11-18

Applicant: Hartmut Nefzger ,  Jörg Hofmann ,  Erika Bauer ,  Bert Klesczewski ,  Klaus Lorenz

Inventor： Hartmut Nefzger ,  Jörg Hofmann ,  Erika Bauer ,  Bert Klesczewski ,  Klaus Lorenz

IPC: C08G63/91 ,  C08G63/06 ,  C08G63/664 ,  C08G63/87 ,  C08G18/42 ,  C08G18/36 ,  C08G63/82 ,  C08G18/40 ,  C08G18/48 ,  C08G18/66 ,  C08G18/76 ,  C08G18/08 ,  C08G101/00

CPC classification number: C08G63/912 ,  C08G18/14 ,  C08G18/36 ,  C08G18/4018 ,  C08G18/4283 ,  C08G18/4288 ,  C08G18/4804 ,  C08G18/4841 ,  C08G18/4891 ,  C08G18/6696 ,  C08G18/7664 ,  C08G63/06 ,  C08G63/664 ,  C08G63/82 ,  C08G63/87 ,  C08G2101/0008 ,  C08G2101/0058 ,  C08G2101/0083

Abstract: The present invention relates to a process for the preparation of polyricinoleic acid ester polyols having primary hydroxyl end groups. It furthermore relates to polyricinoleic acid ester polyols obtainable according to the invention and polyurethane polymers prepared using these polyols. The process comprises the steps: a) polycondensation of ricinoleic acid until a hydroxyl number of >0 mg of KOH/g to 80% by weight to

Abstract translation: 本发明涉及一种制备具有伯羟基端基的聚亚油酸酯多元醇的方法。 此外，它还涉及根据本发明获得的聚亚油酸酯多元醇和使用这些多元醇制备的聚氨酯聚合物。 该方法包括以下步骤：a）蓖麻油酸的缩聚直到羟基数> KOH / g至<60mg KOH / g为止; 和b）将步骤a）中获得的产物或包含羧基的步骤a）中获得的产物的次要产物与通式（I）的环氧化物反应，其中R 1表示氢，烷基或芳基 基团，基于所使用的环氧化物（I）的总量，> 80重量％至<100重量％是环氧乙烷，并且在作为催化剂的胺存在下进行反应。

公开(公告)号：US09139685B2

公开(公告)日：2015-09-22

申请号：US13381139

申请日：2010-06-29

Applicant: Hartmut Nefzger ,  Jörg Hofmann ,  Bert Klesczewski ,  Erika Bauer ,  Klaus Lorenz

Inventor： Hartmut Nefzger ,  Jörg Hofmann ,  Bert Klesczewski ,  Erika Bauer ,  Klaus Lorenz

IPC: C08G18/00 ,  C08G18/42 ,  C08G18/76 ,  C08G63/91 ,  C08G77/46 ,  C08G101/00

CPC classification number: C08G18/4291 ,  C08G18/4241 ,  C08G18/4261 ,  C08G18/4263 ,  C08G18/7621 ,  C08G63/916 ,  C08G77/46 ,  C08G2101/0008 ,  C08G2101/005 ,  C08G2101/0083

Abstract: The invention relates to a process for the preparation of a polyurethane polymer, comprising the step of reaction ofA) polyester polyols with secondary hydroxyl end groups, which are obtainable from the reaction of a polyester comprising carboxyl end groups with an epoxide of the general formula (1): wherein R1 represents an alkyl radical or an aryl radical and wherein the polyester comprising carboxyl end groups has an acid number of from ≧25 mg of KOH/g to ≦400 mg of KOH/g and a hydroxyl number of ≦5 mg of KOH/g, with B) polyisocyanates which are chosen from the group comprising toluoylene-diisocyanate, diphenylmethane-diisocyanate, polymeric diphenylmethane-diisocyanate, xylylene-diisocyanate, naphthylene-diisocyanate, hexamethylene-diisocyanate, diisocyanatodicyclohexylmethane and/or isophorone-diisocyanate. The invention furthermore relates to polyurethane polymers prepared by such a process.

Abstract translation: 本发明涉及一种制备聚氨酯聚合物的方法，包括A）聚酯多元醇与仲羟基端基反应的步骤，其可从包含羧基端基的聚酯与通式 （1）表示：其中R1表示烷基或芳基，其中包含羧基端基的聚酯的酸值为≥25mgKOH / g至＆lt; NlE; 400mg KOH / g，羟值为＆ ; B）多异氰酸酯，其选自甲苯二异氰酸酯，二苯基甲烷二异氰酸酯，聚合二苯基甲烷二异氰酸酯，亚二甲苯基二异氰酸酯，亚萘基二异氰酸酯，六亚甲基二异氰酸酯，二异氰酸二环己基甲烷和/或异佛尔酮 - 二异氰酸酯。 本发明还涉及通过这种方法制备的聚氨酯聚合物。

公开(公告)号：US08110704B2

公开(公告)日：2012-02-07

申请号：US11591779

申请日：2006-11-02

Applicant: James Michael Barnes ,  Hartmut Nefzger ,  Erika Bauer ,  Stefan Penninger ,  Thomas Schultz ,  Heinrich Lutz ,  Horst Di Mews ,  Charles S. Gracik

Inventor： James Michael Barnes ,  Hartmut Nefzger ,  Erika Bauer ,  Stefan Penninger ,  Thomas Schultz ,  Heinrich Lutz ,  Horst Di Mews ,  Charles S. Gracik

IPC: C07C265/00 ,  C07C291/00 ,  C08F6/00 ,  C08J3/00

CPC classification number: C08G18/4277 ,  C08G18/10 ,  C08G18/7678 ,  C08G18/3206

Abstract: Stable NCO prepolymers are produced from polyisocyanates having a melting point greater than 70° C., preferably, naphthalene diisocyanate, having advantageous physical properties. An important feature of the process of the present invention is the rapid cooling of the prepolymer. The process of the present invention may be carried out on a continuous or batch basis. The prepolymers of the present invention are particularly suitable for the production of cast polyurethane elastomers.

Abstract translation: 稳定的NCO预聚物由熔点大于70℃的多异氰酸酯，优选萘二异氰酸酯制成，具有有利的物理性能。 本发明方法的一个重要特征是快速冷却预聚物。 本发明的方法可以连续或间歇地进行。 本发明的预聚物特别适用于生产铸塑聚氨酯弹性体。

公开(公告)号：US20100022739A1

公开(公告)日：2010-01-28

申请号：US12515775

申请日：2007-11-23

Applicant: Hartmut Nefzger ,  Erika Bauer ,  Michael Ludewig ,  Matthias Schaub ,  Klaus-Dieter Nehren ,  Michael Freckmann ,  Holger Urbas

Inventor： Hartmut Nefzger ,  Erika Bauer ,  Michael Ludewig ,  Matthias Schaub ,  Klaus-Dieter Nehren ,  Michael Freckmann ,  Holger Urbas

IPC: C08G77/04

CPC classification number: C08G18/4825 ,  C08G18/10 ,  C08G65/33348 ,  C08G65/336 ,  C08G18/289

Abstract: The present invention relates to impression compounds based on polyether derivatives, a process for their production and their use.

Abstract translation: 本发明涉及基于聚醚衍生物的印模化合物，其制备方法及其用途。

公开(公告)号：US20070265413A1

公开(公告)日：2007-11-15

申请号：US11800117

申请日：2007-05-04

Applicant: Henricus Peerlings ,  Wolfgang Kaufhold ,  Hartmut Nefzger ,  Erika Bauer ,  Markus Broich

Inventor： Henricus Peerlings ,  Wolfgang Kaufhold ,  Hartmut Nefzger ,  Erika Bauer ,  Markus Broich

IPC: C08G18/00

CPC classification number: C08G18/4018 ,  C08G18/3221 ,  C08G18/6607 ,  C08G18/73 ,  C08G2140/00

Abstract: Light-stable, sinterable, thermoplastic polyurethanes with improved blooming behavior and good thermal stability as well as good technical processability are produced from an aliphatic diisocyanate using one or more chain extenders corresponding to a specified formula. These polyurethanes are particularly useful in the production of molded articles, particularly molded articles for automotive interiors.

Abstract translation: 具有改善的起泡性能和良好的热稳定性以及良好的技术加工性能的光稳定的可烧结的热塑性聚氨酯由使用一种或多种对应于特定配方的扩链剂的脂族二异氰酸酯制备。 这些聚氨酯特别可用于制造模制品，特别是用于汽车内部的模塑制品。

公开(公告)号：US09605106B2

公开(公告)日：2017-03-28

申请号：US13322989

申请日：2010-05-18

Applicant: Hartmut Nefzger ,  Erika Bauer ,  Johannes Van De Braak ,  Jürgen Schlossmacher ,  Silvia Kasperek

Inventor： Hartmut Nefzger ,  Erika Bauer ,  Johannes Van De Braak ,  Jürgen Schlossmacher ,  Silvia Kasperek

IPC: C08L75/06 ,  C08J9/00 ,  C07C69/82 ,  C08G18/42 ,  C08G63/672 ,  C08G63/85 ,  C08G101/00

CPC classification number: C08G18/4252 ,  C08G18/4211 ,  C08G63/672 ,  C08G63/85 ,  C08G2101/0025 ,  C08G2101/005 ,  C08G2105/02

Abstract: The present invention relates to a method for producing a polyester polyol having a concentration of ether groups in the range from 9.0 mol/kg of polyester polyol to 22 mol/kg polyester polyol, characterized in that (i) in a first step (A) isophthalic acid, optionally in the form of a C1-C4 alkyl ester, and/or terephthalic acid, optionally in the form of a C1-C4 alkyl ester, is reacted with (B) oligoethylene glycol of the formula H—(OCH2CH2)n—OH having a numerical average number of oxyethylene groups n in the range from 3.0 to 9.0, in the presence of at least one catalyst selected from the group made up of tin(II) salts, bismuth(II) salts, and titanium tetraalkoxylates, at a temperature in the range from 160° C. to 240° C., and at a pressure in the range from 1 to 1013 mbar, for a duration in the range from 7 to 100 hours, and (ii) in a second step the reaction mixture resulting from step (i) is reacted with (C) phthalic acid and/or phthalic acid hydride, the polyester polyols obtained according to said method, and to the use thereof for producing PUR/PIR hard foam materials.