摘要:
A process is proposed for blocking underground formations in the extraction of fossil oil and/or gas, a first step involving introducing water-absorbing particles into liquid-bearing and porous rock formations, said particles being water-swellable, crosslinked and water-insoluble polymers, said particles in the water-bearing rock formation finally preventing liquid flow through the rock layers by water absorption. This process is characterized in that the absorbing particles comprise a superabsorbent polymer with anionic and/or cationic properties and a retarded swelling action. This process, which can also be carried out in saline formation waters, is notable in that the swelling of the superabsorbents used begins no earlier than after five minutes and in that the superabsorbents are obtainable by four proposed process variants and any combination thereof. This process, which does not need a carrier liquid, is notable for its simplicity and especially the controllable retardation of the swelling action under the specific conditions of underground rock formations.
摘要:
Water-soluble, hydrophobically associating copolymer comprising a monoethylenically unsaturated, water-soluble, surface-active monomer (a), and a monoethylenically unsaturated, hydrophilic monomer (b) different from monomer (a). The copolymer is prepared in the presence of a nonpolymerizable surfactant and has marked thickening properties in aqueous systems.
摘要:
Water-soluble, hydrophobically associating copolymers which comprise new types of hydrophobically associating monomers. The monomers comprise an ethylenically unsaturated group and a polyether group with block structure comprising a hydrophilic polyalkylene oxide block which consists essentially of ethylene oxide groups, and a terminal, hydrophobic polyalkylene oxide block which consists of alkylene oxides with at least 4, preferably at least 5 carbon atoms.
摘要:
Water-soluble, hydrophobically associating copolymer comprising a monoethylenically unsaturated, water-soluble, surface-active monomer (a), and a monoethylenically unsaturated, hydrophilic monomer (b) different from monomer (a). The copolymer is prepared in the presence of a nonpolymerizable surfactant and has marked thickening properties in aqueous systems.
摘要:
Water-soluble, hydrophobically associating copolymers which comprise new types of hydrophobically associating monomers. The monomers comprise an ethylenically unsaturated group and a polyether group with block structure comprising a hydrophilic polyalkylene oxide block which consists essentially of ethylene oxide groups, and a terminal, hydrophobic polyalkylene oxide block which consists of alkylene oxides with at least 4, preferably at least 5 carbon atoms.
摘要:
Water-soluble, hydrophobically associating copolymers which comprise new types of hydrophobically associating monomers. The monomers comprise an ethylenically unsaturated group and a polyether group with block structure comprising a hydrophilic polyalkylene oxide block which consists essentially of ethylene oxide groups, and a terminal, hydrophobic polyalkylene oxide block which consists of alkylene oxides with at least 4, preferably at least 5 carbon atoms.
摘要:
Water-soluble, hydrophobically associating copolymers which comprise new types of hydrophobically associating monomers. The monomers comprise an ethylenically unsaturated group and a polyether group with block structure comprising a hydrophilic polyalkylene oxide block which consists essentially of ethylene oxide groups, and a terminal, hydrophobic polyalkylene oxide block which consists of alkylene oxides with at least 4, preferably at least 5 carbon atoms.
摘要:
Surfactants of the general formula R1—X where R1 is an aliphatic C17H35-alkyl radical and X is a hydrophilic group, and the mean degree of branching of the R1 radical is from 2.8 to 3.7. Mixtures which comprise such surfactants and the use of such surfactants and of mixtures thereof for tertiary mineral oil extraction.
摘要:
The invention relates to a process for mineral oil production by means of Winsor Type III microemulsion flooding, in which an aqueous surfactant formulation comprising at least one ionic surfactant of the general formula R1—O—(CH2C(CH3)HO)m(CH2CH2O)n—XY−M+ is injected through injection boreholes into a mineral oil deposit, and crude oil is withdrawn from the deposit through production boreholes. The invention further relates to ionic surfactants of the general formula.
摘要:
Use of copolymers comprising alkylene oxide units, which copolymers comprise incorporated randomly or blockwise by polymerization (a) 50 to 93 mol % of acrylic acid and/or a water-soluble salt of acrylic acid, (b) 5 to 30 mol % of methacrylic acid and/or a water-soluble salt of methacrylic acid and (c) 2 to 20 mol % of at least one nonionic monomer of the formula I where the variables have the following meaning: R1 hydrogen or methyl; R2 a chemical bond or unbranched or branched C1-C6-alkylene; R3 identical or different unbranched or branched C2-C4-alkylene radicals; R4 unbranched or branched C1-C6-alkyl; n 3 to 50, as additive to phosphate- and/or phosphonate-comprising aqueous systems in industrial technical plants.