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    METHODS FOR BLOCKING UNDERGROUND FORMATIONS
    1.
    发明申请
    METHODS FOR BLOCKING UNDERGROUND FORMATIONS 审中-公开
    阻塞地下形态的方法

    公开(公告)号：US20110237468A1

    公开(公告)日：2011-09-29

    申请号：US12733370

    申请日：2009-11-07

    申请人： Roland Reichenbach-Klinke ,  Marcus Guzmann ,  Thomas Pfeuffer ,  Gregor Herth ,  Stefan Friedrich

    发明人： Roland Reichenbach-Klinke ,  Marcus Guzmann ,  Thomas Pfeuffer ,  Gregor Herth ,  Stefan Friedrich

    IPC分类号： C09K8/588

    CPC分类号： C09K8/5083 ,  C09K8/512 ,  C09K8/516

    摘要： A process is proposed for blocking underground formations in the extraction of fossil oil and/or gas, a first step involving introducing water-absorbing particles into liquid-bearing and porous rock formations, said particles being water-swellable, crosslinked and water-insoluble polymers, said particles in the water-bearing rock formation finally preventing liquid flow through the rock layers by water absorption. This process is characterized in that the absorbing particles comprise a superabsorbent polymer with anionic and/or cationic properties and a retarded swelling action. This process, which can also be carried out in saline formation waters, is notable in that the swelling of the superabsorbents used begins no earlier than after five minutes and in that the superabsorbents are obtainable by four proposed process variants and any combination thereof. This process, which does not need a carrier liquid, is notable for its simplicity and especially the controllable retardation of the swelling action under the specific conditions of underground rock formations.

    摘要翻译： 提出了一种在提取化石油和/或气体时阻挡地下地层的方法，第一步涉及将吸水颗粒引入含液和多孔岩层，所述颗粒是水溶胀性，交联和水不溶性聚合物 所述含水岩层中的颗粒最终通过吸水阻止液体流过岩层。 该方法的特征在于吸收颗粒包含具有阴离子和/或阳离子性质和延迟溶胀作用的超吸收性聚合物。 这个也可以在盐水形成水中进行的方法是显着的，因为使用的超吸收剂的溶胀不迟于五分钟之后开始，并且超吸收剂可通过四种所提出的方法变体及其任何组合获得。 这种不需要载体液体的方法是显而易见的，因为它的简单性，特别是在地下岩层的特定条件下可膨胀作用的可控延迟。

    RETARDED SUPERABSORBENT POLYMERS
    6.
    发明申请
    RETARDED SUPERABSORBENT POLYMERS 审中-公开
    阻滞超吸收聚合物

    公开(公告)号：US20110095227A1

    公开(公告)日：2011-04-28

    申请号：US12994201

    申请日：2009-05-15

    申请人： Gregor Herth ,  Michael Schinabeck ,  Stefan Friedrich

    发明人： Gregor Herth ,  Michael Schinabeck ,  Stefan Friedrich

    IPC分类号： B01J20/26 ,  C08F228/02 ,  C08F220/56 ,  C08J3/28

    CPC分类号： C08F220/60 ,  C04B24/2652 ,  C04B28/02 ,  C04B40/0039 ,  C04B2103/0051 ,  C04B2103/0062 ,  C04B40/0608 ,  C04B24/26

    摘要： What is claimed is a superabsorbent polymer (SAP) with anionic and/or cationic properties and retarded swelling action, which was prepared by polymerizing ethylenically unsaturated vinyl compounds. This SAP is characterized in that its swelling begins no earlier than after 5 minutes and in that it was prepared with the aid of at least one process variant selected from the group of a) polymerizing the monomer components in the presence of a combination consisting of at least one hydrolysis-stable crosslinker and at least one hydrolysis-labile crosslinker; b) polymerizing at least one permanently anionic monomer and at least one hydrolysable cationic monomer; c) coating a core polymer component with at least one further polyelectrolyte as a shell polymer; d) polymerizing at least one hydrolysis-stable monomer with at least one hydrolysis-labile monomer in the presence of at least one crosslinker. Owing to the variability of the three preparation alternatives with regard to the starting materials and the process conditions, but also owing to the possible combinations with one another, the present invention can provide superabsorbent polymers which are suitable especially for use in foams, mouldings and fibres, but also as carriers for plant growth- and fungal growth-regulating agents, and for controlled release of active ingredients, or in construction materials. The present polymers are suitable especially for use as construction material additives.

    摘要翻译： 所要求的是具有阴离子和/或阳离子性质和延迟溶胀作用的超吸收聚合物（SAP），其通过聚合烯属不饱和乙烯基化合物制备。 该SAP的特征在于其溶胀不迟于5分钟之后开始，并且其在至少一种选自以下的方法变体制备：a）在由以下组合组成的组合的存在下聚合单体组分： 至少一种水解稳定的交联剂和至少一种水解不稳定的交联剂; b）聚合至少一种永久性阴离子单体和至少一种可水解阳离子单体; c）用至少一种另外的聚电解质作为壳聚合物涂覆芯聚合物组分; d）在至少一种交联剂的存在下，使至少一种水解不稳定的单体与至少一种水解稳定的单体聚合。 由于起始材料和工艺条件的三种制备替代品的可变性，而且由于彼此可能的组合，本发明可以提供特别适用于泡沫，模制品和纤维的超吸收聚合物 ，也可用作植物生长和真菌生长调节剂的载体，以及活性成分的控制释放或建筑材料。 本发明的聚合物特别适用于建筑材料添加剂。

    Mixtures comprising branched oligomeric or polymeric compounds, and preparation and use thereof
    8.
    发明授权
    Mixtures comprising branched oligomeric or polymeric compounds, and preparation and use thereof 失效
    包含支链低聚物或聚合物的混合物及其制备和用途

    公开(公告)号：US08436072B2

    公开(公告)日：2013-05-07

    申请号：US12834373

    申请日：2010-07-12

    申请人： Gregor Herth ,  Monika Haberecht ,  Yulia Fogel ,  Francisco Javier Lopez Villanueva ,  Bernd Bruchmann

    发明人： Gregor Herth ,  Monika Haberecht ,  Yulia Fogel ,  Francisco Javier Lopez Villanueva ,  Bernd Bruchmann

    IPC分类号： C09K8/00 ,  C08F22/02 ,  C08F122/02 ,  C08F222/02

    CPC分类号： C04B24/165 ,  C04B24/2694 ,  C04B28/02 ,  C04B2103/0059 ,  C04B2103/0062 ,  C04B2103/465 ,  C08F283/01 ,  C08G63/676 ,  C08L33/064 ,  C08L71/02 ,  C09K8/035 ,  C09K8/50 ,  C09K8/508 ,  C09K8/5083 ,  C08F220/06 ,  C08F220/56 ,  C08L2666/04

    摘要： Mixtures comprising (A) at least one hydraulic or latently hydraulic binder, (B) at least one copolymer obtainable by reacting (α1) at least one ethylenically unsaturated comonomer having at least one functional group selected from COOH groups, sulfonic acid groups, nitrile groups, hydroxyalkyl groups and amino groups, or (α2) at least one (co)polymer of at least one ethylenically unsaturated comonomer having at least one functional group selected from COOH groups, sulfonic acid groups, nitrile groups, hydroxyalkyl groups and amino groups, with (β) at least one oligomeric or polymeric compound obtainable by reacting (a) at least one ethylenically unsaturated di- or polycarboxylic acid or anhydride or ester thereof with (b) at least one at least trifunctional alcohol and (c) at least one compound of the general formula I in which the variables are each defined as follows: R1 is selected from C1-C4-alkyl and hydrogen, A is the same or different and is selected from C2-C6-alkylene, n is in the range from 4 to 40, and (d) optionally at least one further compound having at least one COOH group or at least one alcoholic OH group per molecule.

    摘要翻译： 包含（A）至少一种液压或潜在水硬性粘合剂的混合物，（B）至少一种可通过（α1）至少一种具有至少一个选自COOH基团，磺酸基团，腈基团的官能团的烯属不饱和共聚单体 ，羟基烷基和氨基，或（α2）至少一种具有至少一个选自COOH基团，磺酸基团，腈基，羟基烷基和氨基的官能团的烯键式不饱和共聚单体的（共）聚合物， （β）至少一种低聚物或聚合物，其通过使（a）至少一种烯键式不饱和二元或多元羧酸或其酸酐或其酯与（b）至少一种至少三官能醇和（c）至少一种化合物 其中变量各自定义如下：R 1选自C 1 -C 4 - 烷基和氢，A相同或不同，并且选自C 2 -C 6 - 烷基 烯，n在4至40的范围内，和（d）任选地至少一种每分子具有至少一个COOH基团或至少一个醇OH基团的其它化合物。

    Water-soluble or water-swellable polymers, particularly water-soluble or water-swellable copolymers made of acrylamide and at least one ionic comonomer having a low residual monomer concentration
    9.
    发明授权
    Water-soluble or water-swellable polymers, particularly water-soluble or water-swellable copolymers made of acrylamide and at least one ionic comonomer having a low residual monomer concentration 有权
    水溶性或水溶胀性聚合物，特别是由丙烯酰胺和至少一种具有低残留单体浓度的离子共聚单体制成的水溶性或水可溶胀共聚物

    公开(公告)号：US07973095B2

    公开(公告)日：2011-07-05

    申请号：US11814633

    申请日：2006-01-16

    申请人： Gregor Herth ,  Manfred Dannehl ,  Norbert Steiner

    发明人： Gregor Herth ,  Manfred Dannehl ,  Norbert Steiner

    IPC分类号： C08F2/48 ,  C08F2/04 ,  C08F2/16 ,  C08F220/56

    CPC分类号： C08F220/56 ,  A61L15/24 ,  C08F2/46 ,  C08F6/006 ,  C08F220/34 ,  C08F220/60 ,  C08L33/26 ,  C08L33/00

    摘要： The invention relates to a process for the production of water-soluble or water-swellable polymers having a low content of residual monomers, particularly on the basis of acrylic acid and/or acrylamide and at least one additional water-soluble comonomer, in which process a monomer solution in a polymerizing state is treated with electromagnetic radiation at the earliest after reaching the maximum temperature of polymerization, and the gel obtained is subsequently crushed and dried, and it also relates to the water-soluble or water-swellable polymers as such, which can be obtained according to said process, to their use in the hygiene industry, packaging industry, in the agrarian technology or in agriculture and horticulture, in the cable industry and information technology, in the food industry, papermaking industry, and to their use as flocculation aids and as drilling fluid in petroleum production.

    摘要翻译： 本发明涉及一种生产具有低含量残留单体的水溶性或水溶胀性聚合物的方法，特别是基于丙烯酸和/或丙烯酰胺和至少一种另外的水溶性共聚单体，其中该方法 聚合状态的单体溶液在达到最高聚合温度后最早用电磁辐射处理，然后将所得凝胶压碎干燥，并且还涉及水溶性或水可溶胀聚合物， 可以根据所述方法获得它们在卫生工业，包装工业，农业技术或农业和园艺，电缆工业和信息技术，食品工业，造纸工业中的应用及其使用 作为絮凝助剂和石油生产中的钻井液。