公开(公告)号：US5891954A

公开(公告)日：1999-04-06

申请号：US929721

申请日：1997-09-15

申请人： Ronald Paul Gee ,  Judith Mervane Vincent

发明人： Ronald Paul Gee ,  Judith Mervane Vincent

IPC分类号： C08J3/03 ,  C08J3/09 ,  C08L83/04 ,  C08L83/12 ,  C08L83/06

CPC分类号： C08J3/09 ,  C08L83/04 ,  C08G77/12 ,  C08G77/14 ,  C08G77/16 ,  C08G77/18 ,  C08G77/20 ,  C08G77/46 ,  C08G77/70 ,  C08G77/80 ,  C08J2383/04

摘要： A solution of an alcohol stable emulsion or microemulsion containing an organopolysiloxane is made by polymerizing a cyclic siloxane in an aqueous medium containing the cyclic siloxane, a nonionic surfactant, an ionic surfactant, and a catalyst, until an organopolysiloxane of desired molecular weight is obtained; adding a silicone polyether to the emulsion or microemulsion and mixing the silicone polyether and the emulsion or microemulsion to form a blend; and adding the blend of silicone polyether and emulsion or microemulsion to aqueous alcohol. It is beneficial to cool the blend to below 20.degree.-25.degree. C. before adding it to aqueous alcohol. It is also beneficial to mix the silicone polyether and the emulsion or microemulsion without application of mechanically induced shear.

摘要翻译： 含有有机聚硅氧烷的醇稳定乳液或微乳液的溶液是通过在含有环状硅氧烷，非离子表面活性剂，离子表面活性剂和催化剂的水性介质中聚合环状硅氧烷制备的，直至得到所需分子量的有机聚硅氧烷; 将硅氧烷聚醚加入到乳液或微乳液中，并将硅氧烷聚醚和乳液或微乳液混合以形成共混物; 并将硅氧烷聚醚和乳液或微乳液的混合物加入到含水醇中。 在将混合物加入到含水醇中之前将共混物冷却至20〜25℃是有益的。 将硅氧烷聚醚和乳液或微乳液混合而不使用机械诱导剪切剂也是有益的。

公开(公告)号：US06316541B1

公开(公告)日：2001-11-13

申请号：US08270345

申请日：1994-07-05

申请人： Ronald Paul Gee

发明人： Ronald Paul Gee

IPC分类号： C08L8300

CPC分类号： C08G77/06

摘要： A method for making oil free polysiloxane standard, fine and microemulsions using emulsion polymerization is disclosed. The method comprises reacting a cyclicsiloxane in the presence of a catalyst, ionic surfactant and nonionic surfactant within a certain operating window. Emulsions containing silicone copolymers can also be produced using the method of the instant invention.

摘要翻译： 公开了一种制备无油聚硅氧烷标准的方法，使用乳液聚合的精细和微乳液。 该方法包括在一定操作窗口内在催化剂，离子表面活性剂和非离子表面活性剂存在下使环硅氧烷反应。 含有硅氧烷共聚物的乳液也可以使用本发明的方法制备。

公开(公告)号：US06465568B1

公开(公告)日：2002-10-15

申请号：US09659813

申请日：2000-09-11

申请人： Ronald Paul Gee ,  Burt Michael Wrolson ,  Brett Lee Zimmerman

发明人： Ronald Paul Gee ,  Burt Michael Wrolson ,  Brett Lee Zimmerman

IPC分类号： C08L8300

CPC分类号： C08G77/06 ,  Y10S516/924

摘要： Emulsions and microemulsions containing particles of siloxane polymers are prepared by an emulsion polymerization process involving (i) the formation of a mixture by combining a siloxane oligomer, an ionic surfactant, no nonionic surfactant, and water; (ii) agitating the mixture without using high shearing forces (homogenization) to form droplets of oligomer prior to polymerization that have an average diameter of greater than 10 micron/10,000 nanometer; (iii) adding a siloxane polymerization catalyst to the oligomer mixture; (iv) agitating the mixture without using high shearing forces; (v) polymerizing the oligomer to form new particles of polymer; and (vi) continuing step (v) until the polymer has increased in viscosity or molecular weight.

摘要翻译： 包含硅氧烷聚合物颗粒的乳液和微乳液通过乳液聚合方法制备，所述乳液聚合方法包括（i）通过组合硅氧烷低聚物，离子表面活性剂，非离子表面活性剂和水来形成混合物; （ii）搅拌混合物而不使用高剪切力（均质化）以在聚合之前形成平均直径大于10微米/ 10,000纳米的低聚物液滴; （iii）向所述低聚物混合物中加入硅氧烷聚合催化剂; （iv）搅拌混合物而不使用高剪切力; （v）使低聚物聚合以形成新的聚合物颗粒; 和（vi）继续步骤（v），直到聚合物的粘度或分子量增加。

公开(公告)号：US5852110A

公开(公告)日：1998-12-22

申请号：US668797

申请日：1996-06-24

申请人： Ronald Paul Gee

发明人： Ronald Paul Gee

IPC分类号： C08G77/26 ,  C08L83/08

CPC分类号： C08G77/26

摘要： The instant invention pertains to a method for making amino-functional polysiloxane emulsions wherein said method comprises the emulsion polymerization of a mixture comprising cyclosiloxanes and an aminosilane having an amino-functional group solubility parameter equal to or less than 10.0. Said emulsion polymerization is carried out in the presence of water, at least one cationic surfactant and a basic polymerization catalyst. By using an aminosilane having an amino-functional group solubility parameter of equal to or less than 10.0 it is possible to produce emulsions with higher amine concentrations in the resulting polymer.

摘要翻译： 本发明涉及一种制备氨基官能聚硅氧烷乳液的方法，其中所述方法包括含有环硅氧烷和氨基官能团溶解度参数等于或小于10.0的氨基硅烷的混合物的乳液聚合。 所述乳液聚合在水，至少一种阳离子表面活性剂和碱性聚合催化​​剂的存在下进行。 通过使用具有等于或小于10.0的氨基官能团溶解度参数的氨基硅烷，可以在所得聚合物中产生具有较高胺浓度的乳液。

公开(公告)号：US6087317A

公开(公告)日：2000-07-11

申请号：US209515

申请日：1998-12-10

申请人： Ronald Paul Gee

发明人： Ronald Paul Gee

IPC分类号： C08L83/04 ,  C08J3/03 ,  C11D17/00

CPC分类号： C08J3/03 ,  C08J2383/04

摘要： By using a nonionic surfactant as the primary emulsifier having an hydrophilic-lipophilic balance (HLB) greater than about 13, at a concentration sufficient to provide about 0.5-3 molecules per 100 square .ANG. of surface area of silicone particles; and a nonionic cosurfactant having an HLB less than about 11, at a concentration sufficient to provide 5-15 molecules of emulsifier per 100 square .ANG. of surface area of silicone particles; aqueous emulsions containing low molecular weight silicones can be prepared which possess improved particle size stability. In particular, the low molecular weight silicones have a molecular weight less than about 1,000, and a viscosity of not greater than about 5 mm.sup.2 /sec. These emulsions can be used in applications relating to laundry pre-spotting, automotive bug and tar removal, and hard surface cleaning.

摘要翻译： 通过使用非离子表面活性剂作为具有大于约13的亲水亲油平衡（HLB）的主要乳化剂，其浓度足以提供约0.5-3分子/ 100平方毫米的硅氧烷颗粒表面积; 和HLB小于约11的非离子辅助表面活性剂，其浓度足以提供5-15分子的乳化剂/ 100平方厘米的硅氧烷颗粒的表面积; 可以制备含有低分子量硅氧烷的水乳液，其具有改善的粒度稳定性。 特别地，低分子量有机硅的分子量小于约1,000，粘度不大于约5平方毫米/秒。 这些乳液可用于与洗衣预先检测，汽车臭氧和焦油去除以及硬表面清洁有关的应用。

公开(公告)号：US6074470A

公开(公告)日：2000-06-13

申请号：US209521

申请日：1998-12-10

申请人： Paul David Fisher ,  Ronald Paul Gee

发明人： Paul David Fisher ,  Ronald Paul Gee

IPC分类号： C04B41/49 ,  C09D183/06

CPC分类号： C04B41/4922

摘要： This invention relates to a stable aqueous silane emulsion with constant particle size. The emulsion comprises a continuous water phase, a discontinuous silane phase, and an emulsifier system. The emulsifier system contains a primary surfactant and a cosurfactant. The primary surfactant functions to prevent coalescence of particles, by steric or ionic repulsion between particles. The cosurfactant prevents diffusion of the silane into the aqueous phase. The combination of primary surfactant and cosurfactant results in an adsorbed inner layer of cosurfactant between the silane and the outer layer of a mixture of both surfactants which contacts the water phase. The combination of primary surfactant and cosurfactant provides a barrier which prevents diffusion of silane into the water phase. A method for preparing the emulsion is also disclosed.

摘要翻译： 本发明涉及具有恒定粒度的稳定的含水硅烷乳液。 该乳液包括连续的水相，不连续的硅烷相和乳化剂体系。 乳化剂体系含有主要的表面活性剂和辅助表面活性剂。 主要表面活性剂用于防止颗粒的聚结，通过颗粒之间的空间或离子排斥。 辅助表面活性剂防止硅烷扩散到水相中。 初级表面活性剂和辅助表面活性剂的组合导致硅烷和外层之间吸附的辅助表面活性剂内层，这两种表面活性剂与水相接触。 初级表面活性剂和辅助表面活性剂的组合提供了阻止硅烷扩散到水相中的屏障。 还公开了一种制备乳液的方法。

公开(公告)号：US5776454A

公开(公告)日：1998-07-07

申请号：US713910

申请日：1996-09-13

申请人： Ronald Paul Gee ,  Carol Anne Hoag

发明人： Ronald Paul Gee ,  Carol Anne Hoag

IPC分类号： A61K8/00 ,  A61K8/31 ,  A61K8/34 ,  A61K8/89 ,  A61K8/891 ,  A61K8/899 ,  A61Q5/04 ,  C08L83/08 ,  A61K7/09 ,  A61K7/06

CPC分类号： A61K8/899 ,  A61Q5/04

摘要： A process for permanent waving of hair by a reaction in which cystine bridges are reduced to cysteine, the hair reshaped, and the reaction reversed. The improvement in the process resides in the step of reducing or reversing the reaction by applying to hair a composition which includes an emulsion polymerized mercapto functional silicone. Permanent hair waving with waving lotions, neutralizing solutions, or both, containing such emulsion polymerized mercapto functional silicones, provide waved hair with improved conditioning benefits.

摘要翻译： 一种通过胱氨酸桥被还原成半胱氨酸的反应永久挥发毛发的过程，毛发重塑，反应相反。 该方法的改进在于通过向毛发施用包含乳液聚合的巯基官能硅氧烷的组合物来减少或逆转反应的步骤。 包含这种乳液聚合的巯基功能性硅氧烷的挥发性洗剂，中和溶液或两者的永久性头发为挥发的头发提供改善的调理益处。

公开(公告)号：US5684085A

公开(公告)日：1997-11-04

申请号：US777161

申请日：1996-12-26

申请人： Ronald Paul Gee ,  Burt Michael Wrolson

发明人： Ronald Paul Gee ,  Burt Michael Wrolson

IPC分类号： C08G77/06 ,  C08L83/08

CPC分类号： C08G77/06

摘要： Described is a method of preparing microemulsions of organopolysiloxanes, by copolymerizing a cyclic siloxane and a polyfunctional silane, in an aqueous medium containing a nonionic surfactant, an anionic or cationic surfactant, and a catalyst, until the desired increase in molecular weight is obtained. The invention resides in controlling the gel content of the organopolysiloxanes in the microemulsion by control of the concentration of silane and concentration of silanol in the resulting organopolysiloxane, such that a functionality ratio .phi. results in formation of a gel-free polymer molecular weight distribution of finite organopolysiloxane species in the microemulsion.

摘要翻译： 描述了通过在含有非离子表面活性剂，阴离子或阳离子表面活性剂和催化剂的水性介质中共聚环状硅氧烷和多官能硅烷来制备有机聚硅氧烷的微乳液的方法，直到获得所需的分子量增加。 本发明在于通过控制所得有机聚硅氧烷中硅烷的浓度和硅烷醇浓度来控制微乳液中的有机聚硅氧烷的凝胶含量，使得官能度比phi导致形成无凝胶的聚合物分子量分布有限 微乳液中的有机聚硅氧烷物质。

公开(公告)号：US6103001A

公开(公告)日：2000-08-15

申请号：US323325

申请日：1999-06-01

申请人： Paul David Fisher ,  Ronald Paul Gee

发明人： Paul David Fisher ,  Ronald Paul Gee

IPC分类号： C04B41/49 ,  C09D183/16

CPC分类号： C04B41/4922

摘要： This invention relates to a stable aqueous silane emulsion with constant particle size. The emulsion comprises a continuous water phase, a discontinuous silane phase, and an emulsifier system. The emulsifier system contains a primary surfactant and a cosurfactant. The primary surfactant functions to prevent coalescence of particles, by steric or ionic repulsion between particles. The cosurfactant prevents diffusion of the silane into the aqueous phase. The combination of primary surfactant and cosurfactant results in an adsorbed inner layer of cosurfactant between the silane and the outer layer of a mixture of both surfactants which contacts the water phase. The combination of primary surfactant and cosurfactant provides a barrier which prevents diffusion of silane into the water phase. A method for preparing the emulsion is also disclosed.

公开(公告)号：US5925469A

公开(公告)日：1999-07-20

申请号：US993552

申请日：1997-12-18

申请人： Ronald Paul Gee

发明人： Ronald Paul Gee

IPC分类号： C08L83/06 ,  C08G77/06 ,  C08G77/14 ,  C09D183/06 ,  D06M15/643 ,  D21H19/32 ,  D21H21/22 ,  B32B9/04 ,  C08J83/06

CPC分类号： D06M15/643 ,  C08G77/14 ,  C09D183/06 ,  D21H19/32 ,  D21H21/22 ,  Y10T428/31663

摘要： This invention relates to 1,2-diol functional polysiloxane emulsions obtained by a variety of polymerization methods. This invention further relates to an organopolysiloxane emulsion comprising an organopolysiloxane polymer having pendant organic diol groups, at least one nonionic surfactant, at least one anionic surfactant, and water. The emulsions of this invention are useful as fiber treatment agents and provide softness and hydrophilicity to fibers treated with the emulsion.

摘要翻译： 本发明涉及通过各种聚合方法获得的1,2-二醇官能聚硅氧烷乳液。 本发明还涉及包含具有侧基有机二醇基团的有机聚硅氧烷聚合物，至少一种非离子表面活性剂，至少一种阴离子表面活性剂和水的有机聚硅氧烷乳液。 本发明的乳液可用作纤维处理剂，并且对用乳液处理的纤维提供柔软性和亲水性。