-
1.发明授权Aminoplast-based crosslinkers and powder coating compositions containing such crosslinkers 失效含有氨基塑料的交联剂和含有这种交联剂的粉末涂料组合物公开(公告)号：US06451928B1
公开(公告)日：2002-09-17
申请号：US09666575
申请日：2000-09-21
IPC分类号： C08G6391
CPC分类号： C08L67/02 , C08K5/34922 , C09D167/00 , Y10S525/934 , Y10T428/31511 , Y10T428/31551 , Y10T428/31794 , Y10T428/31935 , C08L61/20
摘要： Provided is a crosslinking agent which is the ungelled reaction product of a polyester polyol and an aminotriazine compound having one or less non-alkylated NH bond per triazine ring. The polyester polyol is the reaction product of a cycloaliphatic polyol and a cyclic polycarboxylic acid or anhydride. The crosslinking agent is essentially free of hydroxyl functionality and has a glass transition temperature of at least 10° C. Further provided is a powder coating composition including a solid particulate film-forming mixture of a polymer containing reactive functional groups and having a Tg of at least 30° C., and the crosslinking agent. Additionally provided is a multi-layer composite coating composition having a basecoat layer deposited from a basecoat film-forming composition and a topcoat over the basecoat deposited from the previously described powder coating composition. Coated substrates are also provided.
摘要翻译： 提供了一种交联剂，其是聚酯多元醇和具有每个三嗪环具有一个或多个非烷基化NH键的氨基三嗪化合物的未凝胶化反应产物。 聚酯多元醇是脂环族多元醇与环状多元羧酸或酸酐的反应产物。 交联剂基本上不含羟基官能团并且具有至少10℃的玻璃化转变温度。还提供了一种粉末涂料组合物，其包含含有反应性官能团并且具有Tg的Tg的聚合物的固体颗粒成膜混合物 至少30℃，和交联剂。 另外提供了一种多层复合涂料组合物，其具有从底涂层成膜组合物沉积的底涂层和在前述粉末涂料组合物沉积的底涂层上的顶涂层。 还提供涂覆的基材。
-
2.发明授权Aminoplast-based crosslinkers and powder coating compositions containing such crosslinkers 失效含有氨基塑料的交联剂和含有这种交联剂的粉末涂料组合物公开(公告)号：US06500545B1
公开(公告)日：2002-12-31
申请号：US09666175
申请日：2000-09-21
IPC分类号： B32B2738
CPC分类号： C09D167/00 , C08G12/427 , C08G14/06 , C08G14/12 , C08L61/28 , C08L61/32 , C08L61/34 , C09D161/32 , C09D161/34 , C09D163/00 , C09D175/04 , Y10T428/31511 , Y10T428/31529 , Y10T428/31551 , Y10T428/31681 , Y10T428/31688 , Y10T428/31699 , Y10T428/31942 , C08L2666/16 , C08L61/20
摘要： The present invention provides a crosslinking agent having reactive benzoxazine groups which is the ungelled reaction product of (a) at least one mono-hydroxy aromatic compound and (b) at least one aminotriazine compound having one or less non-alkylated NH group present in a molar ratio of reactant (a) to reactant (b) ranging from 1.0 to 3.0: 1.0, provided that where reactant (a) is a single ring monohydroxy aromatic compound, the molar ratio of reactant (a) to reactant (b) ranges from 1.0 to 1.8:1.0 and from 2.2 to 3.0:1.0. The crosslinking agent is essentially free of hydroxyl functionality and has a glass transition temperature of at least 25° C. The present invention is further directed to a method for preparing the above-described crosslinking agent. Also provided is a curable powder coating composition comprising a solid particulate, film-forming mixture of (A) a polymer having functional groups reactive with aminotriazine and/or benzoxazine groups, the polymer having a glass transition temperature of at least 30° C.; and (B) the previously described crosslinking agent. Multilayer composite coating compositions are also provided including a base coat deposited from a film-forming composition and a topcoat over the base coat. The topcoat is deposited from the curable powder coating composition described above. The present invention further provides coated substrates.
摘要翻译： 本发明提供具有反应性苯并恶嗪基团的交联剂，其是（a）至少一种单羟基芳族化合物和（b）至少一种具有一个或多个非烷基化NH基团的氨基三嗪化合物的未凝胶化反应产物， 反应物（a）与反应物（b）的摩尔比为1.0-3.0:1.0，条件是当反应物（a）为单环一羟基芳族化合物时，反应物（a）与反应物（b）的摩尔比范围为 1.0至1.8：1.0和2.2至3.0：1.0。 交联剂基本上不含羟基官能团，玻璃化转变温度至少为25℃。本发明还涉及制备上述交联剂的方法。 还提供了一种可固化粉末涂料组合物，其包含（A）具有与氨基三嗪和/或苯并恶嗪基反应的官能团的聚合物的固体颗粒，成膜混合物，所述聚合物具有至少30℃的玻璃化转变温度; 和（B）前述交联剂。 还提供了多层复合涂料组合物，包括从成膜组合物沉积的底涂层和底涂层上的顶涂层。 从上述可固化粉末涂料组合物沉积面漆。 本发明还提供涂覆的基材。
-
3.发明授权Aminoplast-based crosslinkers and powder coating compositions containing such crosslinkers 失效含有氨基塑料的交联剂和含有这种交联剂的粉末涂料组合物公开(公告)号：US06441103B1
公开(公告)日：2002-08-27
申请号：US09666265
申请日：2000-09-21
IPC分类号： C08L7506
CPC分类号： C09D5/033 , C08G12/20 , C08G12/30 , C08G12/42 , C08G12/427 , C08G12/428 , C08G18/2825 , C08G18/3851 , C08G18/423 , C08G18/71 , C08G18/792 , C08G18/8064 , C08G2150/20 , C08K5/0025 , C08K5/34922 , C08L61/28 , C08L61/32 , C09D161/32 , C09D167/00 , Y10S524/904 , Y10S525/934 , C08L2666/20 , C08L61/20
摘要： Two types of aminotriazine-based crosslinking agents are provided. Crosslinking agent I includes the ungelled reaction product of (A) a reactive urethane group-containing reaction product and (B) an aminotriazine compound having one or less non-alkylated NH bond per triazine ring. The reactive urethane group-containing reaction product (A) is the reaction product of (1) a polyester polyol, and (2) a mono-isocyanate. The crosslinking agent I is essentially free of urethane NH functionality and has a glass transition temperature of at least 25° C. Crosslinking agent II includes the ungelled reaction product of (A) a reactive urethane group-containing reaction product and (B) an aminotriazine compound having one or less non-alkylated NH bond per triazine ring. The reactive urethane group-containing reaction product (A) is the reaction product of (1) a polyisocyanate and (2) a monohydric capping agent. The crosslinking agent II is essentially free of urethane N—H functionality and has a glass transition temperature of at least 10° C. Methods for preparing crosslinking agents I and II are also provided. Further provided is a curable composition of a film-forming polymer having reactive functional groups and the previously described crosslinking agent II. Also provided are powder coating compositions which each include a solid particulate mixture of a reactive group-containing polymer having a Tg of at least 30° C and the previously described crosslinking agents I or II. Multilayer composite coating compositions and coated substrates are also provided.
摘要翻译： 提供了两种类型的氨基三嗪类交联剂。 交联剂I包括（A）含有反应性氨基甲酸酯基的反应产物和（B）具有每个三嗪环具有一个或多个非烷基化NH键的氨基三嗪化合物的未凝胶化反应产物。 反应性氨基甲酸酯基反应产物（A）是（1）聚酯多元醇和（2）单异氰酸酯的反应产物。 交联剂I基本上不含氨基甲酸酯官能团，玻璃化转变温度至少为25℃。交联剂II包括（A）反应性氨基甲酸酯基反应产物和（B）氨基三嗪的未凝胶化反应产物 每个三嗪环具有一个或多个非烷基化NH键的化合物。 反应性氨基甲酸酯基反应产物（A）是（1）多异氰酸酯与（2）一羟基封端剂的反应产物。 交联剂II基本上不含氨基甲酸酯N-H官能团，玻璃化转变温度至少为10℃。还提供了制备交联剂I和II的方法。 还提供了具有反应性官能团的成膜聚合物和前述交联剂II的可固化组合物。 还提供了粉末涂料组合物，其各自包含Tg至少为30℃的反应性基团聚合物和前述交联剂I或II的固体颗粒混合物。 还提供了多层复合涂层组合物和涂覆的基底。
-
4.发明授权Aminoplast-based crosslinkers and powder coating compositions containing such crosslinkers 失效含有氨基塑料的交联剂和含有这种交联剂的粉末涂料组合物公开(公告)号：US06479611B2
公开(公告)日：2002-11-12
申请号：US10058928
申请日：2002-01-28
IPC分类号： C08G1810
CPC分类号： C09D5/033 , C08G12/20 , C08G12/30 , C08G12/42 , C08G12/427 , C08G12/428 , C08G18/2825 , C08G18/3851 , C08G18/423 , C08G18/71 , C08G18/792 , C08G18/8064 , C08G2150/20 , C08K5/0025 , C08K5/34922 , C08L61/28 , C08L61/32 , C09D161/32 , C09D167/00 , Y10S524/904 , Y10S525/934 , C08L2666/20 , C08L61/20
摘要： Two types of aminotriazine-based crosslinking agents are provided. Crosslinking agent I includes the ungelled reaction product of (A) a reactive urethane group-containing reaction product and (B) an aminotriazine compound having one or less non-alkylated NH bond per triazine ring. The reactive urethane group-containing reaction product (A) is the reaction product of (1) a polyester polyol, and (2) a mono-isocyanate. The crosslinking agent I is essentially free of urethane NH functionality and has a glass transition temperature of at least 25° C. Crosslinking agent II includes the ungelled reaction product of (A) a reactive urethane group-containing reaction product and (B) an aminotriazine compound having one or less non-alkylated NH bond per triazine ring. The reactive urethane group-containing reaction product (A) is the reaction product of (1) a polyisocyanate and (2) a monohydric capping agent. The crosslinking agent II is essentially free of urethane N—H functionality and has a glass transition temperature of at least 10° C. Methods for preparing crosslinking agents I and II are also provided. Further provided is a curable composition of a film-forming polymer having reactive functional groups and the previously described crosslinking agent II. Also provided are powder coating compositions which each include a solid particulate mixture of a reactive group-containing polymer having a Tg of at least 30° C. and the previously described crosslinking agents I or II. Multilayer composite coating compositions and coated substrates are also provided.
摘要翻译： 提供了两种类型的氨基三嗪类交联剂。 交联剂I包括（A）含有反应性氨基甲酸酯基的反应产物和（B）具有每个三嗪环具有一个或多个非烷基化NH键的氨基三嗪化合物的未凝胶化反应产物。 反应性氨基甲酸酯基反应产物（A）是（1）聚酯多元醇和（2）单异氰酸酯的反应产物。 交联剂I基本上不含氨基甲酸酯官能团，玻璃化转变温度至少为25℃。交联剂II包括（A）反应性氨基甲酸酯基反应产物和（B）氨基三嗪的未凝胶化反应产物 每个三嗪环具有一个或多个非烷基化NH键的化合物。 反应性氨基甲酸酯基反应产物（A）是（1）多异氰酸酯与（2）一羟基封端剂的反应产物。 交联剂II基本上不含氨基甲酸酯N-H官能团，玻璃化转变温度至少为10℃。还提供了制备交联剂I和II的方法。 还提供了具有反应性官能团的成膜聚合物和前述交联剂II的可固化组合物。 还提供了粉末涂料组合物，其各自包含Tg至少为30℃的反应性基团聚合物和前述交联剂I或II的固体颗粒混合物。 还提供了多层复合涂层组合物和涂覆的基底。
-
5.发明授权Aminoplast-based crosslinkers and powder coating compositions containing such crosslinkers 失效含有氨基塑料的交联剂和含有这种交联剂的粉末涂料组合物公开(公告)号：US06316109B1
公开(公告)日：2001-11-13
申请号：US09666253
申请日：2000-09-21
IPC分类号： C07D26512
CPC分类号： C09D5/033 , C08G14/06 , C08G14/10 , C08G14/12 , C08G59/4007 , C08K5/357 , C08L61/32 , C08L61/34 , C09D161/32 , C09D161/34 , Y10T428/31511 , Y10T428/31551 , Y10T428/31794 , Y10T428/31855
摘要： A crosslinking agent having reactive benzoxazine groups is provided. The crosslinking agent is the ungelled reaction product of a polyhydric aromatic compound and an aminotriazine compound having one or less non-alkylated NH bond per triazine ring. The crosslinking agent is essentially free of hydroxyl functionality and has a glass transition temperature of at least 10° C. Additionally provided is a method for preparing the crosslinking agent. Also provided is a curable powder coating composition including a solid particulate, film-forming mixture of a polymer having functional groups reactive with benzoxazine groups and the crosslinking agent. Further provided is a multilayer composite coating composition having a base coat layer deposited from a film-forming base coating composition and a topcoat layer deposited from the curable powder coating composition. Coated substrates are also provided.
摘要翻译： 提供了具有反应性苯并恶嗪基团的交联剂。 交联剂是多元芳族化合物和每三嗪环具有一个或多个非烷基化NH键的氨基三嗪化合物的未凝胶化反应产物。 交联剂基本上不含羟基官能团并且具有至少10℃的玻璃化转变温度。另外提供了制备交联剂的方法。 还提供了一种可固化粉末涂料组合物，其包含具有与苯并恶嗪基团反应的官能团的聚合物的固体颗粒，成膜混合物和交联剂。 还提供了一种多层复合涂料组合物，其具有从成膜基础涂料组合物沉积的底涂层和由可固化粉末涂料组合物沉积的外涂层。 还提供涂覆的基材。
-
6.发明授权Modified aminoplast crosslinkers and powder coating compositions containing such crosslinkers 失效含有这种交联剂的改性氨基塑料交联剂和粉末涂料组合物公开(公告)号：US06784258B2
公开(公告)日：2004-08-31
申请号：US09918983
申请日：2001-07-31
IPC分类号： C08L7500
CPC分类号： C09D161/32 , C08G12/20 , C08G12/30 , C08G12/42 , C08G12/427 , C08G12/428 , C08G18/2825 , C08G18/3851 , C08G18/423 , C08G18/71 , C08G18/792 , C08G18/8064 , C08G2150/20 , C08K5/0025 , C08K5/34922 , C08L61/28 , C08L61/32 , C09D5/033 , C09D167/00 , C09D175/04 , Y10S524/904 , Y10S525/934 , C08L2666/16 , C08L2666/20 , C08L61/20
摘要： A crosslinking agent is provided, prepared by reacting (A) an aminoplast resin; (B) a reactive urethane group-containing adduct and (C) at least one other compound having active hydrogen groups reactive with aminoplast resin (A). Compound (C) is selected from: (i) compounds having the structure (I): wherein X is aromatic; R1, R2, and R3 each independently represents H, (cyclo)alkyl having from 1 to 12 carbon atoms, aryl, alkaryl, aralkyl, or an active hydrogen-containing group, (ii) compounds having the structure (II) or (III): where R′ and R″ each independently represents an aromatic group or an alkyl group having 1 to 12 carbon atoms; and (iii) compounds different from (i) and (ii), having a melting point of at least 80° C. Further provided are methods for preparing the crosslinking agent curable compositions containing the crosslinking agent, and coated substrates.
摘要翻译： 提供了一种通过（A）氨基塑料树脂反应制备的交联剂; （B）含反应性氨基甲酸酯基团的加合物和（C）至少一种具有与氨基塑料树脂（A）反应的活性氢基团的其它化合物。 化合物（C）选自：（i）具有结构（I）的化合物：其中X是芳族的; R 1，R 2和R 3各自独立地表示H 1，具有1至12个碳原子的（环）烷基，芳基，烷芳基，芳烷基或含活性氢基团，（ii）化合物 具有结构（II）或（III）：其中R'和R“各自独立地表示芳族基团或具有1至12个碳原子的烷基; 和（iii）不同于（i）和（ii）的化合物，其熔点至少为80℃。进一步提供了制备含有交联剂的交联剂可固化组合物和涂覆的基材的方法。
-
7.发明授权Modified aminoplast crosslinkers and powder coating compositions containing such crosslinkers 失效含有这种交联剂的改性氨基塑料交联剂和粉末涂料组合物公开(公告)号：US06797387B2
公开(公告)日：2004-09-28
申请号：US09919094
申请日：2001-07-31
IPC分类号： B32B2706
CPC分类号： C08G12/30 , C08G12/20 , C08G12/42 , C08G12/427 , C08G12/428 , C08G18/2825 , C08G18/3851 , C08G18/423 , C08G18/71 , C08G18/792 , C08G18/8064 , C08G2150/20 , C08K5/0025 , C08K5/34922 , C08L61/28 , C08L61/32 , C09D5/033 , C09D161/32 , C09D167/00 , Y10S524/904 , Y10S525/934 , Y10T428/31576 , Y10T428/31794 , C08L2666/20 , C08L61/20
摘要： A crosslinking agent is provided, prepared by reacting (A) an aminoplast resin; (B) a reactive urethane group-containing adduct of a polyfunctional polymer and monoisocyanate, and (C) at least one other compound having active hydrogen groups reactive with aminoplast resin (A). Compound (C) is selected from: (i) compounds having the structure (I): wherein X is aromatic; R1, R2, and R3 each independently represents H, (cyclo)alkyl having from 1 to 12 carbon atoms, aryl, alkaryl, aralkyl, or an active hydrogen-containing group, (ii) compounds having the structure (II) or (III): where R′ and R″ each independently represents an aromatic group or an alkyl group having 1 to 12 carbon atoms; and (iii) compounds different from (i) and (ii), having a melting point of at least 80° C. Further provided are methods for preparing the crosslinking agent, curable compositions containing the crosslinking agent, and coated substrates.
摘要翻译： 提供了一种通过（A）氨基塑料树脂反应制备的交联剂; （B）多官能聚合物和单异氰酸酯的反应性氨基甲酸酯基加合物，和（C）至少一种具有与氨基塑料树脂（A）反应的活性氢基团的其它化合物。 化合物（C）选自：（i）具有结构（I）的化合物：其中X是芳族的; R 1，R 2和R 3各自独立地表示H 1，具有1至12个碳原子的（环）烷基，芳基，烷芳基，芳烷基或含活性氢基团，（ii）化合物 具有结构（II）或（III）：其中R'和R“各自独立地表示芳族基团或具有1至12个碳原子的烷基; 和（iii）不同于（i）和（ii）的化合物，其熔点至少为80℃。进一步提供了制备交联剂的方法，含有交联剂的可固化组合物和涂覆的基材。
-
8.发明授权Aminoplast-based crosslinkers and powder coating compositions containing such crosslinkers 失效含有氨基塑料的交联剂和含有这种交联剂的粉末涂料组合物公开(公告)号：US06713182B2
公开(公告)日：2004-03-30
申请号：US10206719
申请日：2002-07-25
IPC分类号： B32B2738
CPC分类号： C08L67/02 , C08K5/34922 , C09D167/00 , Y10S525/934 , Y10T428/31511 , Y10T428/31551 , Y10T428/31794 , Y10T428/31935 , C08L61/20
摘要： Provided is a crosslinking agent which is the ungelled reaction product of a polyester polyol and an aminotriazine compound having one or less non-alkylated NH bond per triazine ring. The polyester polyol is the reaction product of a cycloaliphatic polyol and a cyclic polycarboxylic acid or anhydride. The crosslinking agent is essentially free of hydroxyl functionality and has a glass transition temperature of at least 10° C. Further provided is a powder coating composition including a solid particulate film-forming mixture of a polymer containing reactive functional groups and having a Tg of at least 30° C., and the crosslinking agent. Additionally provided is a multi-layer composite coating composition having a basecoat layer deposited from a basecoat film-forming composition and a topcoat over the basecoat deposited from the previously described powder coating composition. Coated substrates are also provided.
摘要翻译： 提供了一种交联剂，其是聚酯多元醇和具有每个三嗪环具有一个或多个非烷基化NH键的氨基三嗪化合物的未凝胶化反应产物。 聚酯多元醇是脂环族多元醇与环状多元羧酸或酸酐的反应产物。 交联剂基本上不含羟基官能团并且具有至少10℃的玻璃化转变温度。还提供了一种粉末涂料组合物，其包含含有反应性官能团并且具有Tg的Tg的聚合物的固体颗粒成膜混合物 至少30℃，和交联剂。 另外提供了一种多层复合涂料组合物，其具有从底涂层成膜组合物沉积的底涂层和在前述粉末涂料组合物沉积的底涂层上的顶涂层。 还提供涂覆的基材。
-
9.发明授权Modified aminoplast crosslinkers and powder coating compositions containing such crosslinkers 失效含有这种交联剂的改性氨基塑料交联剂和粉末涂料组合物公开(公告)号：US06663972B2
公开(公告)日：2003-12-16
申请号：US09918848
申请日：2001-07-31
IPC分类号： C07D26512
CPC分类号： C08G14/10 , C08G14/06 , C08G14/12 , C08G59/4007 , C08K5/357 , C08L61/32 , C08L61/34 , C09D5/033 , C09D161/32 , C09D161/34 , Y10T428/31511 , Y10T428/31551 , Y10T428/31855
摘要： A crosslinking agent having reactive benzoxazine groups is provided. The crosslinking agent is an ungelled reaction product of aminoplast resin, a polyhydric aromatic compound, and at least one compound having active hydrogen groups reactive with aminoplast resin which is selected from at least one of: (i) compounds having the structure (I): where X is aromatic; R1, R2, and R3 each independently represents H, (cyclo)alkyl having from 1 to 12 carbon atoms, aryl, alkaryl, aralkyl, or an active hydrogen-containing group; (ii) compounds having structure (II) or (III): where R′ and R″ each independently represents an aromatic group or an alkyl group having 1 to 12 carbon atoms; and (iii) compounds different from (i) and (ii) and having a melting point of at least 80° C. Curable powder coating composition and multilayer composite coating compositions are also provided, as well as coated substrates.
摘要翻译： 提供了具有反应性苯并恶嗪基团的交联剂。 交联剂是氨基塑料树脂，多元芳族化合物和至少一种具有与氨基塑料树脂反应的活性氢基团的化合物的非凝胶化反应产物，其选自以下至少一种：（i）具有结构（I）的化合物： 其中X是芳香族; R 1，R 2和R 3各自独立地表示H，具有1至12个碳原子的（环）烷基，芳基，烷芳基，芳烷基或含活性氢基团; （ii）具有结构（II）或（III）的化合物：其中R'和R“各自独立地表示芳族基团或具有1至12个碳原子的烷基; 和（iii）不同于（i）和（ii）的化合物，并具有至少80℃的熔点。也提供可固化的粉末涂料组合物和多层复合涂料组合物以及涂覆的基材。
-
10.发明授权公开(公告)号：US06613436B2
公开(公告)日：2003-09-02
申请号：US09919092
申请日：2001-07-31
IPC分类号： B32B2738
CPC分类号： C08G12/427 , C08G14/06 , C08G14/12 , C08L61/28 , C08L61/32 , C08L61/34 , C09D161/32 , C09D161/34 , C09D163/00 , C09D167/00 , C09D175/04 , Y10T428/31511 , Y10T428/31529 , Y10T428/31551 , Y10T428/31594 , Y10T428/31681 , Y10T428/31688 , Y10T428/31699 , Y10T428/31862 , Y10T428/31942 , C08L2666/16 , C08L61/20
摘要： The present invention provides a crosslinking agent which may have reactive benzoxazine groups prepared from (a) at least one aromatic compound, (b) at least one aminotriazine compound, and (c) at least one other compound having active hydrogen groups reactive with aminoplast compound (b). The crosslinking agent is essentially free of hydroxyl functionality and has a glass transition temperature of at least 25° C. The present invention is further directed to a method for preparing the above-described crosslinking agent, and a curable powder coating composition comprising a mixture of (A) a polymer having functional groups reactive with aminotriazine and/or benzoxazine groups having a glass transition temperature of at least 30° C.; and (B) the above crosslinking agent. Multilayer composite coating compositions are also provided including a basecoat deposited from a film-forming composition and a topcoat over the basecoat, deposited from the curable powder coating composition described above. Coated substrates are also provided.
-
-
-
-
-
-
-
-
-
搜索结果
88 条记录 (耗时 0.034 秒)
