摘要:
Cyanine dyes are disclosed having a nucleus of the formula: ##STR1## wherein; A and B are independently selected from the group consisting of heterocyclic ring nuclei and heterocyclic fused ring nuclei so as to complete a cyanine dye,m and n independently have values of 0, 1, 2 or 3 with the proviso that 2.ltoreq.m+n.ltoreq.4,R is selected from the group consisting of hydrogen, alkyl groups and aryl groups, each of which groups may be substituted, andQ represents those non-metallic atoms necessary to complete a nucleus selected from the group consisting of heterocyclic ring nuclei, carbocyclic ring nuclei, heterocyclic fused ring nuclei and carbocyclic fused ring nuclei.The cyanine dyes of formula (I) may be used to spectrally sensitise silver halide grains to radiation in the wavelength range from 650 nm upwards, especially 700 to 850 nm, to provide infrared-sensitive, silver halide photographic materials which are particularly suitable for use with electronically modulated exposure sources, such as lasers and light emitting diodes.
摘要:
Compounds suitable for use as antihalation or acutance dyes in silver halide photographic emulsions having a nucleus of the general formula (I), ##STR1## in which: Y and Z independently represent the non-metallic atoms necessary to complete a carbocyclic or heterocyclic ring or a fused ring system,M.sup..sym. is a cation, and,X represents the non-metallic atoms necessary to complete a 5-, 6- or 7- membered carbocyclic ring, a 5-,6- or 7- membered heterocyclic ring or a fused ring system on a 5-, 6- or 7- membered nucleus and comprising up to 14 total ring atoms selected from C,N, 0, S and Se.
摘要:
Pepper fog may be reduced in high contrast photographic materials comprising silver halide emulsion in association with a hydrazine by the presence of at least 0.001 mole per mole of silver halide of a water-soluble bromide and/or water-soluble chloride. Suitable water-soluble bromides and chlorides are alkali metal bromides and chlorides which are advantageously added to the silver halide emulsion after physical ripening and washing.
摘要:
A negative-acting photographic element comprising a support having coated thereon one or more layers of a radiation-sensitive silver halide emulsion, at least one of the layers containing a hydrazine compound in which the one or more radiation-sensitive silver halide layers contain a first silver halide emulsion having an average grain size of from 0.1 to 0.4 microns and a second silver halide emulsion of particles with an average grain volume of less than one half that of the particles of the first emulsion.
摘要:
Compounds suitable for use as acutance, antihalation and filter dyes in silver halide imaging materials having a nucleus represented by a compound comprising a nucleus represented by one of the following general formulae (I) and (II): in which; A and B independently represent those non-metallic atoms necessary to complete a neutral heterocyclic ring in which at least one ring atom is nitrogen, R represents hydrogen or an alkyl group, and Y represents a divalent aliphatic linking group.
摘要:
A photosensitive element having a photosensitive medium comprising silver halide in reactive association with an organoborate salt and wherein said medium is selected from:(a) silver halide photographic emulsions comprising a cationic dye, and(b) photothermographic media comprising in one or more layers a reducible silver source, a reducing agent for silver ion and an antifoggant.
摘要:
A silver halide photographic light sensitive emulsion containing a hydrazine of the general formulaR.sup.3 -NR.sup.4 -NR.sup.5 -G-X (I)in which:R.sup.3 represents an aryl group,one of R.sup.4 and R.sup.5 is a hydrogen and the other is selected from hydrogen, aryl sulphonyl and trifluoroacetyl,G represents carbonyl, sulphonyl, sulphoxy, phosphoryl or an N-substituted or unsubstituted imino group andX is a moiety such that at a pH in the range of 9.5 to 12.5 in the presence of an oxidized hydroquinone a cyclization reaction takes place cleaving the moiety -G-X from the remainder of the molecule and forming a cyclic structure comprising atoms of the moiety -G-X.
摘要:
A black and white photographic element comprising as a photosensitive medium a layer of a silver halide emulsion characterised in that the photosensitive medium comprises in the same layer or in an adjacent layer thereto a developer comprising a substantially non-diffusing polymeric compound having as a component part of its structure a plurality of units having a nucleus of general formula (I): ##STR1## wherein; each Z independently is a member selected from the group consisting of --OH and a group which leaves an --OH residue when contacted with an alkali (pH .gtoreq.10) at temperatures of .ltoreq.50.degree. C.
摘要:
A silver halide photographic light sensitive emulsion containing a hydrazine of the general formulaR.sup.3 -NR.sup.4 -NR.sup.5 -G-X (I)in whichR.sup.3 represents an aryl group,one of R.sup.4 and R.sup.5 is a hydrogen and the other is selected from hydrogen, aryl sulphonyl and trifluoroacetyl,G represents carbonyl, sulphonyl, sulphoxy, phosphoryl or an N-substituted or unsubstituted imino group and X is a moiety such that at a pH in the range of 9.5 to 12.5 in the presence of an oxidized hydroquinone a cyclization reaction takes place cleaving the moiety -G-X from the remainder of the molecule and forming a cyclic structure comprising atoms of the moiety -G-X.