公开(公告)号：US4826998A

公开(公告)日：1989-05-02

申请号：US772836

申请日：1985-09-05

申请人： Rudolf Veitenhansl ,  Wolfgang Froeschke ,  Robert Piorr

发明人： Rudolf Veitenhansl ,  Wolfgang Froeschke ,  Robert Piorr

IPC分类号： C08K5/42 ,  C09K3/16 ,  D06M13/256 ,  C07D327/02 ,  C07D327/04 ,  C07D327/06

CPC分类号： C09K3/16 ,  C08K5/42 ,  D06M13/256 ,  Y10T428/2969

摘要： Salts of sulfonic acids of the type formed in the sulfonation of alkenyl alkyl polyglycol ethers corresponding to the following formulaR--O (--C.sub.n H.sub.2n O).sub.x --R.sup.1with sulfur trioxide, followed by hydrolysis, are used as antistatic agents for plastics. R is a straight chain C.sub.10 -C.sub.22 alkenyl group, R.sub.1 is a C.sub.1 -C.sub.12 alkyl group, n is an integer of from 2 or 4, and x is an integer of from 0 to 35. The products show a particularly long-lasting effect as external antistatic agents on polyamide fibers.

摘要翻译： 对应于下式R-O（-CnH2nO）x-R1与三氧化硫进行磺化的链烯基烷基聚乙二醇醚形成的磺酸类盐酸盐，随后水解，被用作塑料的抗静电剂。 R是直链C 10 -C 22烯基，R 1是C 1 -C 12烷基，n是2或4的整数，x是0至35的整数。产物表现出特别长效 作为聚酰胺纤维上的外部抗静电剂。

公开(公告)号：US4929504A

公开(公告)日：1990-05-29

申请号：US306377

申请日：1989-02-03

申请人： Rudolf Veitenhansl ,  Wolfgang Froeschke ,  Robert Piorr

发明人： Rudolf Veitenhansl ,  Wolfgang Froeschke ,  Robert Piorr

IPC分类号： C08K5/42 ,  C09K3/16 ,  D06M13/256

CPC分类号： C09K3/16 ,  C08K5/42 ,  D06M13/256 ,  Y10T428/2969

摘要： Salts of sulfonic acids of the type formed in the sulfonation of alkenyl alkyl polyglycol ethers corresponding to the following formulaR--O(--C.sub.n H.sub.2n O).sub.x --R.sup.1with sulfur trioxide, followed by hydrolysis, are used as antistatic agents for plastics. R is a straight chain C.sub.10 -C.sub.22 alkenyl group, R.sup.1 is a C.sub.1 -C.sub.12 alkyl group, n is an integer of from 2 or 4, and x is an integer of from 0 to 35. The products show a particularly long-lasting effect as external antistatic agents on polyamide fibers.

公开(公告)号：US4981617A

公开(公告)日：1991-01-01

申请号：US240772

申请日：1988-09-02

申请人： Bernd Fabry ,  Robert Piorr ,  Frank Clasen ,  Horst Ritterbex ,  Hans Bornmann

发明人： Bernd Fabry ,  Robert Piorr ,  Frank Clasen ,  Horst Ritterbex ,  Hans Bornmann

IPC分类号： C07C303/00 ,  C07C305/02 ,  C07C305/04 ,  C07C305/10 ,  C07C309/00 ,  C07C311/00 ,  C11D1/28

CPC分类号： C07C303/24

摘要： The sulfonation of epoxidized ricinoleic acid glycerides with a dry stream of gaseous sulfur trioxide diluted with a carrier gas, followed by a reaction of the sulfonated reaction product with nucleophiles, leads to salt-free and anhydrous products showing surface-active properties.

摘要翻译： 用载气稀释的气态三氧化硫干燥流体，随后将磺化反应产物与亲核试剂反应的环氧化蓖麻油酸甘油酯的磺化产生显示表面活性的无盐和无水产品。

公开(公告)号：US4865774A

公开(公告)日：1989-09-12

申请号：US226596

申请日：1988-07-29

申请人： Bernd Fabry ,  Robert Piorr ,  Astrid Schumacher

发明人： Bernd Fabry ,  Robert Piorr ,  Astrid Schumacher

IPC分类号： B01F17/42 ,  B01F17/02 ,  C07C67/00 ,  C07C301/00 ,  C07C303/02 ,  C07C303/06 ,  C07C303/32 ,  C07C309/08 ,  C07C309/09 ,  C07C309/10 ,  C11D1/16 ,  C11D1/29

CPC分类号： C07C309/00 ,  C11D1/16 ,  Y10S516/03

摘要： Aqueous solutions of surface-active hydroxysulfonates are obtained by reaction of unsaturated fatty alkenyl or fatty alkenyl polyalkoxyl esters, for example of oleyl acetate or oleyl polyethoxyl acetate, with sulfur trioxide, introduction of the reaction product into aqueous alkali metal, alkaline-earth or ammonium hydroxide and heating of the solutions until the ester and sultone groups present have been hydrolyzed.

摘要翻译： 表面活性羟基磺酸盐的水溶液是通过使不饱和脂肪链烯基或脂肪链烯基多烷基酯例如乙酸油酯或油基聚乙氧基乙酸酯与三氧化硫反应而获得的，将反应产物引入碱金属，碱土金属或铵盐水溶液 氢氧化物和加热溶液直到存在的酯和磺内酯基团已被水解。

公开(公告)号：US4695409A

公开(公告)日：1987-09-22

申请号：US753304

申请日：1985-07-10

申请人： Robert Piorr ,  Guenter Panthel ,  Karl H. Schmid ,  Dietmar Colignon ,  Hans J. Rommerskirchen ,  Wolfgang Schmidt ,  Horst Ritterbex

发明人： Robert Piorr ,  Guenter Panthel ,  Karl H. Schmid ,  Dietmar Colignon ,  Hans J. Rommerskirchen ,  Wolfgang Schmidt ,  Horst Ritterbex

IPC分类号： C07C309/17 ,  C07B45/02 ,  C07C67/00 ,  C07C301/00 ,  C07C303/06 ,  C07C303/32 ,  C07C303/42 ,  C07C303/44 ,  C07C309/01 ,  C07C309/22 ,  C07C309/62 ,  C11D1/28 ,  C07C143/90

CPC分类号： C07C303/42

摘要： In light colored surfactants produced by sulfonation of fatty acid alkyl esters with less than 2 moles of SO.sub.3 per mole of fatty acid alkyl ester and subsequent work-up of the crude sulfonate in aqueous medium to form salts, the content of .alpha.-sulfofatty acid disalts is regulated and reduced by transesterifying the sulfonation product before its treatment with an aqueous medium with at least about 0.5 mole equivalent of an alcohol, based on the SO.sub.3 which is not for .alpha.-sulfonation.

摘要翻译： 在通过用每摩尔脂肪酸烷基酯少于2摩尔SO 3的脂肪酸烷基酯磺化生成的浅色表面活性剂中，随后在水性介质中处理粗磺酸盐以形成盐，α-磺基脂肪酸的含量为 通过基于不用于α-磺化的SO 3的具有至少约0.5摩尔当量的醇的水性介质在其处理之前将磺化产物进行酯交换来调节和还原。

公开(公告)号：US4898621A

公开(公告)日：1990-02-06

申请号：US220142

申请日：1988-07-15

申请人： Horst Pruehs ,  Gilbert Schenker ,  Theodor Altenschoepfer ,  Robert Piorr

发明人： Horst Pruehs ,  Gilbert Schenker ,  Theodor Altenschoepfer ,  Robert Piorr

IPC分类号： C11D1/72 ,  C11D17/00

CPC分类号： C11D1/721 ,  Y10S516/01

摘要： The invention relates to the use of hydroxyalkyl polyethylene glycol ethers corresponding to the following general formula ##STR1## in which R.sup.1 is hydrogen or a linear C.sub.1 -C.sub.16 alkyl radical,R.sup.2 is a linear or branched C.sub.4 -C.sub.8 alkyl radical,R.sup.3 is hydrogen or a C.sub.1 -C.sub.16 alkyl radical andn is a number of 7 to 30with the proviso that the total number of carbon atoms in R.sup.1 and R.sup.3 is 6 to 16, and mixtures thereof in rinse aid compositions for dishwashing machines in addition to other additives typically used in rinse aids.

摘要翻译： 本发明涉及对应于以下通式（I）的羟烷基聚乙二醇醚，其中R 1是氢或直链C 1 -C 16烷基，R 2是直链或支链C 4 -C 8烷基，R 3 是氢或C 1 -C 16烷基，n是7至30的数，条件是R 1和R 3中的碳原子总数为6至16，并且其混合物在洗碗机的漂洗助剂组合物中除了 通常用于冲洗助剂的其他添加剂。

公开(公告)号：US4820451A

公开(公告)日：1989-04-11

申请号：US925442

申请日：1986-10-31

申请人： Robert Piorr ,  Hans-Josef Rommerskirchen ,  Horst Ritterbex ,  Frantisek Jost

发明人： Robert Piorr ,  Hans-Josef Rommerskirchen ,  Horst Ritterbex ,  Frantisek Jost

IPC分类号： C11D1/20 ,  B01F20060101 ,  B01F17/08 ,  C07C20060101 ,  C07C67/00 ,  C07C301/00 ,  C07C303/06 ,  C07C303/24 ,  C07C303/32 ,  C07C309/03 ,  C07C309/17 ,  C07C309/22 ,  C07C309/62 ,  C11D20060101 ,  C11D1/28 ,  C11D17/00

CPC分类号： C07C303/42

摘要： In the production of washing-active .alpha.-sulfofatty acid esters by sulfonation of fatty acid alkyl esters with SO.sub.3 in molar ratios of up to 1:2 and more especially of from 1:1.2 to 1:1.8 and subsequent working-up of the crude sulfonic acid in aqueous medium with salt formation, aqueous pastes which are mobile, more especially pumpable, at moderately elevated temperatures are obtained by subjecting the crude sulfonate before the treatment with the aqueous medium to a post-reaction with at least about 0.5 mole equivalent, based on the SO.sub.3 which is not used for the .alpha.-sulfonation, of monohydric alcohols and/or alkoxylation products thereof at temperatures above 70.degree. C. and adjusting the solids contents of the .alpha.-sulfofatty acid ester salts to more than 35% by weight in the subsequent aqueous working-up step.

摘要翻译： 在通过脂肪酸烷基酯与SO 3的摩尔比高达1：2，更特别是1：1.2至1：1.8的磺化磺化生产洗涤 - 活性α-磺基脂肪酸酯后，随后加工粗制 在具有盐形成的水性介质中的磺酸，在适度升高的温度下是可移动的，更特别是可泵送的水性糊料通过在处理之前用水性介质经受粗磺酸盐进行至少约0.5摩尔当量的后反应， 基于不用于α-磺化的SO 3，在高于70℃的温度下将一元醇和/或其烷氧基化产物调节至大于35重量％的α-磺基脂肪酸酯盐的固体含量 在随后的水处理步骤中。

公开(公告)号：US4792582A

公开(公告)日：1988-12-20

申请号：US895077

申请日：1986-08-11

申请人： Rainer Hoefer ,  Alfred Meffert ,  Robert Piorr ,  Bernd Wegemund ,  Uwe Held

发明人： Rainer Hoefer ,  Alfred Meffert ,  Robert Piorr ,  Bernd Wegemund ,  Uwe Held

IPC分类号： B01D19/04 ,  B01F17/42 ,  C08F2/30 ,  C08K5/06

CPC分类号： B01D19/04 ,  B01D19/0404

摘要： A method for emulsifying, emulsion-stabilizing, and/or foam-inhibiting an aqueous polymer dispersion or latex by incorporating therein a polyglycol ether; and a polymer dispersion or latex composition containing such polyglycol ether.

摘要翻译： 通过在其中引入聚二醇醚来乳化，乳化稳定和/或泡沫抑制聚合物水分散体或胶乳的方法; 和含有这种聚乙二醇醚的聚合物分散体或胶乳组合物。

公开(公告)号：US4792419A

公开(公告)日：1988-12-20

申请号：US644482

申请日：1984-08-24

申请人： Robert Piorr ,  Alfred Meffert

发明人： Robert Piorr ,  Alfred Meffert

IPC分类号： B01F17/42 ,  B01F17/00 ,  C07C67/00 ,  C07C301/00 ,  C07C303/06 ,  C07C303/32 ,  C07C309/09 ,  C07C309/20 ,  C11D1/28 ,  C11D1/29 ,  C07C143/02

CPC分类号： C07C309/00

摘要： Ether sulfonates are produced by reacting a C.sub.10 -C.sub.20 fatty alkyl C.sub.1 -C.sub.6 lower alkyl ether or a fatty alkyl (polyoxyalkyl) lower alkyl ether corresponding to the following formulaR--O--(C.sub.n H.sub.2n O).sub.x --R.sup.1 (I) psin which R is an oleyl, palmitoleyl, or linoleyl radical, or mixtures thereof, n is an integer of from 2 to 4, x is an integer of from 0 to 30, and R.sup.1 is a saturated C.sub.1 -C.sub.6 lower alkyl radical, with sulfur trioxide, contacting the sulfonate with aqueous alkali metal hydroxide solution and heating the solution until the sultones formed have been hydrolyzed.

摘要翻译： 醚磺酸盐是通过使C 10 -C 20脂肪烷基C 1 -C 6低级烷基醚或与下列通式对应的脂肪烷基（聚氧烷基）低级烷基醚反应制备的：其中R为 油基，棕榈油基或亚油酰基，或其混合物，n为2至4的整数，x为0至30的整数，R 1为饱和的C 1 -C 6低级烷基，与三氧化硫接触， 磺酸盐与碱金属氢氧化物水溶液混合，并加热溶液直到形成的磺内酯已经水解。

公开(公告)号：US4935159A

公开(公告)日：1990-06-19

申请号：US264421

申请日：1988-10-31

申请人： Gilbert Schenker ,  Andreas Syldatk ,  Robert Piorr

发明人： Gilbert Schenker ,  Andreas Syldatk ,  Robert Piorr

IPC分类号： B01F17/42 ,  B01F17/46 ,  C11D3/30 ,  D06M13/02 ,  D06M13/322 ,  D06M13/342 ,  D06M13/345 ,  D06M13/368 ,  D06M13/372 ,  D06M13/447

CPC分类号： D06M13/368

摘要： Long-chain hydroxyalkyl ether amines corresponding to the general formulaR.sup.1 --CHOH--CH.sub.2 --(O--CH.sub.2 --CH.sub.2 --).sub.X NR.sup.2 R.sup.3are suitable as wetting agents for textile products of all kinds and are distinguished by particularly low-foaming behavior. In the formula, R.sup.1 is a linear C.sub.6 -C.sub.22 alkyl group, R.sup.2 and R.sup.3 independently of one another represent a linear or branched C.sub.1 -C.sub.6 alkyl radical, and x is a number of 3 to 20.

摘要翻译： 对应于通式为R1-CHOH-CH2-（O-CH2-CH2-）XNR2R3的长链羟基烷基醚胺适用于各种纺织品的润湿剂，并且特别是低发泡性能。 在该式中，R 1为直链C 6 -C 22烷基，R 2和R 3彼此独立地表示直链或支链C 1 -C 6烷基，x为3至20的数。