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公开(公告)号：US06649558B2
公开(公告)日：2003-11-18
申请号：US09753387
申请日：2001-01-03
申请人： Stephen John Brown , Xiaoliang Gao , Daryll G. Harrison , Ian McKay , Linda Koch , Qinyan Wang , Wei Xu , Rupert Edward von Haken Spence , Douglas W. Stephan
发明人： Stephen John Brown , Xiaoliang Gao , Daryll G. Harrison , Ian McKay , Linda Koch , Qinyan Wang , Wei Xu , Rupert Edward von Haken Spence , Douglas W. Stephan
IPC分类号： B01J3100
CPC分类号： C08F10/00 , C07F7/00 , C07F7/003 , C07F7/28 , C07F9/5355 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F110/02 , Y10S526/901 , C08F4/659 , C08F4/64 , C08F2500/12 , C08F2500/03
摘要： Organometallic complexes having two phosphinimine ligands and at least one activatable ligand are catalyst components for olefin polymerization. Preferred polymerization systems are prepared by combining the organometallic complexes with an ionic activator and/or an alumoxane. Preferred catalyst components contain titanium, zirconium, or hafnium and are activated with an ionic activator to form catalysts for ethylene polymerization.
摘要翻译： 具有两个膦亚胺配体和至少一个可活化配体的有机金属络合物是用于烯烃聚合的催化剂组分。 通过将有机金属络合物与离子活化剂和/或铝氧烷组合来制备优选的聚合体系。 优选的催化剂组分含有钛，锆或铪，并用离子活化剂活化以形成用于乙烯聚合的催化剂。
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公开(公告)号：US06239238B1
公开(公告)日：2001-05-29
申请号：US09333750
申请日：1999-06-15
申请人： Stephen John Brown , Xiaoliang Gao , Daryll G. Harrison , Ian McKay , Linda Koch , Qinyan Wang , Wei Xu , Rupert Edward von Haken Spence , Douglas W. Stephan
发明人： Stephen John Brown , Xiaoliang Gao , Daryll G. Harrison , Ian McKay , Linda Koch , Qinyan Wang , Wei Xu , Rupert Edward von Haken Spence , Douglas W. Stephan
IPC分类号： C08F442
CPC分类号： C08F10/00 , C07F7/00 , C07F7/003 , C07F7/28 , C07F9/5355 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F110/02 , Y10S526/901 , C08F4/659 , C08F4/64 , C08F2500/12 , C08F2500/03
摘要： Organometallic complexes having two phosphinimine ligands and at least one activatable ligand are catalyst components for olefin polymerization. Preferred polymerization systems are prepared by combining the organometallic complexes with an ionic activator and/or an alumoxane. Preferred catalyst components contain titanium, zirconium, or hafnium and are activated with an ionic activator to form catalysts for ethylene polymerization.
摘要翻译： 具有两个膦亚胺配体和至少一个可活化配体的有机金属络合物是用于烯烃聚合的催化剂组分。 通过将有机金属络合物与离子活化剂和/或铝氧烷组合来制备优选的聚合体系。 优选的催化剂组分含有钛，锆或铪，并用离子活化剂活化以形成用于乙烯聚合的催化剂。
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3.发明授权Olefin polymerization using a catalyst having a bridged cyclopentadienyl-phosphole ligand 失效使用具有桥连环戊二烯基磷光体配体的催化剂进行烯烃聚合
公开(公告)号：US6051667A
公开(公告)日：2000-04-18
申请号：US65594
申请日：1998-04-24
申请人： Rupert Edward von Haken Spence , Xiaoliang Gao , Linda Koch , Stephen John Brown , Daryll G. Harrison , Qinyan Wang
发明人： Rupert Edward von Haken Spence , Xiaoliang Gao , Linda Koch , Stephen John Brown , Daryll G. Harrison , Qinyan Wang
CPC分类号： C08F10/02 , C07F17/00 , C07F9/65683 , C08F110/02 , C08F210/16 , C08F4/65908 , C08F4/65912 , C08F4/65916 , Y10S526/943
摘要： An olefin polymerization process uses a catalyst with an organometallic complex of a group 4 metal having a bridged cyclopentadienyl-phosphole ligand, as defined by the formula: ##STR1## wherein: each Sl is a non-interfering spectator ligand;Y is selected from Si, Ge and Sn;Z is 2;R.sub.1, R.sub.2, and R.sub.3 are hydrogen or non-interfering substituents;Cp* is selected from cyclopentadienyl, substituted cyclopentadienyl, indenyl, substituted indenyl, fluorenyl and substituted fluorenyl;M4 is selected from Ti, Zr and Hf;X is an anionic ligand; andn is 1 or 2, depending upon the oxidation state of M4.A catalyst having a fluorenyl ligand and a dimethyl silyl bridge is preferred. This invention may be used to prepare polyethylenes having a broad molecular weight distribution.
摘要翻译： 烯烃聚合方法使用具有如下式所定义的具有桥连环戊二烯基磷光体配体的第4族金属的有机金属络合物的催化剂：其中：每个S 1是非干扰观察配体; Y选自Si，Ge，Sn; Z为2; R1，R2和R3是氢或非干扰取代基; Cp *选自环戊二烯基，取代的环戊二烯基，茚基，取代的茚基，芴基和取代的芴基; M4选自Ti，Zr和Hf; X是阴离子配体; 取决于M4的氧化态，n为1或2。 具有芴基配体和二甲基甲硅烷基桥的催化剂是优选的。 本发明可用于制备具有宽分子量分布的聚乙烯。
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4.发明授权
公开(公告)号：US6124487A
公开(公告)日：2000-09-26
申请号：US36241
申请日：1998-03-06
申请人： Rupert Edward von Haken Spence , Xiaoliang Gao , Linda Koch , Stephen John Brown , Daryll G. Harrison
发明人： Rupert Edward von Haken Spence , Xiaoliang Gao , Linda Koch , Stephen John Brown , Daryll G. Harrison
IPC分类号： C07F9/6568 , C07F9/70 , C07F9/90 , C07F9/94 , C07F17/00 , C08F4/659 , C08F10/02 , C08F110/02 , C08F210/16 , C07F15/00 , C07F9/02
CPC分类号： C08F10/02 , C07F17/00 , C07F9/6568 , C07F9/706 , C07F9/906 , C07F9/94 , C08F110/02 , C08F210/16 , C08F4/65908 , C08F4/65912 , C08F4/65916 , Y10S106/901
摘要： A new family of metallacycles, which are preferably zirconacycles, is characterized by having a unique halogenated substituent. The metallacycles are useful for the preparation of main group heterocycles, especially two novel families of heterocycles. The first new family of heterocycles preferably contains a halosilyl substituent. A preferred group of the second family of novel heterocycles contains a silyl group having a leaving group bonded thereto. The preferred group of these heterocycles is suitable for preparing novel organometallic complexes having a bridged bidentate heterocyclic ligand. These novel organometallic complexes may be used as catalyst components in olefin polymerization. The subject catalyst components are particularly well suited for use in the medium pressure solution process to prepare linear low density polyethylene.
摘要翻译： 一个新的金属系列，优选是锆石环，其特征在于具有独特的卤代取代基。 金属螯合物可用于制备主要杂环，特别是两个新的杂环族。 第一个新的杂环族优选含有卤代甲硅烷基取代基。 第二族新杂环的优选基团含有具有与其结合的离去基团的甲硅烷基。 这些杂环的优选基团适用于制备具有桥连二齿杂环配体的新的有机金属络合物。 这些新型有机金属络合物可用作烯烃聚合中的催化剂组分。 本发明的催化剂组分特别适用于中压溶液法制备线性低密度聚乙烯。
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公开(公告)号：US5661098A
公开(公告)日：1997-08-26
申请号：US584815
申请日：1996-01-11
IPC分类号： C08F4/42 , C08F4/64 , C08F4/659 , C08F4/6592 , C08F10/00
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65916 , C08F4/6592 , Y10S526/901 , Y10S526/943
摘要： A catalyst prepared by firstly depositing a large amount of aluminoxane on a particulate support, then depositing a small amount of monocyclopentadienyl zirconium trihalide on the support. The catalyst is active for the polymerization of ethylene, optionally with a minor amount of other alpha olefins such as butene or hexene, particularly in a gas phase process.
摘要翻译： 一种催化剂，首先将大量的铝氧烷沉积在颗粒载体上，然后在载体上沉积少量的单环戊二烯基三卤化锆。 催化剂对于乙烯的聚合是有活性的，任选地含有少量的其它α-烯烃如丁烯或己烯，特别是在气相方法中。
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公开(公告)号：US5965677A
公开(公告)日：1999-10-12
申请号：US959589
申请日：1997-10-29
IPC分类号： C08F4/642 , C08F4/02 , C08F4/44 , C08F4/64 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/00 , C08F210/16 , B01J31/00
CPC分类号： C08F10/00 , C08F210/16 , C08F4/65908 , C08F4/65912 , C08F4/65916 , Y10S526/901 , Y10S526/943
摘要： A catalyst component which is especially useful in so-called "slurry" or "gas phase" olefin polymerizations and which comprises an organometallic complex of a group 4 metal (having a cyclopentadienyl-type ligand and a phosphinimine ligand) and a particulate support. The catalyst component forms an excellent catalyst system when combined with an activator such as an aluminoxane or a so-called "substantially non-coordinating anion". In a preferred embodiment the organometallic complex and the activator are both deposited on the particulate support.
摘要翻译： 一种催化剂组分，其特别可用于所谓的“淤浆”或“气相”烯烃聚合反应，并且其包含第4族金属（具有环戊二烯基型配体和膦亚胺配体）的有机金属络合物和颗粒载体。 当与活化剂如铝氧烷或所谓的“基本上非配位阴离子”组合时，催化剂组分形成优异的催化剂体系。 在优选的实施方案中，有机金属络合物和活化剂都沉积在颗粒载体上。
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