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公开(公告)号：US06066701A
公开(公告)日：2000-05-23
申请号：US959759
申请日：1997-10-29
CPC分类号： B01J19/245 , C08F10/00 , B01J2219/00114 , B01J2219/0013 , B01J2219/00162 , B01J2219/00182
摘要： The present invention provides a method for substantially continuously polymerizing olefins comprising: introducing into a first reaction zone a fresh olefin polymerization catalyst; contacting said fresh olefin polymerization catalyst in said first reaction zone with a first vent mixture at a first feed rate and under conditions sufficient to form and avoid melting a polyolefin, wherein first vent mixture comprises unreacted olefins and a diluent vented from a second reaction zone; withdrawing a vent product of unreacted olefins and diluent from said first reaction zone; withdrawing from said first reaction zone a first product mixture comprising said catalyst and said polyolefin; passing said first product mixture to said second reaction zone; contacting said first product mixture in said second reaction zone with a second vent mixture at a second feed rate and under conditions sufficient to form and avoid melting said polyolefin, wherein said second vent mixture comprises a material selected from the group consisting of a fresh feed and a mixture comprising unreacted olefins and diluent from a third reaction zone; and, withdrawing from said second reaction zone a second product mixture comprising said catalyst and said polyolefin.
摘要翻译： 本发明提供了一种基本上连续聚合烯烃的方法，包括：将新鲜的烯烃聚合催化剂引入第一反应区; 在第一进料速率和足以形成和避免熔化聚烯烃的条件下使所述第一反应区中的所述新鲜烯烃聚合催化剂与第一排气混合物接触，其中第一排气混合物包含未反应的烯烃和从第二反应区排出的稀释剂; 从所述第一反应区抽出未反应的烯烃和稀释剂的排放产物; 从所述第一反应区抽出含有所述催化剂和所述聚烯烃的第一产物混合物; 将所述第一产物混合物通入所述第二反应区; 使所述第二反应区中的所述第一产物混合物与第二排气混合物以第二进料速率和足以形成和避免熔化所述聚烯烃的条件接触，其中所述第二排气混合物包含选自新鲜进料和 包含来自第三反应区的未反应烯烃和稀释剂的混合物; 并且从所述第二反应区抽出包含所述催化剂和所述聚烯烃的第二产物混合物。
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公开(公告)号：US06326442B1
公开(公告)日：2001-12-04
申请号：US09570946
申请日：2000-05-15
IPC分类号： C08F201
CPC分类号： B01J19/245 , B01J2219/00114 , B01J2219/0013 , B01J2219/00162 , B01J2219/00182 , C08F10/00 , C08F2/001
摘要： The present invention provides a method for substantially continuously polymerizing olefins comprising: introducing into a first reaction zone a fresh olefin polymerization catalyst; contacting said fresh olefin polymerization catalyst in said first reaction zone with a first vent mixture at a first feed rate and under conditions sufficient to form and avoid melting a polyolefin, wherein first vent mixture comprises unreacted olefins and a diluent vented from a second reaction zone; withdrawing a vent product of unreacted olefins and diluent from said first reaction zone; withdrawing from said first reaction zone a first product mixture comprising said catalyst and said polyolefin; passing said first product mixture to said second reaction zone; contacting said first product mixture in said second reaction zone with a second vent mixture at a second feed rate and under conditions sufficient to form and avoid melting said polyolefin, wherein said second vent mixture comprises a material selected from the group consisting of a fresh feed and a mixture comprising unreacted olefins and diluent from a third reaction zone; and, withdrawing from said second reaction zone a second product mixture comprising said catalyst and said polyolefin.
摘要翻译： 本发明提供了一种基本上连续聚合烯烃的方法，包括：将新鲜的烯烃聚合催化剂引入第一反应区; 在第一进料速率和足以形成和避免熔化聚烯烃的条件下使所述第一反应区中的所述新鲜烯烃聚合催化剂与第一排气混合物接触，其中第一排气混合物包含未反应的烯烃和从第二反应区排出的稀释剂; 从所述第一反应区抽出未反应的烯烃和稀释剂的排放产物; 从所述第一反应区抽出含有所述催化剂和所述聚烯烃的第一产物混合物; 将所述第一产物混合物通入所述第二反应区; 使所述第二反应区中的所述第一产物混合物与第二排气混合物以第二进料速率和足以形成和避免熔化所述聚烯烃的条件接触，其中所述第二排气混合物包含选自新鲜进料和 包含来自第三反应区的未反应烯烃和稀释剂的混合物; 并且从所述第二反应区抽出包含所述催化剂和所述聚烯烃的第二产物混合物。
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公开(公告)号：US6114479A
公开(公告)日：2000-09-05
申请号：US691848
申请日：1996-07-30
CPC分类号： C08F10/00 , C08F2410/02 , C08F4/61912 , C08F4/61916 , C08F4/61927 , Y10S526/943
摘要： This invention is generally directed toward a supported catalyst system useful for polymerizing olefins. The method for supporting the catalyst of the invention provides for a supported bulky ligand transition metal catalyst which when utilized in a polymerication process substantially reduces the reactor fouling and sheeting in a gas, slurry or liquid pool polymerization process.
摘要翻译： 本发明通常涉及用于聚合烯烃的负载型催化剂体系。 支持本发明的催化剂的方法提供了一种负载的大体积配体过渡金属催化剂，其在聚合过程中使用时，基本上减少了反应器在气体，浆液或液池聚合过程中的结垢和压片。
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公开(公告)号：US6124230A
公开(公告)日：2000-09-26
申请号：US502231
申请日：1995-07-13
CPC分类号： C08F10/00 , C08F2410/02 , C08F4/61912 , C08F4/61916 , C08F4/61927 , Y10S526/943
摘要： This invention is generally directed toward a supported catalyst system useful for polymerizing olefins. The method for supporting the catalyst of the invention provides for a supported bulky ligand transition metal catalyst which when utilized in a polymerization process substantially reduces the reactor fouling and sheeting in a gas, slurry or liquid pool polymerization process.
摘要翻译： 本发明通常涉及用于聚合烯烃的负载型催化剂体系。 用于支撑本发明的催化剂的方法提供了支撑的大体积配体过渡金属催化剂，当其用于聚合方法时，基本上减少了反应器在气体，浆液或液池聚合方法中的结垢和压片。
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5.发明授权Method for making supported catalyst systems and catalyst systems therefrom 失效从其制备负载型催化剂体系和催化剂体系的方法
公开(公告)号：US5721184A
公开(公告)日：1998-02-24
申请号：US708136
申请日：1996-08-27
IPC分类号： C08F4/02 , C08F4/42 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/14 , C08F210/16
CPC分类号： C08F10/00 , C08F210/14 , C08F210/16 , C08F4/65912 , C08F4/65927 , Y10S526/943
摘要： Catalyst systems and methods for supporting catalysts and their components, particularly metallocene catalyst components, are provided. The method involves techniques for evenly distributing a small volume of catalyst component over and among a porous support material. Such even distribution is thought to result in reduced fouling.
摘要翻译： 提供用于支持催化剂及其组分，特别是金属茂催化剂组分的催化剂体系和方法。 该方法涉及在多孔载体材料之上和之间均匀分布少量催化剂组分的技术。 这种均匀分布被认为会导致结垢减少。
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6.发明授权Method for making supported catalyst systems and catalyst systems therefrom 失效从其制备负载型催化剂体系和催化剂体系的方法
公开(公告)号：US5665665A
公开(公告)日：1997-09-09
申请号：US559928
申请日：1995-11-17
IPC分类号： C08F4/02 , C08F4/42 , C08F4/60 , C08F4/619 , C08F4/6192 , C08F4/642 , C08F10/00 , C08F210/14 , C08F210/16 , B01J19/06
CPC分类号： C08F10/00 , C08F210/14 , C08F210/16 , C08F4/61912 , C08F4/61916 , C08F4/61922 , Y10S502/503 , Y10S526/943
摘要： Catalyst systems and methods for supporting catalysts and their components, particularly metallocene catalyst components, are provided. The method involves teqhniques for evenly distributing a small volume of catalyst component over and among a porous support material. Such even distribution is thought to result in reduced fouling.
摘要翻译： 提供用于支持催化剂及其组分，特别是金属茂催化剂组分的催化剂体系和方法。 该方法涉及在多孔载体材料之上和之间均匀分布少量催化剂组分的方法。 这种均匀分布被认为会导致结垢减少。
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7.发明授权Peroxide-cured thermoplastic vulcanizates prepared with ultrahigh molecular weight plastics 有权用超高分子量塑料制备的过氧化物固化的热塑性硫化胶公开(公告)号：US08846815B2
公开(公告)日：2014-09-30
申请号：US12163349
申请日：2008-06-27
CPC分类号： C08L23/16 , C08L23/10 , C08L91/00 , C08L2312/00 , C08L2666/06 , C08L2666/04
摘要： A thermoplastic vulcanizate comprising a dynamically cured rubber, where the rubber is peroxide cured, and a thermoplastic phase, where at least 10% by weight of the thermoplastic phase includes an ultrahigh molecular weight plastic, where the ultrahigh molecular weight plastic is characterized by a Mw that is greater than 0.8×106 g/mole.
摘要翻译： 包含动态硫化橡胶的热塑性硫化橡胶，其中橡胶是过氧化物固化的，以及热塑性相，其中至少10重量％的热塑性相包括超高分子量塑料，其中超高分子量塑料的特征在于Mw 大于0.8×10 6 g / mol。
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8.发明申请Peroxide-Cured Thermoplastic Vulcanizates Prepared With Ultrahigh Molecular Weight Plastics 有权用超高分子量塑料制备的过氧化物固化的热塑性硫化橡胶公开(公告)号：US20090043048A1
公开(公告)日：2009-02-12
申请号：US12163349
申请日：2008-06-27
IPC分类号： C08C19/00
CPC分类号： C08L23/16 , C08L23/10 , C08L91/00 , C08L2312/00 , C08L2666/06 , C08L2666/04
摘要： A thermoplastic vulcanizate comprising a dynamically cured rubber, where the rubber is peroxide cured, and a thermoplastic phase, where at least 10% by weight of the thermoplastic phase includes an ultrahigh molecular weight plastic, where the ultrahigh molecular weight plastic is characterized by a Mw that is greater than 0.8×106 g/mole.
摘要翻译： 包含动态硫化橡胶的热塑性硫化橡胶，其中橡胶是过氧化物固化的，以及热塑性相，其中至少10重量％的热塑性相包括超高分子量塑料，其中超高分子量塑料的特征在于Mw 大于0.8×10 6 g / mol。
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公开(公告)号：US6087291A
公开(公告)日：2000-07-11
申请号：US959965
申请日：1997-10-24
申请人： Anthony Nicholas Speca , Jeffrey Lawrence Brinen , George Alan Vaughan , Patrick Brant , Terry John Burkhardt
发明人： Anthony Nicholas Speca , Jeffrey Lawrence Brinen , George Alan Vaughan , Patrick Brant , Terry John Burkhardt
IPC分类号： B01J31/00 , B01J37/00 , C08F4/02 , C08F4/60 , C08F4/619 , C08F4/6192 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/06
CPC分类号： C08F10/00 , C08F110/06 , C08F4/61912 , C08F4/61916 , C08F4/61927 , C08F4/65912 , C08F4/65927 , Y10S526/943
摘要： This invention is generally directed toward a supported catalyst system useful for polymerizing olefins. The method for supporting the catalyst system of the invention provides for a metallocene catalyst and alumoxane activator supported on a porous support using a total volume of catalyst solution that is less than that of which a slurry is formed. The metallocene and alumoxane aer mixed in solution, then the solution is added to a porous support in a volume between the total pore volume of the support and the volume at which a slurry forms. The solvent is then removed, leaving an activated supported metallocene.
摘要翻译： 本发明通常涉及用于聚合烯烃的负载型催化剂体系。 用于支撑本发明的催化剂体系的方法提供了使用小于形成浆料的催化剂溶液的总体积的负载在多孔载体上的茂金属催化剂和铝氧烷激活剂。 将金属茂和铝氧烷混合在溶液中，然后将溶液以支撑体的总孔体积和浆料形成的体积之间的体积加入到多孔载体中。 然后除去溶剂，留下活化的负载金属茂。
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