Flame retardant polycarbonate compositions
    1.
    发明授权
    Flame retardant polycarbonate compositions 失效
    阻燃聚碳酸酯组合物

    公开(公告)号:US4753994A

    公开(公告)日:1988-06-28

    申请号:US936852

    申请日:1986-12-02

    CPC分类号: C08J3/005 C08L69/00

    摘要: The present invention is related to polycarbonate molding compositions containing a co-precipitate of a polycarbonate resin and a fluoropolymer. This co-precipitate was found to be suitable as an additive for polycarbonate resins because it offers improved dispersibility with the resin and good flammability performance as well as aesthetic characteristics. The co-precipitate is prepared by first mixing an aqueous dispersion of a fluoropolymer with a polycarbonate solution and then precipitating both using a suitable precipitation agent. After isolation washing and drying the co-precipitate of the invention is suitable for incorporation in a polycarbonate resin optionally with known flame retarding agents. Molded parts prepared from the compositions of the invention are characterized by their improved homogeneity and flame retardance.

    摘要翻译: 本发明涉及含有聚碳酸酯树脂和含氟聚合物的共沉淀物的聚碳酸酯模塑组合物。 发现这种共沉淀物适合作为聚碳酸酯树脂的添加剂,因为它提供了与树脂的改善的分散性和良好的可燃性以及美学特性。 通过首先将含氟聚合物的水性分散体与聚碳酸酯溶液混合,然后使用合适的沉淀剂沉淀二者来制备共沉淀物。 分离洗涤和干燥后,本发明的共沉淀物适合于任选地使用已知的阻燃剂掺入聚碳酸酯树脂中。 由本发明组合物制备的成型部件的特征在于其均匀性和阻燃性的改善。

    Polycarbonate foams
    5.
    发明授权
    Polycarbonate foams 失效
    聚碳酸酯

    公开(公告)号:US5132331A

    公开(公告)日:1992-07-21

    申请号:US815302

    申请日:1991-12-27

    CPC分类号: C08J9/125 C08J2369/00

    摘要: A foamable thermoplastic molding composition comprising:a) an aromatic polycarbonate, andb) 0.1 to 5% by weight of a hydrate of an inorganic salt, is disclosed. The salt is inert to the polycarbonate and is capable of releasing its water of hydration only at a temperature above 100.degree. C.The composition which may optionally further contain c) up to 10% by weight of a nucleating agent, and d) up to 30% by weight of glass fibers is characterized by its good pore structure.

    摘要翻译: 一种可发泡热塑性模塑组合物,其包含:a)芳族聚碳酸酯,和b)0.1至5重量%的无机盐水合物。 该盐对聚碳酸酯是惰性的,并且只能在高于100℃的温度下释放其水合水。可任选地进一步含有c)至多10重量%的成核剂的组合物,和d)直到 30%(重量)玻璃纤维的特征在于其孔结构良好。

    Polycarbonates of substituted cyclohexylindenebisphenols
    7.
    发明授权
    Polycarbonates of substituted cyclohexylindenebisphenols 失效
    取代环己二烯双酚的聚碳酸酯

    公开(公告)号:US5034458A

    公开(公告)日:1991-07-23

    申请号:US565290

    申请日:1990-08-09

    CPC分类号: C08G64/06 C08L69/00

    摘要: Aromatic polycarbonates having weight average molecular weight M.sub.w of at least 10,000 which contain bifunctional carbonate structural units corresponding to general formula (I): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4 independently represent hydrogen, C.sub.1 -C.sub.12 hdyrocarbon or halogen radicals; andR.sup.5, R.sup.6, R.sup.7, R.sup.8 and R.sup.9 independently represent hydrogen or C.sub.1 -C.sub.12 hydrocarbon radicals, one or R.sup.5 and R.sup.9 representing hydrogen and the other C.sub.1 -C.sub.12 hydrocarbon radical;in amounts of from 100 to 1 mole % based on the total amount of difunctional carbonate structural units in the polycarbonate were found to be useful for thermoplast processing of compositions which are characterized by their improved toughness and high heat deflection temperature.

    摘要翻译: 重均分子量> Mw至少为10,000的芳族聚碳酸酯含有对应于通式(I)的双官能碳酸酯结构单元:其中R 1,R 2,R 3,R 4独立地表示氢,C 1 -C 12羟基或 卤素自由基 R5,R6,R7,R8和R9独立地表示氢或C1-C12烃基,一个或R5和R9代表氢和另一个C1-C12烃基; 发现聚碳酸酯中双官能碳酸酯结构单元的总量为100至1摩尔%可用于组合物的热塑性加工,其特征在于其改进的韧性和高的热变形温度。

    Polycarbonate of polysubstituted cyclohexylidene bisphenols
    8.
    发明授权
    Polycarbonate of polysubstituted cyclohexylidene bisphenols 失效
    多取代亚环己基双酚的聚碳酸酯

    公开(公告)号:US5021542A

    公开(公告)日:1991-06-04

    申请号:US450655

    申请日:1989-12-13

    IPC分类号: C08G64/00 C08G64/06

    CPC分类号: C08G64/06

    摘要: Thermoplastic aromatic polycarbonates having average molecular weights Mw of at least 10,000 which contain bifunctional carbonate structural units corresponding formula (I) ##STR1## in which R.sup.1, R.sup.2, R.sup.3, R.sup.4 independently of one another represent hydrogen, a C.sub.1-12 hydrocarbon, halogen,Y.sup.1, Y.sup.2, Y.sup.3 independently of one another represent hydrogen,C.sub.1-5 alkyl, a C.sub.6-12 hydrocarbon radical,at least two of the substituents Y.sup.1, Y.sup.2 and Y.sup.3 not being hydrogen and at least one of the substituents Y.sup.1, Y.sup.2 and Y.sup.3 being C.sub.1-5 alkyl,in quantities of from 100 to 1 mol-%, based on the total quantity of difunctional carbonate structural units in the polycarbonate.

    摘要翻译: 平均分子量&upbar&Mw至少为10,000的热塑性芳族聚碳酸酯含有对应式(I)的双官能碳酸酯结构单元,其中R 1,R 2,R 3,R 4彼此独立地表示氢,C1-12 烃,卤素,Y 1,Y 2,Y 3彼此独立地表示氢,C 1-5烷基,C 6-12烃基,至少两个取代基Y1,Y2和Y3不为氢,并且至少一个取代基Y1 ,Y2和Y3为C1-5烷基,其量为100至1mol%,基于聚碳酸酯中双官能碳酸酯结构单元的总量。

    Polycarbonate of cycloalkylidene bisphenol
    9.
    发明授权
    Polycarbonate of cycloalkylidene bisphenol 失效
    环亚烷基双酚的聚碳酸酯

    公开(公告)号:US5010163A

    公开(公告)日:1991-04-23

    申请号:US450604

    申请日:1989-12-13

    IPC分类号: C08G64/00 C08G64/06

    CPC分类号: C08G64/06

    摘要: Thermoplastic aromatic polycarbonates having average molecular weight Mw of at least 10,000 which contain bifunctional carbonate structural units corresponding to formula (I) ##STR1## in which R.sup.1, R.sup.2, R.sup.3 and R.sup.4 independently of one another represent hydrogen, a C.sub.1 -C.sub.12 -hydrocarbon, halogen,m is 2 or 3 andX represents hydrogen or a C.sub.6 -C.sub.12 hydrocarbon, at least one substituent X being a C.sub.6 -C.sub.12 hydrocarbon radical,in quantities of from 100 to 1 mol-% based on the total quantity of difunctional carbonate structural units in the polycarbonate.

    摘要翻译: 具有至少10,000的平均分子量& Mw和Mw的热塑性芳族聚碳酸酯,其含有对应于式(I)的双官能碳酸酯结构单元,其中R 1,R 2,R 3和R 4彼此独立地表示氢,C1- C 12烃,卤素,m为2或3,X表示氢或C 6 -C 12烃,至少一个取代基X为C 6 -C 12烃基,其量为100至1摩尔%,基于总量 的聚碳酸酯中的双官能碳酸酯结构单元。