摘要:
The present invention is related to polycarbonate molding compositions containing a co-precipitate of a polycarbonate resin and a fluoropolymer. This co-precipitate was found to be suitable as an additive for polycarbonate resins because it offers improved dispersibility with the resin and good flammability performance as well as aesthetic characteristics. The co-precipitate is prepared by first mixing an aqueous dispersion of a fluoropolymer with a polycarbonate solution and then precipitating both using a suitable precipitation agent. After isolation washing and drying the co-precipitate of the invention is suitable for incorporation in a polycarbonate resin optionally with known flame retarding agents. Molded parts prepared from the compositions of the invention are characterized by their improved homogeneity and flame retardance.
摘要:
The present invention relates to the preparation of thermoplastic poly-(diorganosiloxane)/polycarbonate block copolymers containing monoalkylphenyl or dialkylphenyl end groups by the phase boundary process, and to the block copolymers which can be obtained by the process.
摘要:
Aromatic polyesters are prepared by the transesterification of aromatic dicarboxylic acid dialkyl esters with diester derivatives of divalent phenols at temperatures of about 260.degree. to 350.degree. C. with removal of the resulting monocarboxylic acid alkyl ester from the reaction mixture.
摘要:
A three-step process for the production of solventless polycarbonate is disclosed. Accordingly, a mixture of two different oligocarbonates each prepared by the interfacial method, is prepared in the first process step. In a second step, the mixture is crystallized. The third step entails polycondensation. In an additional embodiment of the invention the first step uses a mixture of one oligocarbonate with a suitable monomer.
摘要:
A foamable thermoplastic molding composition comprising:a) an aromatic polycarbonate, andb) 0.1 to 5% by weight of a hydrate of an inorganic salt, is disclosed. The salt is inert to the polycarbonate and is capable of releasing its water of hydration only at a temperature above 100.degree. C.The composition which may optionally further contain c) up to 10% by weight of a nucleating agent, and d) up to 30% by weight of glass fibers is characterized by its good pore structure.
摘要:
The invention relates to the use of the diphenol corresponding to formula (I) ##STR1## for the production of high molecular weight, thermoplastic, aromataic polycarbonates, to a process for the production of these polycarbonates and to the new thermoplastic having improved heat resistance obtainable by the process.
摘要:
Aromatic polycarbonates having weight average molecular weight M.sub.w of at least 10,000 which contain bifunctional carbonate structural units corresponding to general formula (I): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4 independently represent hydrogen, C.sub.1 -C.sub.12 hdyrocarbon or halogen radicals; andR.sup.5, R.sup.6, R.sup.7, R.sup.8 and R.sup.9 independently represent hydrogen or C.sub.1 -C.sub.12 hydrocarbon radicals, one or R.sup.5 and R.sup.9 representing hydrogen and the other C.sub.1 -C.sub.12 hydrocarbon radical;in amounts of from 100 to 1 mole % based on the total amount of difunctional carbonate structural units in the polycarbonate were found to be useful for thermoplast processing of compositions which are characterized by their improved toughness and high heat deflection temperature.
摘要:
Thermoplastic aromatic polycarbonates having average molecular weights Mw of at least 10,000 which contain bifunctional carbonate structural units corresponding formula (I) ##STR1## in which R.sup.1, R.sup.2, R.sup.3, R.sup.4 independently of one another represent hydrogen, a C.sub.1-12 hydrocarbon, halogen,Y.sup.1, Y.sup.2, Y.sup.3 independently of one another represent hydrogen,C.sub.1-5 alkyl, a C.sub.6-12 hydrocarbon radical,at least two of the substituents Y.sup.1, Y.sup.2 and Y.sup.3 not being hydrogen and at least one of the substituents Y.sup.1, Y.sup.2 and Y.sup.3 being C.sub.1-5 alkyl,in quantities of from 100 to 1 mol-%, based on the total quantity of difunctional carbonate structural units in the polycarbonate.
摘要:
Thermoplastic aromatic polycarbonates having average molecular weight Mw of at least 10,000 which contain bifunctional carbonate structural units corresponding to formula (I) ##STR1## in which R.sup.1, R.sup.2, R.sup.3 and R.sup.4 independently of one another represent hydrogen, a C.sub.1 -C.sub.12 -hydrocarbon, halogen,m is 2 or 3 andX represents hydrogen or a C.sub.6 -C.sub.12 hydrocarbon, at least one substituent X being a C.sub.6 -C.sub.12 hydrocarbon radical,in quantities of from 100 to 1 mol-% based on the total quantity of difunctional carbonate structural units in the polycarbonate.
摘要:
This invention relates to a process for the production of aromatic polycarbonates from cyclic aromatic carbonate oligomers in the presence of aprotic organic solvents at low temperatures.