公开(公告)号：US06719826B2

公开(公告)日：2004-04-13

申请号：US10194980

申请日：2002-07-15

申请人： Ryoichi Sasano ,  Motoaki Satoh ,  Yutaka Nakanishi

发明人： Ryoichi Sasano ,  Motoaki Satoh ,  Yutaka Nakanishi

IPC分类号： B01D1508

CPC分类号： G01N30/12 ,  G01N2030/025 ,  G01N2030/127

摘要： A method and an apparatus for sample injection in gas chromatography increases the injecting volume of a sample, and can analyze any of high-boiling-point compounds, low-compounds boiling-point compounds, and compounds decomposed by heat. A sample is injected into a vaporizing chamber 6 having curved or crooked outer wall 6G and sample path S and formed of continuous inner walls 6H; the sample is temporarily held in the vaporizing chamber 6; then an objective compound is vaporized, and introduced into a separation column 17.

摘要翻译： 气相色谱仪中样品注入的方法和装置增加了样品的注入体积，并且可以分析高沸点化合物，低沸点化合物和热分解化合物中的任何一种。 将样品注入具有弯曲或弯曲的外壁6G和样品路径S并由连续内壁6H形成的蒸发室6; 将样品暂时保持在蒸发室6中; 然后将目标化合物蒸发，并引入分离塔17中。

公开(公告)号：US20080209983A1

公开(公告)日：2008-09-04

申请号：US10581317

申请日：2004-12-03

申请人： Ryoichi Sasano ,  Yutaka Nakanishi

发明人： Ryoichi Sasano ,  Yutaka Nakanishi

IPC分类号： G01N1/28

CPC分类号： G01N30/462 ,  G01N2030/062 ,  G01N30/14

摘要： A combination of a liquid chromatograph and a gas chromatograph was a possible measure for improving precision in analyzing organic chemical substances. However, because elutes from liquid chromatoghaphies contain water and a highly polar solvent, injection thereof into a gas chromatograph has been impossible. Consequently, to develop an analytical method which realizes that combination and an apparatus thereof has been a subject. The method of the quantitative analysis comprises subjecting a sample for analysis prepared beforehand by extracting organic chemical substances from an assay sample to fractionation by a liquid chromatograph, continuously adsorbing a fractionated elute containing a substance to be determined onto a solid-phase cartridge while conducting the fractionation, eluting this substance, which has been adsorbed on the solid-phase cartridge, with an eluent, and transferring the elute to a storage chamber of a gas chromatograph.

摘要翻译： 液相色谱仪和气相色谱仪的组合是提高分析有机化学物质精度的可行措施。 然而，因为来自液体色谱法的洗脱液含有水和高极性溶剂，所以注入气相色谱仪是不可能的。 因此，开发一种实现该组合的分析方法及其装置已经成为一个主题。 定量分析方法包括：将样品预先分析，通过从测定样品中提取有机化学物质进行分析，通过液相色谱仪进行分级，将含有待测物质的分馏洗脱液连续吸附到固相盒上，同时进行 分离，用吸附在固相柱上的该物质洗脱，并将洗脱液转移到气相色谱仪的储存室中。

公开(公告)号：US20080179252A1

公开(公告)日：2008-07-31

申请号：US11661264

申请日：2005-06-14

申请人： Ryoichi Sasano ,  Kazuaki Kiji ,  Yutaka Nakanishi

发明人： Ryoichi Sasano ,  Kazuaki Kiji ,  Yutaka Nakanishi

IPC分类号： B01D15/08

CPC分类号： G01N30/24 ,  G01N35/1095 ,  G01N2030/085

摘要： This invention relates to an analytical method and an apparatus utilizing a SPE cartridge, which can realize enhanced accuracy and workability in the analysis of trace substances, such as residual pesticides, can clean the inside of piping, needle valves etc, can eliminate the influence on the analysis and can conduct these operations automatically. In the analytical method and apparatus utilizing a SPE cartridge, analytes previously adsorbed to a SPE cartridge is eluted with a solvent from a liquid feed pump. The eluate was injected into a storage chamber in a gas chromatograph through a needle inserted into an injection port in the storage chamber. The needle is pulled up from the injection port, and the inside of the needle is washed with a solvent fed from the liquid feed pump. The wash liquid is discarded, and the analysis of organic compounds as analytes in an subject sample is carried out.

摘要翻译： 本发明涉及一种利用SPE滤芯的分析方法和装置，其可以在残留农药等痕量物质的分析中实现更高的精度和可操作性，可以清洗管道内部，针阀等，可以消除对 分析并自动进行这些操作。 在使用SPE柱的分析方法和装置中，先前被吸附到SPE柱的分析物用来自液体进料泵的溶剂洗脱。 将洗脱液通过插入储存室中的注入口中的针注入气相色谱仪的储存室中。 针从注射口拉起，针头内部用从液体供给泵供给的溶剂洗涤。 将洗涤液弃去，对被检样品中的有机化合物作为分析物进行分析。

公开(公告)号：US20070240777A1

公开(公告)日：2007-10-18

申请号：US10594546

申请日：2005-03-24

申请人： Ryoichi Sasano ,  Kazuaki Kiji ,  Yutaka Nakanishi

发明人： Ryoichi Sasano ,  Kazuaki Kiji ,  Yutaka Nakanishi

IPC分类号： B05B1/22

CPC分类号： G01N30/603 ,  G01N30/6065 ,  Y10T137/9464

摘要： An inflow side frit (3), a stationary phase filler (4), and an outflow side frit (5) are installed in a cylindrical cartridge body (1A) from the upper side, a stopper part (1f) supporting the outflow side frit is formed at the inner surface bottom end of the cartridge body (1A), and a fitting part capable of holding the inserted state of the lower end of the other cartridge body (1A) inserted from the upper end of the cartridge body (1A) to a specified position is formed on the cartridge body (1A). The fitting part comprises an inside tapered surface (1g) formed on the inner surface of the cartridge body (1A) on the inserted side and having a diameter increased toward the upper side and an outside tapered surface formed on the outer surface of the cartridge body on the insert side and having a diameter increased toward the upper side.

摘要翻译： 流入侧玻璃料（3），固定相填料（4）和流出侧玻璃料（5）从上侧安装在圆筒形筒体（1A）中，支撑流出物的止动部分（1f） 在盒主体（1A）的内表面底端形成侧玻璃料，并且能够保持从盒的上端插入的另一个盒体（1A）的下端的插入状态的装配部 主体（1A）到指定位置形成在盒体（1A）上。 装配部分包括形成在插入侧的盒体（1A）的内表面上的内锥形表面（1g），并且具有朝向上侧增加的直径和形成在该外壳的外表面上的外锥形表面 盒体在插入物侧上并且具有朝向上侧增加的直径。

公开(公告)号：US08042379B2

公开(公告)日：2011-10-25

申请号：US10581317

申请日：2004-12-03

申请人： Ryoichi Sasano ,  Yutaka Nakanishi

发明人： Ryoichi Sasano ,  Yutaka Nakanishi

IPC分类号： G01N1/28 ,  G01N30/84

CPC分类号： G01N30/462 ,  G01N2030/062 ,  G01N30/14

摘要： A combination of a liquid chromatograph and a gas chromatograph was a possible measure for improving precision in analyzing organic chemical substances. However, because elutes from liquid chromatoghaphies contain water and a highly polar solvent, injection thereof into a gas chromatograph has been impossible. Consequently, to develop an analytical method which realizes that combination and an apparatus thereof has been a subject. The method of the quantitative analysis comprises subjecting a sample for analysis prepared beforehand by extracting organic chemical substances from an assay sample to fractionation by a liquid chromatograph, continuously adsorbing a fractionated elute containing a substance to be determined onto a solid-phase cartridge while conducting the fractionation, eluting this substance, which has been adsorbed on the solid-phase cartridge, with an eluent, and transferring the elute to a storage chamber of a gas chromatograph.

摘要翻译： 液相色谱仪和气相色谱仪的组合是提高分析有机化学物质精度的可行措施。 然而，因为来自液体色谱法的洗脱液含有水和高极性溶剂，所以注入气相色谱仪是不可能的。 因此，开发一种实现该组合的分析方法及其装置已经成为一个主题。 定量分析方法包括：将样品预先分析，通过从测定样品中提取有机化学物质进行分析，通过液相色谱仪进行分级，将含有待测物质的分馏洗脱液连续吸附到固相盒上，同时进行 分离，用吸附在固相柱上的该物质洗脱，并将洗脱液转移到气相色谱仪的储存室中。

公开(公告)号：USD519868S1

公开(公告)日：2006-05-02

申请号：US29205741

申请日：2004-05-20

申请人： Ryoichi Sasano ,  Kazuaki Kiji

设计人： Ryoichi Sasano ,  Kazuaki Kiji

公开(公告)号：USD493514S1

公开(公告)日：2004-07-27

申请号：US29181166

申请日：2003-05-07

申请人： Ryoichi Sasano ,  Kazuaki Kiji ,  Takasi Otoi ,  Motoaki Satoh

设计人： Ryoichi Sasano ,  Kazuaki Kiji ,  Takasi Otoi ,  Motoaki Satoh

公开(公告)号：USD493871S1

公开(公告)日：2004-08-03

申请号：US29181168

申请日：2003-05-07

申请人： Ryoichi Sasano ,  Kazuaki Kiji ,  Takasi Otoi ,  Motoaki Satoh

设计人： Ryoichi Sasano ,  Kazuaki Kiji ,  Takasi Otoi ,  Motoaki Satoh

公开(公告)号：USD493513S1

公开(公告)日：2004-07-27

申请号：US29181165

申请日：2003-05-07

申请人： Ryoichi Sasano ,  Kazuaki Kiji ,  Takasi Otoi ,  Motoaki Satoh

设计人： Ryoichi Sasano ,  Kazuaki Kiji ,  Takasi Otoi ,  Motoaki Satoh

公开(公告)号：US06203597B1

公开(公告)日：2001-03-20

申请号：US09291461

申请日：1999-04-14

申请人： Ryoichi Sasano ,  Kazuhiko Yamazaki ,  Masahiro Furuno

发明人： Ryoichi Sasano ,  Kazuhiko Yamazaki ,  Masahiro Furuno

IPC分类号： B01D1508

CPC分类号： G01N30/12 ,  G01N2030/127

摘要： To enable the mass injection of a sample in a gas chromatography and prevent occurrence of residue or decomposition of a desired constituent during analysis. The invention calls for providing the injection port with a liner, connecting the column and the liner to a press-fit, evaporating the solvent introduced into the liner, and discharging the evaporated solvent from a discharge port formed at the upper part of the liner.

摘要翻译： 为了能够在气相色谱中大量注入样品，并且防止在分析期间发生所需成分的残留或分解。 本发明要求为喷射口提供衬套，将柱和衬套连接成压配合，蒸发引入到衬套中的溶剂，并从形成在衬套上部的排出口排出蒸发的溶剂。