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    Process for producing BTX
    1.
    发明授权
    Process for producing BTX 有权

    公开(公告)号：US10344223B2

    公开(公告)日：2019-07-09

    申请号：US15571599

    申请日：2016-05-03

    Applicant: SABIC Global Technologies B.V.

    Inventor： Kae Shin Wong ,  Christoph Dittrich ,  Emiel van Kimmenade

    IPC: C10G47/18 ,  C07C4/06 ,  B01J8/04 ,  B01J29/46

    Abstract: The invention relates to a process for hydrocracking a feedstream comprising hydrocarbons to obtain BTX in a gas phase hydrocracking reactor system which comprises (i) an upstream end and a downstream end, (ii) a plurality of successive reaction zones distributed along the reactor between the upstream end and the downstream end, wherein each of the reaction zones has a bed of a hydrocracking catalyst contained therein and (iii) a plurality of quench zones, the quench zones being distributed along the reactor and each being situated between successive reaction zones, wherein the process comprises: (a) injecting a first portion of a hydrogen gas into the upstream end and a first portion of a hydrocarbon gas into the upstream end and (b) injecting a second portion of the hydrogen gas into at least one of the quench zones and injecting a second portion of the hydrocarbon gas into at least one of the quench zones, wherein the molar ratio between hydrogen and hydrocarbons entering each of the reaction zones is 1:1 to 4:1, wherein the molar ratio between hydrogen and hydrocarbons entering the reaction zones decreases with the distance of the reaction zone from the upstream end of the reactor.

    PROCESS FOR PRODUCING BTX
    2.
    发明申请
    PROCESS FOR PRODUCING BTX 审中-公开

    公开(公告)号：US20190127646A1

    公开(公告)日：2019-05-02

    申请号：US15571599

    申请日：2016-05-03

    Applicant: SABIC Global Technologies B.V.

    Inventor： Kae Shin Wong ,  Christoph Dittrich ,  Emiel van Kimmenade

    IPC: C10G47/18 ,  C07C4/06 ,  B01J8/04 ,  B01J29/46

    CPC classification number: C10G47/18 ,  B01J8/0492 ,  B01J8/0496 ,  B01J29/46 ,  B01J2208/00371 ,  C07C4/06 ,  C07C2521/12 ,  C07C2529/40 ,  C07C2529/44 ,  C10G49/002 ,  C10G65/10 ,  C10G2300/1044 ,  C10G2400/30

    Abstract: The invention relates to a process for hydrocracking a feedstream comprising hydrocarbons to obtain BTX in a gas phase hydrocracking reactor system which comprises (i) an upstream end and a downstream end, (ii) a plurality of successive reaction zones distributed along the reactor between the upstream end and the downstream end, wherein each of the reaction zones has a bed of a hydrocracking catalyst contained therein and (iii) a plurality of quench zones, the quench zones being distributed along the reactor and each being situated between successive reaction zones, wherein the process comprises: (a) injecting a first portion of a hydrogen gas into the upstream end and a first portion of a hydrocarbon gas into the upstream end and (b) injecting a second portion of the hydrogen gas into at least one of the quench zones and injecting a second portion of the hydrocarbon gas into at least one of the quench zones, wherein the molar ratio between hydrogen and hydrocarbons entering each of the reaction zones is 1:1 to 4:1, wherein the molar ratio between hydrogen and hydrocarbons entering the reaction zones decreases with the distance of the reaction zone from the upstream end of the reactor.

    Process for producing alkylated aromatic hydrocarbons from a mixed hydrocarbon feedstream
    3.
    发明授权
    Process for producing alkylated aromatic hydrocarbons from a mixed hydrocarbon feedstream 有权

    公开(公告)号：US10065904B2

    公开(公告)日：2018-09-04

    申请号：US15506429

    申请日：2015-08-27

    Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

    Inventor： Kae Shin Wong ,  Andrew Mark Ward

    IPC: C07C2/66 ,  C10G11/05 ,  C10G9/00

    Abstract: The invention relates to a process for producing alkylated aromatic hydrocarbons comprising the steps of: (a) subjecting a mixed hydrocarbon feedstream comprising benzene to a separation to provide a C6 cut comprising benzene, wherein the C6 cut comprises at least 60 wt-% of C6 hydrocarbons; (b) subjecting the C6 cut to catalytic cracking or thermal cracking to provide a cracking product stream comprising benzene and C2-C4 alkenes and (c) after step (b), without pre-separation of the cracking product stream, subjecting the cracking product stream to conditions suitable for alkylation to provide an alkylation product stream rich in alkylated aromatic hydrocarbons, wherein the process further comprises the steps of separating benzene and benzene coboilers from the alkylation product stream to obtain a stream of benzene and benzene coboilers and wherein the stream of benzene and benzene coboilers is separated into a benzene-rich stream comprising a higher proportion of benzene than the stream of benzene and benzene coboilers and a benzene-lean stream comprising a lower proportion of benzene than the stream of benzene and benzene coboilers and wherein the benzene-lean stream is recycled back to the catalytic cracking or thermal cracking in step (b).

    Process for producing LPG and BTX
    4.
    再颁专利
    Process for producing LPG and BTX 有权

    公开(公告)号：USRE49154E1

    公开(公告)日：2022-08-02

    申请号：US17061811

    申请日：2020-10-02

    Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

    Inventor： Arno Johannes Maria Oprins ,  Andrew Mark Ward ,  Andrew P. Davies ,  Kae Shin Wong ,  Luis Aramburo ,  Maikel Van Iersel

    IPC: C10G65/18 ,  B01D3/14 ,  B01D11/00 ,  C10G47/16 ,  C10G65/00 ,  C10G65/10

    Abstract: The invention relates to a process for producing LPG and BTX, comprising a) subjecting a mixed hydrocarbon stream to first hydrocracking in the presence of a first hydrocracking catalyst to produce a first hydrocracking product stream; b) separating the first hydrocracking product stream to provide at least a light hydrocarbon stream comprising at least C2 and C3 hydrocarbons, a middle hydrocarbon stream consisting of C4 and/or C5 hydrocarbons and a heavy hydrocarbon stream comprising at least C6+ hydrocarbons and c) subjecting the heavy hydrocarbon stream to second hydrocracking in the presence of a second hydrocracking catalyst to produce a second hydrocracking product stream comprising BTX, wherein the second hydrocracking is more severe than the first hydrocracking, d) wherein at least part of the middle hydrocarbon stream is subjected to C4 hydrocracking optimized for converting C4 hydrocarbons into C3 hydrocarbons in the presence of a C4 hydrocracking catalyst to produce a C4 hydrocracking product stream.

    Process for producing LPG and BTX
    7.
    发明授权
    Process for producing LPG and BTX 有权

    公开(公告)号：US10287518B2

    公开(公告)日：2019-05-14

    申请号：US15538447

    申请日：2015-12-15

    Applicant: SABIC Global Technologies B.V.

    Inventor： Arno Johannes Maria Oprins ,  Andrew P. Davies ,  Andrew Mark Ward ,  Kae Shin Wong ,  Luis Aramburo ,  Maikel Van Iersel

    IPC: C10G65/10 ,  C10G47/16 ,  C10G67/02 ,  C10G65/00 ,  C10G65/18 ,  C10G69/02

    Abstract: The invention relates to a process for producing LPG and BTX, comprising a) subjecting a mixed hydrocarbon feedstream to first hydrocracking in the presence of a first hydrocracking catalyst to produce a first hydrocracking product stream; b) separating the first hydrocracking product stream to provide at least a light hydrocarbon stream comprising at least C2 and C3 hydrocarbons, a middle hydrocarbon stream comprising C4 and/or C5 hydrocarbons and a heavy hydrocarbon stream comprising at least C6+ hydrocarbons and c) subjecting the heavy hydrocarbon stream to second hydrocracking to produce a second hydrocracking product stream comprising BTX, wherein the second hydrocracking is more severe than the first hydrocracking, wherein at least part of the middle hydrocarbon stream is recycled back to the first hydrocracking in step a).

    Process for producing LPG and BTX
    8.
    发明授权
    Process for producing LPG and BTX 有权

    公开(公告)号：US10087378B2

    公开(公告)日：2018-10-02

    申请号：US15538391

    申请日：2015-12-15

    Applicant: SABIC Global Technologies B.V.

    Inventor： Arno Johannes Maria Oprins ,  Andrew Mark Ward ,  Andrew P. Davies ,  Kae Shin Wong ,  Luis Aramburo ,  Maikel Van Iersel

    IPC: C10G47/16 ,  C10G65/10 ,  C10G65/18 ,  B01D3/14 ,  B01D11/00

    Abstract: The invention relates to a process for producing LPG and BTX, comprising a) subjecting a mixed hydrocarbon stream to first hydrocracking in the presence of a first hydrocracking catalyst to produce a first hydrocracking product stream; b) separating the first hydrocracking product stream to provide at least a light hydrocarbon stream comprising at least C2 and C3 hydrocarbons, a middle hydrocarbon stream consisting of C4 and/or C5 hydrocarbons and a heavy hydrocarbon stream comprising at least C6+ hydrocarbons and c) subjecting the heavy hydrocarbon stream to second hydrocracking in the presence of a second hydrocracking catalyst to produce a second hydrocracking product stream comprising BTX, wherein the second hydrocracking is more severe than the first hydrocracking, d) wherein at least part of the middle hydrocarbon stream is subjected to C4 hydrocracking optimized for converting C4 hydrocarbons into C3 hydrocarbons in the presence of a C4 hydrocracking catalyst to produce a C4 hydrocracking product stream.

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