Abstract:
Provided are a separator coating composition, a method of manufacturing a separator using the same, and a separator and a lithium battery using the same. The separator coating composition includes a binder containing an aqueous crosslinking reactive poly(vinylamide)-based copolymer, a crosslinking agent having at least bifunctionality, inorganic particles, and water, wherein the poly(vinylamide)-based copolymer includes a repeating unit derived from a vinylamide monomer and a repeating unit derived from a crosslinking reactive group-containing monomer. The separator coating composition may be used to prepare a separator capable of exhibiting high heat resistance even at a thinner coating thickness.
Abstract:
Provided are a separator, a lithium secondary battery employing the same, and a method of preparing the separator. The separator includes: a porous substrate; and a coating layer arranged on at least one surface of the porous substrate, wherein the coating layer includes a binder and inorganic particles, the binder includes an aqueous cross-linking reactive polyacrylamide-based copolymer, and the polyacrylamide-based copolymer includes at least two cross-linking reactive groups cross-linkable with each other, a weight ratio of the binder to the inorganic particles is about 1:10 to about 1:35, and a thickness of the coating layer is greater than 0.5 μm and no greater than 4 μm. The separator has significantly improved thermal resistance characteristics and low resistance, and therefore, a lithium secondary battery with improved battery stability and lifespan characteristics at the same time may be provided.
Abstract:
The present disclosure provides a separator for a rechargeable lithium battery and a rechargeable lithium battery including same, the separator includes a porous substrate; and an adhesive layer formed on the porous substrate. The adhesive layer includes a particle-type binder having a core-shell structure including a core and a shell surrounding the core, the core includes a first polymer having a glass transition temperature of less than or equal to 30° C., the shell includes a second polymer having a glass transition temperature of greater than or equal to 40° C., and the particle-type binder has a diameter of 50 nm to 500 nm.
Abstract:
The present disclosure relates to a separator for a lithium secondary battery, and a lithium secondary battery including same, the separator including: a porous substrate, and a heat-resistant layer on at least one surface of the porous substrate, wherein the heat-resistant layer includes a first coating layer including alumina, and a second coating layer including magnesium hydroxide, and the first coating layer and the second coating layer are consecutively disposed in a stacked form on the porous substrate.
Abstract:
Provided are a composite separator, a lithium battery including the same, and a method of manufacturing the composite separator. The composite separator includes: a porous substrate; and a coating layer on at least one surface of the porous substrate, wherein the coating layer includes a water-soluble binder and inorganic particles, and the water-soluble binder includes a polyacrylic acid metal salt.
Abstract:
Provided are a composite separator, a lithium battery including the same, and a method of manufacturing the composite separator. The composite separator includes: a porous substrate; and a coating layer on at least one surface of the porous substrate, wherein the coating layer includes a water-soluble binder and inorganic particles, and the water-soluble binder includes a polyacrylic acid metal salt.
Abstract:
Provided are a composite separator, a lithium battery including the same, and a method of manufacturing the composite separator. The composite separator includes: a porous substrate; and a coating layer on at least one surface of the porous substrate, wherein the coating layer includes a water-soluble binder and inorganic particles, and the water-soluble binder includes a polyacrylic acid metal salt.
Abstract:
The separator includes: a porous substrate; a first coating layer arranged on at least one surface of the porous substrate, the first coating layer including a binder and inorganic particles, wherein the binder includes a cross-linked product of an aqueous cross-linking reactive poly(vinylamide)-based copolymer, wherein the poly(vinylamide)-based copolymer includes repeating units derived from vinylamide monomers and repeating units derived from cross-linking reactive group-containing monomers, and is cross-linked by the cross-linking reactive groups; and a second coating layer arranged on both surfaces of the porous substrate on which the first coating layer is arranged, the second coating layer including an acrylic copolymer and a polyvinylidene fluoride-based binder in a weight ratio of greater than 1:1 and less than 1:4. The separator has high thermal resistance characteristics and enhanced electrode plate adhesion, and therefore, a lithium battery having excellent lifespan characteristics may be provided.
Abstract:
A separator for a rechargeable lithium battery includes a substrate and a heat-resistant porous layer on at least one side of the substrate. The heat-resistant porous layer includes a crosslinked binder. The crosslinked binder has a cross-linked structure of a crosslinkable compound including a siloxane compound. The siloxane compound includes a siloxane resin including a unit represented by the chemical formula R1SiO3/2, where R1 is a curable reactive group, or an organic group having a curable reactive group.
Abstract:
A separator for a rechargeable lithium battery and a rechargeable lithium battery, the separator including a porous substrate; and a coating layer on at least one surface of the porous substrate, wherein the coating layer includes a binder and inorganic particles, the binder including a polyurethane and a polyvinyl alcohol, and the polyurethane and the polyvinyl alcohol are included in a weight ratio of about 5:5 to about 9:1.