公开(公告)号：US09518151B2

公开(公告)日：2016-12-13

申请号：US14785522

申请日：2013-11-20

Applicant: SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY, CHINESE ACADEMY OF SCIENCES

Inventor： Qiang Fang ,  Chao Yuan ,  Kaikai Jin ,  Yingchun Liu ,  Shen Diao ,  Kai Li

IPC: C08G65/38 ,  C08G65/40 ,  C07C41/30 ,  C08G61/12 ,  H01L51/05 ,  C07C41/16 ,  C07C41/24 ,  C07C41/09 ,  C07C43/247 ,  C09D171/12 ,  C08G2/00

CPC classification number: C08G65/40 ,  C07C41/09 ,  C07C41/16 ,  C07C41/24 ,  C07C41/30 ,  C07C43/247 ,  C07C2601/04 ,  C08G61/12 ,  C08G65/007 ,  C08G65/4025 ,  C08G65/4075 ,  C08G65/4093 ,  C08G2261/146 ,  C08G2261/344 ,  C08G2261/43 ,  C08G2261/65 ,  C09D171/12 ,  H01L51/052 ,  C07C43/225

Abstract: The present invention belongs to the field of preparation of high performance polymers, and specifically relates to a low dielectric constant polymer containing dinaphthyl and hexafluorocyclobutyl ether units, and preparation method and use thereof. The polymer is prepared as follows: under the effect of an alkali, 1-naphthol bromotetrafluoroethane ether is prepared from 1-naphthol and tetrafluorodibromoethane in an organic solvent, and then reduced by a zinc powder so as to obtain 1-naphthol trifluorovinyl ether. 1-naphthol trifluorovinyl ether is treated at a high temperature to obtain a bisnaphthol hexafluorocyclobutyl ether monomer. The monomer is subjected to oxidative coupling in the presence of ferric trichloride so as to obtain a thermal polymer containing dinaphthyl and hexafluorocyclobutyl structural units with a good film-forming property, and in a nitrogen atmosphere, the temperature for 5% weight loss (Td5%) of the obtained film is 437° C., and the carbon residue yield at 1000° C. is 54.24%. The dielectric constant (30 MHz) of the film is 2.33. The polymer is suitable for use in the electronic and electrical industries as an insulation coating layer and an encapsulating material for electron components.

Abstract translation: 本发明属于高性能聚合物的制备领域，具体涉及含有二萘基和六氟环丁基醚单元的低介电常数聚合物及其制备方法和用途。 聚合物制备如下：在碱的作用下，1-萘酚溴四氟乙醚由1-萘酚和四氟二溴乙烷在有机溶剂中制备，然后用锌粉还原，得到1-萘酚三氟乙烯醚。 1-萘酚三氟乙烯醚在高温下处理，得到双萘酚六氟环丁基醚单体。 单体在三氯化铁存在下进行氧化偶合，得到含有成膜性能好的二萘基和六氟环丁基结构单元的热聚合物，在氮气气氛中，5％重量损失温度（Td5％ ）为437℃，1000℃下的碳残渣产率为54.24％。 该膜的介电常数（30MHz）为2.33。 聚合物适用于电子和电气工业中作为绝缘涂层和用于电子部件的封装材料。