公开(公告)号：US09346042B2

公开(公告)日：2016-05-24

申请号：US14369215

申请日：2012-12-28

Applicant: SHELL OIL COMPANY ,  CHINA UNIVERSITY OF PETROLEUM

Inventor： Rui Zhang ,  Zhichang Liu ,  Chunming Xu ,  Xianghai Meng ,  Peter Anton August Klusener

IPC: B01J38/64 ,  B01J31/40 ,  B01J31/02 ,  B01J38/66

CPC classification number: B01J31/4069 ,  B01J31/0279 ,  B01J31/40 ,  B01J38/66 ,  B01J2231/44 ,  C07C2/58 ,  C07C2527/125 ,  C10G29/205 ,  Y02P20/584 ,  C07C9/16

Abstract: The present invention relates to a regeneration process for producing a regenerated ionic liquid catalyst from solids formed in an ionic liquid alkylation process wherein a first ionic liquid is used as a catalyst which is a composite ionic liquid comprising ammonium cations, and anions being composite coordinate anions derived from two or more metal salts, the regeneration process comprising (a) removing the solids from the reaction zone of the alkylation process; and (b) subsequently treating the solids with a second ionic liquid made from an ammonium salt as cation, and an aluminum salt as anion which is the same as the aluminum salt present in the first ionic liquid.

Abstract translation: 本发明涉及一种用于在离子液体烷基化方法中形成的固体生产再生离子液体催化剂的再生方法，其中使用第一离子液体作为催化剂，其为包含铵阳离子的复合离子液体，阴离子为复合配位阴离子 衍生自两种或更多种金属盐，再生方法包括（a）从烷基化方法的反应区除去固体; 和（b）随后用由铵盐形成的第二离子液体作为阳离子处理固体，和作为阴离子的铝盐与第一离子液体中存在的铝盐相同。

公开(公告)号：US20150231624A1

公开(公告)日：2015-08-20

申请号：US14369215

申请日：2012-12-28

Applicant: SHELL OIL COMPANY ,  CHINA UNIVERSITY OF PETROLEUM

Inventor： Rui Zhang ,  Zhichang Liu ,  Chunming Xu ,  Xianghai Meng ,  Peter Anton August Klusener

IPC: B01J31/40 ,  B01J38/66 ,  B01J31/02

CPC classification number: B01J31/4069 ,  B01J31/0279 ,  B01J31/40 ,  B01J38/66 ,  B01J2231/44 ,  C07C2/58 ,  C07C2527/125 ,  C10G29/205 ,  Y02P20/584 ,  C07C9/16

Abstract: The present invention relates to a regeneration process for producing a regenerated ionic liquid catalyst from solids formed in an ionic liquid alkylation process wherein a first ionic liquid is used as a catalyst which is a composite ionic liquid comprising ammonium cations, and anions being composite coordinate anions derived from two or more metal salts, wherein at least one metal salt is an aluminium salt and any further metal salt is a salt of a metal selected from the group consisting of Group IB elements of the Periodic Table, Group IIB elements of the Periodic Table and transition elements of the Periodic Table, the regeneration process comprising (a) removing the solids from the reaction zone of the alkylation process; and (b) subsequently treating the solids with a second ionic liquid made from an ammonium salt as cation, and an aluminium salt as anion which is the same as the aluminium salt present in the first ionic liquid. The process of the invention provides means to more efficiently run an ionic liquid alkylation process with less impact on the environment than processes known from the prior art.

Abstract translation: 本发明涉及一种用于在离子液体烷基化方法中形成的固体生产再生离子液体催化剂的再生方法，其中使用第一离子液体作为催化剂，其为包含铵阳离子的复合离子液体，阴离子为复合配位阴离子 衍生自两种或更多种金属盐，其中至少一种金属盐是铝盐，并且任何另外的金属盐是选自元素周期表第IB族元素，元素周期表IIB族元素的金属盐 和周期表的过渡元素，再生过程包括（a）从烷基化方法的反应区除去固体; 和（b）随后用由铵盐形成的第二离子液体作为阳离子处理固体，和作为阴离子的铝盐与第一离子液体中存在的铝盐相同。 本发明的方法提供了比现有技术已知的方法更有效地运行对环境的影响较小的离子液体烷基化方法的方法。

公开(公告)号：US09758443B2

公开(公告)日：2017-09-12

申请号：US14651329

申请日：2013-12-13

Applicant: SHELL OIL COMPANY ,  CHINA UNIVERSITY OF PETROLEUM

Inventor： Peter Anton August Klusener ,  Rui Zhang

IPC: C07C2/56 ,  C07C2/62 ,  C07C2/58 ,  C10G29/20

CPC classification number: C07C2/58 ,  C07C2531/02 ,  C10G29/205 ,  C07C9/16

Abstract: The present invention relates to a continuous or non-continuous ionic liquid alkylation process comprising a step for solids removal, the process further comprising the steps (a) measuring the solids content in the ionic liquid alkylation process stream by on line (in situ) or off line sampling; (b) in response to the solids measurement signal, regulating the flow of the ionic liquid side stream to be sent to the solids removal device; (c) regulating the flow of the fresh ionic liquid inlet stream, for controlling the solids content in the ionic liquid alkylation process to a pre-defined level. The process of the invention provides a means to more efficiently run an ionic liquid alkylation process.

公开(公告)号：US20150315103A1

公开(公告)日：2015-11-05

申请号：US14651405

申请日：2013-12-13

Applicant: SHELL OIL COMPANY ,  CHINA UNIVERSITY OF PETROLEUM

Inventor： Peter Anton August KLUSENER ,  Zhichang LIU ,  Xianghai MENG ,  Rui Zhang ,  Jan DE WITH ,  Chunming XU

IPC: C07C7/00 ,  C07C2/58

CPC classification number: C07C7/005 ,  C07C2/58 ,  C07C2521/02 ,  C07C2523/72 ,  C07C2527/10 ,  C07C2527/126 ,  C07C2531/02 ,  C10G29/205 ,  C10G31/09 ,  C10G31/10 ,  C10G2300/1088 ,  C10G2400/02 ,  Y02P20/542 ,  C07C9/16 ,  C07C9/21

Abstract: The present invention relates to a process for preparing alkylate comprising the subsequent steps (a), (b) and (c): (a) an alkylation step, wherein in a reaction zone a hydrocarbon mixture comprising at least an isoparaffin and an olefin is reacted with an ionic liquid catalyst to obtain an effluent comprising alkylate and solids, which latter are formed as side products in the alkylation step; (b) a separation step, wherein at least part of the alkylate-comprising effluent coming from the reaction zone is separated in a separator unit into a hydrocarbon-rich phase and an ionic liquid catalyst-rich phase which latter phase also comprises solids formed as side products during the alkylation reaction; and (c) a solids removal step, wherein the solids in ionic liquid catalyst-rich phase are separated from the ionic liquid catalyst using a suitable separating device; wherein the process further comprises a step following the separation step (b) and prior to the solids removal step (c).

Abstract translation: 本发明涉及一种制备烷基化物的方法，其包括随后的步骤（a），（b）和（c）：（a）烷基化步骤，其中在反应区中至少包含异链烷烃和烯烃的烃混合物为 与离子液体催化剂反应以获得包含烷基化物和固体的流出物，其在烷基化步骤中形成为副产物; （b）分离步骤，其中来自反应区的至少部分含烷基化物的流出物在分离器单元中分离成富烃阶段和富含离子液体催化剂的相，其后相还包含固体形成为 在烷基化反应过程中产生副产物; 和（c）固体去除步骤，其中离子液体富含催化剂相的固体使用合适的分离装置与离子液体催化剂分离; 其中所述方法还包括在分离步骤（b）之后并且在固体除去步骤（c）之前的步骤。

公开(公告)号：US09567273B2

公开(公告)日：2017-02-14

申请号：US14651405

申请日：2013-12-13

Applicant: SHELL OIL COMPANY ,  CHINA UNIVERSITY OF PETROLEUM

Inventor： Peter Anton August Klusener ,  Zhichang Liu ,  Xianghai Meng ,  Rui Zhang ,  Jan De With ,  Chunming Xu

IPC: C07C2/56 ,  C07C2/58 ,  C07C2/60 ,  C07C2/62 ,  C07C7/00 ,  C10G29/20 ,  C10G31/09 ,  C10G31/10

CPC classification number: C07C7/005 ,  C07C2/58 ,  C07C2521/02 ,  C07C2523/72 ,  C07C2527/10 ,  C07C2527/126 ,  C07C2531/02 ,  C10G29/205 ,  C10G31/09 ,  C10G31/10 ,  C10G2300/1088 ,  C10G2400/02 ,  Y02P20/542 ,  C07C9/16 ,  C07C9/21

Abstract: The present invention relates to a process for preparing alkylate comprising the subsequent steps (a), (b) and (c): (a) an alkylation step, wherein in a reaction zone a hydrocarbon mixture comprising at least an isoparaffin and an olefin is reacted with an ionic liquid catalyst to obtain an effluent comprising alkylate and solids, which latter are formed as side products in the alkylation step; (b) a separation step, wherein at least part of the alkylate-comprising effluent coming from the reaction zone is separated in a separator unit into a hydrocarbon-rich phase and an ionic liquid catalyst-rich phase which latter phase also comprises solids formed as side products during the alkylation reaction; and (c) a solids removal step, wherein the solids in ionic liquid catalyst-rich phase are separated from the ionic liquid catalyst using a suitable separating device; wherein the process further comprises a step following the separation step (b) and prior to the solids removal step (c).

Abstract translation: 本发明涉及一种制备烷基化物的方法，其包括随后的步骤（a），（b）和（c）：（a）烷基化步骤，其中在反应区中至少包含异链烷烃和烯烃的烃混合物为 与离子液体催化剂反应以获得包含烷基化物和固体的流出物，其在烷基化步骤中形成为副产物; （b）分离步骤，其中来自反应区的至少部分含烷基化物的流出物在分离器单元中分离成富烃阶段和富含离子液体催化剂的相，其后相还包含固体形成为 在烷基化反应过程中产生副产物; 和（c）固体去除步骤，其中使用合适的分离装置将离子液体富含催化剂相的固体与离子液体催化剂分离; 其中所述方法还包括在分离步骤（b）之后并且在固体除去步骤（c）之前的步骤。

公开(公告)号：US11426702B2

公开(公告)日：2022-08-30

申请号：US17006723

申请日：2020-08-28

Applicant: CHINA UNIVERSITY OF PETROLEUM-BEIJING

Inventor： Chunmao Chen ,  Zhichang Liu ,  Zhongjin Yi ,  Rui Zhang ,  Jiahao Liang ,  Xianghai Meng ,  Haiyan Liu ,  Chunming Xu ,  Qinghong Wang

IPC: C02F9/00 ,  C02F11/122 ,  C04B5/00 ,  C02F11/16 ,  B01J19/20 ,  C02F11/13 ,  C10G53/04 ,  C02F11/12 ,  C02F1/52 ,  C02F1/56 ,  C02F1/66 ,  C02F11/127 ,  C02F1/00 ,  C02F103/36 ,  C02F11/121

Abstract: A method and a system for treatment of a spent chloroaluminate ionic liquid catalyst and an alkaline wastewater, where the method includes: 1) mixing the catalyst with a concentrated brine for hydrolysis reaction until residual activity of the catalyst is completely eliminated, to obtain an acidic hydrolysate and an acid-soluble oil; 2) mixing the acidic hydrolysate with an alkaline solution containing the alkaline wastewater for neutralization reaction until this reaction system becomes weak alkaline, to obtain a neutralization solution; 3) fully mixing the neutralization solution with a flocculant, carrying out sedimentation and separation, collecting the concentrated brine at an upper layer for reuse in the hydrolysis reaction, and collecting concentrated flocs at a lower layer; 4) dehydrating the concentrated flocs to obtain concentrated brine for reuse into the hydrolysis reaction, and collecting a wet solid slag; and 5) drying the wet solid slag to obtain a dry solid slag.

公开(公告)号：US10822242B2

公开(公告)日：2020-11-03

申请号：US16525503

申请日：2019-07-29

Applicant: CHINA UNIVERSITY OF PETROLEUM—BEIJING

Inventor： Haiyan Liu ,  Tao Zheng ,  Zhichang Liu ,  Xianghai Meng ,  Rui Zhang ,  Chunming Xu

IPC: C01B39/44 ,  B01J29/65 ,  B01J35/00

Abstract: The present application provides a ZSM-35 molecular sieve and a preparation method thereof. The ZSM-35 molecular sieve is an aggregated ZSM-35 molecular sieve having a hierarchical macro-meso-microporous pore structure. Raw materials for the preparation method do not include an organic template agent and a crystal seed, and the preparation method includes the following steps: preparing a reactant gel where a molar ratio of SiO2, Al2O3, Na2O, K2O, oxygen-containing acid radical and H2O is (20-40):1.0:(1.5-2.0):(4.0-6.5):(1.0-4.0):(600-1200); sequentially performing an aging treatment and a crystallization treatment on the reactant gel, washing and drying a resulting synthetic product. The ZSM-35 molecular sieve provided by the present application may be obtained by synthesizing without using an organic template agent and crystal seed, and because it has a hierarchical pore structure, it is favorable for material diffusion and mass transfer.

公开(公告)号：US12203365B2

公开(公告)日：2025-01-21

申请号：US17883616

申请日：2022-08-09

Applicant: CHINA UNIVERSITY OF PETROLEUM (EAST CHINA)

Inventor： Zizhen Wang ,  Xianbo Lei ,  Weidong Zhou ,  Chengwen Wang ,  Ruihe Wang ,  Xian Shi ,  Luopeng Li ,  Hongjian Ni ,  Rui Zhang

IPC: E21B49/02 ,  G01N3/42

Abstract: A method for evaluating rock drillability by a nano-indentation test on a rock cutting includes: conducting a nano-indentation test on a rock cutting sample, acquiring a displacement-load curve of an indenter, and calculating a micro-hardness under the nano-indentation test; calculating mineral composition of the rock cutting sample based on a statistical distribution characteristic of the micro-hardness, and transforming the micro-hardness under the nano-indentation test on the rock cutting sample into a macro-hardness; and calculating a rock drillability grade characterized by the micro-hardness under the nano-indentation test on the rock cutting sample based on a correlation between the macro-hardness of the rock cutting sample and the rock drillability grade. In the context of few downhole rock samples and high cost, the method overcomes the limitation of sample size and shape on conventional testing and solves the difficult problem of mechanical parameter testing of deep rocks.

公开(公告)号：US11873712B2

公开(公告)日：2024-01-16

申请号：US17495640

申请日：2021-10-06

Applicant: China University of Petroleum-Beijing

Inventor： Zhaojie Song ,  Changxiao Cao ,  Daqian Zeng ,  Shaohua Gu ,  Jiangbo Dong ,  Rui Zhang ,  Zehui Xie ,  Ying Jia

IPC: E21B49/00 ,  E21B41/00 ,  G01N33/24 ,  G09B25/02 ,  E21B43/12 ,  E21B47/00 ,  G06F30/20 ,  G06F111/10

CPC classification number: E21B49/00 ,  E21B41/00 ,  E21B43/12 ,  E21B47/00 ,  G01N33/241 ,  G09B25/02 ,  E21B2200/20 ,  G06F30/20 ,  G06F2111/10

Abstract: The present disclosure provides an edge and bottom water invasion simulation apparatus and method, a storage medium, and a product. A controller controls an inert gas to be injected into a first intermediate container, and stops the injection. The controller controls formation water to be injected into the first intermediate container, and stops the injection. The controller controls the first intermediate container to be communicated with a core holder, and adjusts a pressure of a back pressure valve, so that the formation water enters a core to simulate edge and bottom water invasion. In the present disclosure, by adding the inert gas and the formation water to the intermediate container, an infinite edge and bottom water with sufficient energy at an early stage of a water invasion and a limited edge and bottom water with lower energy at a later stage of the water invasion can be effectively simulated.

公开(公告)号：US11634334B2

公开(公告)日：2023-04-25

申请号：US17037409

申请日：2020-09-29

Applicant: CHINA UNIVERSITY OF PETROLEUM-BEIJING

Inventor： Tao Zheng ,  Haiyan Liu ,  Zhichang Liu ,  Xianghai Meng ,  Rui Zhang ,  Chunming Xu

IPC: C01B39/44

Abstract: The present disclosure provides a method of synthesizing an aluminosilicate molecular sieve by a crystal seed-assisted method, a natural aluminosilicate clay mineral treated and activated by an alkali is used as a crystal seed for synthesis of the aluminosilicate molecular sieve, and the target molecular sieve product is synthesized by hydrothermal crystallization, wherein the synthesis process does not require addition of conventional crystal seeds of a molecular sieve or use of any organic template agent, thus the synthesized product does not require a calcination process to remove the template agent. The method of synthesizing an aluminosilicate molecular sieve by a crystal seed-assisted method can meet the requirements of both crystallinity and nucleation time, and greatly reduce costs of synthesizing the aluminosilicate molecular sieve, and reduce the environmental pollution caused by removal of the template agent by calcinating.