公开(公告)号：US09249320B2

公开(公告)日：2016-02-02

申请号：US13673418

申请日：2012-11-09

Applicant: SICPA HOLDING SA

Inventor： Cecile Pasquier ,  Patrick Wyss

IPC: B41M3/14 ,  B42D15/00 ,  B44F1/10 ,  C09D11/037 ,  C09D11/103 ,  C07D311/00 ,  C07D221/00 ,  C07D471/00 ,  C09D11/328 ,  C09B69/10 ,  B44F1/08 ,  C09B57/08

CPC classification number: C09D11/103 ,  B41M3/14 ,  B42D15/00 ,  B42D25/378 ,  B44F1/08 ,  C07D221/00 ,  C07D311/00 ,  C07D471/00 ,  C09B57/08 ,  C09B69/102 ,  C09D11/037 ,  C09D11/328 ,  Y10T428/24802

Abstract: A polymer-bonded polycyclic aromatic hydrocarbon compound of general formula (1): (P—O)x-Q-(Y)w  (1) wherein P represents a polymeric moiety having at least three repeating units which comprise an optionally substituted phenyl ring; Q represents a perylene, quaterrylene or terrylene moiety; Y is selected from (i) halogen and (ii) optionally substituted N-heterocycloaliphatic groups having from 3 to about 8 ring members which are bonded to Q through an N atom, provided that at least one Y represents (ii); x represents an integer of from 1 to 4; w represents an integer of from 1 to 4. Also, are provided processes of producing the compounds, polymers, markings and articles, and methods of authenticating.

Abstract translation: 通式（1）的聚合物键合的多环芳烃化合物：（P-O）x-Q-（Y）w（1）其中P表示具有至少三个包含任选取代的苯环的重复单元的聚合物部分; Q表示苝，四亚甲基或二十二烷基; Y选自（i）卤素和（ii）具有3至约8个环成员的任选取代的N-杂环脂族基团，其通过N原子与Q键合，条件是至少一个Y表示（ii）; x表示1〜4的整数， w表示1〜4的整数。此外，提供了制备化合物，聚合物，标记和制品的方法以及认证方法。

公开(公告)号：US10654307B2

公开(公告)日：2020-05-19

申请号：US15029660

申请日：2014-10-09

Applicant: SICPA HOLDING SA

Inventor： Christophe Garnier ,  Lucien Vuilleumier ,  Cecile Pasquier

IPC: B42D25/364 ,  C09K19/38 ,  B41M3/14 ,  C09K19/58 ,  C09D11/03 ,  B42D25/23 ,  B42D25/29 ,  B42D25/355 ,  B42D25/44 ,  B41F11/02 ,  C09K19/34 ,  B41M1/10 ,  C09K19/04

Abstract: The present invention is related to the filed of optically variable security elements comprising a region based on a single cured ink comprising a cholesteric liquid crystal polymer, said region having at least two, preferably at least three, patterns exhibiting, at at least one viewing angle, a different CIE (1976) color index parameter and/or a different position of the selective reflection band for protecting security documents against counterfeiting and/or illegal reproduction. In particular, the present invention relates to processes for manufacturing said features, when the processes comprises the steps of a) applying on a substrate by a rotogravure process with the use of a gravure cylinder having at least two, preferably at least three, different engravings a single cholesteric liquid crystal precursor composition, b) heating the applied composition to bring said composition to a cholesteric liquid crystal state, and c) curing the composition so as to form the region based on a single cured ink comprising a cholesteric liquid crystal polymer.

公开(公告)号：US09505869B2

公开(公告)日：2016-11-29

申请号：US14719842

申请日：2015-05-22

Applicant: SICPA HOLDING SA

Inventor： Cecile Pasquier ,  Patrick Wyss

IPC: C08G8/28 ,  C07D495/16 ,  C09B57/08 ,  C09B5/62 ,  C09B57/00

CPC classification number: C08G8/28 ,  C07D495/16 ,  C09B5/62 ,  C09B57/00 ,  C09B57/08

Abstract: Polycyclic aromatic hydrocarbon compounds having an S atom or S(═O)2 moiety incorporated in their basic polycyclic structure that can have a nitrogen-containing heterocycloaliphatic group and/or a substituted or unsubstituted phenoxy group and/or a polymeric moiety bonded to the polycyclic structure and to compositions such as, e.g., printing inks which comprise these polycyclic aromatic hydrocarbons as colorants.

Abstract translation: 具有S原子或S（= O）2部分的多环芳烃化合物掺入其碱性多环结构中，其可具有含氮杂环脂族基团和/或取代或未取代的苯氧基和/或与多环结合的聚合部分 结构和组合物，例如包含这些多环芳烃作为着色剂的印刷油墨。