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1.
公开(公告)号:US20240300871A1
公开(公告)日:2024-09-12
申请号:US18269165
申请日:2021-11-16
Inventor: Daesung PARK , Hawon PARK , Changyeol SONG , Eun Sang KIM , Yong Ki PARK , Won Choon CHOI , Ung Gi HONG , Miyoung LEE , Hae Bin SHIN , Sanghyeon PARK , Deuk Soo PARK
CPC classification number: C07C5/325 , C07C7/005 , C07C2521/02 , C07C2521/04 , C07C2523/42 , C07C2523/89
Abstract: A method for producing olefins using a circulating fluidized bed process, includes: supplying a propane-containing hydrocarbon mixture and a dehydrogenation catalyst into a riser, which is a fast fluidization regime, to cause a dehydrogenation reaction; separating, from a propylene mixture, the catalyst which is a product of the dehydrogenation reaction; removing unseparated hydrocarbon compounds remaining in the catalyst separated in the separating; continuously regenerating the catalyst by mixing the catalyst stripped in the removing with a gas containing oxygen; circulating the catalyst regenerated in the continuously regenerating to the supplying and resupplying it into the riser; and preparing propylene by cooling, compressing, and separating the propylene mixture which is a reaction product separated in the separating.
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2.
公开(公告)号:US20230127784A1
公开(公告)日:2023-04-27
申请号:US17909241
申请日:2020-12-24
Inventor: Daesung PARK , Hawon PARK , Changyeol SONG , Yong Ki PARK , Won Choon CHOI , Ung Gi HONG , Hae Bin SHIN , Miyoung LEE , Deuk Soo PARK
Abstract: The present disclosure is to provide a catalyst for olefin production which is eco-friendly and has excellent conversion rates and selectivity and a preparation method thereof, and the catalyst for olefin production according to the present disclosure is one in which cobalt and zinc are supported with alumina. Particularly, the catalyst according to the present disclosure uses an amount of platinum that is about 400 times smaller than that of the conventional catalysts, and has high conversion rates and selectivity under conditions in which continuous reaction-regeneration process is possible without an additional hydrogen reduction process.
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3.
公开(公告)号:US20210354113A1
公开(公告)日:2021-11-18
申请号:US17281114
申请日:2019-05-14
Inventor: Yong Ki PARK , Won Choon CHOI , Daesung PARK , Hawon PARK , Changyeol SONG , Deuk Soo PARK , Ung Gi HONG , Miyoung LEE
Abstract: Disclosed is a catalyst for producing an olefin including an oxygen carrier material and a dehydrogenation catalyst. The catalyst allows hydrogen to be converted into water by using oxygen inside the lattice of an oxide catalyst without the additional supply of oxygen, and thus, the conversion can be increased while the decrease in selectivity, which is a disadvantage of an additional oxidative dehydrogenation reaction (ODHP), is suppressed.
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4.
公开(公告)号:US20230381749A1
公开(公告)日:2023-11-30
申请号:US18032990
申请日:2021-11-01
Inventor: Daesung PARK , Hawon PARK , Changyeol SONG , Yong Ki PARK , Won Choon CHOI , Ung Gi HONG , Deuk Soo PARK , Miyoung LEE , Hae Bin SHIN , Sanghyeon PARK
CPC classification number: B01J23/75 , B01J35/0006 , B01J35/02 , B01J21/04 , B01J23/42 , B01J37/0211 , B01J37/0209 , B01J6/001 , C07C5/3337
Abstract: There is provided a dehydrogenation catalyst for producing olefins from alkane gases, in which a metal active component is supported on an alumina carrier containing boron. There is provided a method for preparing a dehydrogenation catalyst for producing olefins from alkane gases. The method includes impregnating alumina in a boron-containing solution and calcining it to provide a boron-alumina carrier; providing a solution containing the metal active component; impregnating the boron-alumina solution in the solution containing the metal active component and drying it; and calcining the boron-alumina carrier on which the metal active component is supported at 700° C. to 900° C.
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公开(公告)号:US20210113993A1
公开(公告)日:2021-04-22
申请号:US17253835
申请日:2019-04-15
Inventor: Yong Ki PARK , Won Choon CHOI , Daesung PARK , Hawon PARK , Deuk Soo PARK , Ung Gi HONG , Byungjun KANG , Miyoung LEE
Abstract: Disclosed is a catalyst for producing an olefin, the catalyst having an excellent conversion and excellent selectivity, and a method for preparing the catalyst. The catalyst for producing an olefin, according to the present invention, includes: a support including alumina and an auxiliary support component; a main catalyst including an active metal oxide supported on the support; and a co-catalyst including an oxide of an alkali metal and a Group 6B transition metal.
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公开(公告)号:US20210354112A1
公开(公告)日:2021-11-18
申请号:US17281132
申请日:2019-12-04
Applicant: SK GAS CO., LTD. , KOREA RESEARCH INSTITUTE OF CHEMICAL TECHNOLOGY , KOREA NATIONAL UNIVERSITY OF TRANSPORTATION INDUSTRY-ACADEMIC COOPERATION FOUNDATION
Inventor: Yong Ki PARK , Won Choon CHOI , Daesung PARK , Hawon PARK , Changyeol SONG , Deuk Soo PARK , Ung Gi HONG , Miyoung LEE , Sungwon KIM , Chaeeun YEO
IPC: B01J21/06 , B01J8/38 , C07C5/333 , B01J21/04 , B01J35/02 , B01J23/26 , B01J23/30 , B01J35/10 , B01J37/08
Abstract: Disclosed is a method of producing an olefin using a circulating fluidized bed process, including: (a) supplying a hydrocarbon mixture including propane and a dehydrogenation catalyst to a riser which is in a state of a fast fluidization regime, and thus inducing a dehydrogenation reaction; (b) separating an effluent from the dehydrogenation reaction into the catalyst and a propylene mixture; (c) stripping, in which a residual hydrocarbon compound is removed from the catalyst separated in step (b); (d) mixing the catalyst stripped in step (c) with a gas containing oxygen and thus continuously regenerating the catalyst; (e) circulating the catalyst regenerated in step (d) to step (a) and thus resupplying the catalyst to the riser; and (f) cooling, compressing, and separating the propylene mixture, which is a reaction product separated in step (b), and thus producing a propylene product.
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